Advances in Controlled/Living Radical Polymerization

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ISBN: 9780841238541 | 0841238545
Cover: Hardcover
Copyright: 6/26/2003

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Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis and characterization of many newmaterials.

Preface

xiii

Fundamentals

Controlled/Living Radical Polymerization: State of the Art in 2002

(8)

Krzysztof Matyjaszewski

Criteria for Livingness and Control in Nitroxide-Mediated and Related Radical Polymerizations

(14)

Hanns Fischer

Mechanisms and Kinetics of Living Radical Polymerization: Absolute Comparison of Theory and Experiment

(18)

Takeshi Fukuda

Chiaki Yoshikawa

Yungwan Kwak

Atsushi Goto

Yoshinobu Tsujii

Conventional Radical Polymerization

Termination Kinetics of Acrylate and Methacrylate Homo- and Copolymerizations

(17)

Michael Buback

Mark Egorov

Achim Feldermann

Lewis Acid-Catalyzed Tacticity Control during Radical Polymerization of (Meth)acrylamides

(13)

Yoshio Okamoto

Shigeki Habaue

Yutaka Isobe

Propagation and Termination in Free Radical Polymerization of Styrene to High Conversion Investigated by Electron Spin Resonance Spectroscopy

(14)

Per B. Zetterlund

Hirotomo Yamazoe

Satoru Yamauchi

Bunichiro Yamada

Electron Spin Resonance Study of Conventional Radical Polymerization of tert-Butyl (Meth)acrylates Using Radical Precursors Prepared by Atom Transfer Radical Polymerization

(16)

Atsushi Kajiwara

Mikiharu Kamachi

Atom Transfer Radical Polymerization: Mechanisms

Living Radical Polymerization with Designed Metal Complexes

102

(14)

Masami Kamigaito

Tsuyoshi Ando

Mitsuo Sawamoto

Controlled Radical Polymerization Catalyzed by Ruthenium Complexes: Variations on Ru-Cp#

116

(14)

Sebastien Delfosse

Aurore Richel

Francois Simal

Albert Demonceau

Alfred F. Noels

Oscar Tutusaus

Rosario Nunez

Clara Vinas

Francesc Teixidor

Toward Structural and Mechanistic Understanding of Transition Metal-Catalyzed Atom Transfer Radical Processes

130

(18)

Tomislav Pintauer

Blayne McKenzie

Krzysztof Matyjaszewski

Mechanistic Aspects of Copper-Mediated Living Radical Polymerization

148

(13)

Jeetan Lad

Simon Harrisson

David M. Haddleton

ESR Study and Radical Observation in Transition Metal-Mediated Polymerization: Unified View of Atom Transfer Radical Polymerization Mechanism

161

(19)

Aileen R. Wang

Shiping Zhu

Krzysztof Matyjaszewski

Peculiarities in Atom Transfer Radical Copolymerization

180

(13)

Bert Klumperman

Gregory Chambard

Richard H. G. Brinkhuis

Atom Transfer Radical Polymerization of Methyl Methacrylate Utilizing an Automated Synthesizer

193

(13)

Huiqi Zhang

Martin W. M. Fijten

Richard Hoogenboom

Ulrich S. Schubert

Asymmetric Atom Transfer Radical Polymerization: Enantiomer-Selective Cyclopolymerization of rac-2,4-Pentanediyl Dimethacrylate Using Chiral ATRP Initiator

206

(15)

Toyoji Kakuchi

Masashi Tsuji

Toshifumi Satoh

Organic Acids Used as New Ligands for Atom Transfer Radical Polymerization

221

(15)

Shenmin Zhu

Deyue Yan

Marcel Van Beylen

Nøvel Fluorinated Polymer Materials Based on 2,3,5,6- Tetrafluoro-4-methoxystyrene

236

(14)

Soren Hvilsted

Sachin Borkar

Heinz W. Siesler

Katja Jankova

Copper Removal in Atom Transfer Radical Polymerization

250

(18)

Mical E. Honigfort

Shingtza Liou

Jude Rademacher

Dennis Malaba

Todd Bosanac

Craig S. Wilcox

William J. Brittain

Atom Transfer Radical Polymerization: Materials and Applications

Synthesis and Properties of Copolymers with Tailored Sequence Distribution by Controlled/Living Radical Polymerization

268

(15)

Jean-Francois Lutz

Tadeusz Pakula

Krzysztof Matyjaszewski

Controlled Synthesis of Amphiphilic Poly(methacrylate)-g-[poly(ester)/poly(ether)] Graft Terpolymers

283

(16)

Isabelle Ydens

Philippe Degee

Jan Libiszowski

Andrzej Duda

Stanislaw Penczek

Philippe Dubois

New Materials Using Atom Transfer Radical Polymerization: Microcapsules Containing Polar Core Oil

299

(17)

Mir Mukkaram Ali

Harald D. H. Stover

Synthesis of Poly(N, N-Dimethylacrylamide) Brushes from Functionalized Latex Surfaces by Aqueous Atom Transfer Radical Polymerization

316

(15)

Jayachandran N. Kizhakkedathu

Diane Goodman

Donald E. Brooks

End-Functional Polystyrenes via Quasiliving Atom Transfer Radical Polymerization and New Polymer Structures Therefrom

331

(11)

Bela Ivan

Tamas Fonagy

Tibor Erdey-Gruz

Gyorgy Hollo-Szabo

Marta Szesztay

Ulrich Schulze

Jurgen Pionteck

A Strategy to Prepare Anemone-Shaped Polymer Brush by Controlled/Living Radical Polymerization

342

(10)

Fu-Mian Li

Ming-Qiang Zhu

Xin Zhang

Liu-He Wei

Fu-Sheng Du

Zi-Chen Li

Surface Modification of Ethylene-Vinyl Alcohol Copolymer Films by Surface-Confined Atom Transfer Radical Polymerization

352

(14)

Ning Luo

Scott M. Husson

Douglas E. Hirt

Dwight W. Schwark

Polymers, Particles, and Surfaces with Hairy Coatings: Synthesis, Structure, Dynamics, and Resulting Properties

366

(17)

Tadeusz Pakula

Piotr Minkin

Krzysztof Matyjaszewski

Photoinduced Free Radical Promoted Cationic Block Copolymerization by Using Macrophotoinitiators Prepared by ATRP and Ring-Opening Polymerization Methods

383

(11)

Yusuf Yagci

Mustafa Degirmenci

Bioinspired Triblock Copolymers Prepared by Atom Transfer Radical Copolymerization

394

(18)

Jan C. M. van Hest

Lee Ayres

Henri Spijker

Matthijn Vos

Joost Opsteen

Nitroxide-Mediated Polymerization and Stable Free Radical Polymerization

Influence of Solvent and Polymer Chain Length on the Homolysis of SGI-Based Alkoxyamines

412

(12)

Olivier Guerret

Jean-Luc Couturier

Florence Chauvin

Hafid El-Bouazzy

Denis Bertin

Didier Gigmes

Sylvain Marque

Hanns Fischer

Paul Tordo

Impact of Dilution on the Rate Constant of Termination <kt> in Nitroxide-Mediated Polymerization

424

(14)

Celine Chevalier

Olivier Guerret

Yves Gnanou

Nitroxide-Mediated Polymerization in Miniemulsion: A Direct Way from Bulk to Aqueous Dispersed Systems

438

(14)

B. Charleux

The Use of PROXYL Nitroxides in Nitroxide-Mediated Polymerization

452

(14)

Neil R. Cameron

Catherine A. Bacon

Alistair J. Reid

Nitroxide-Mediated Semibatch Polymerization for the Production of Low-Molecular Weight Solvent-Borne Coatings Resins

466

(15)

Yanxiang Wang

Frederic Naulet

Michael F. Cunningham

Robin A. Hutchinson

Boroxyl-Based Radical Initiators and Polymerization

481

(15)

T. C. Chung

H. Hong

Controlled Radical Polymerization of Alkyl Methacrylates in the Presence of NO/NO2 Mixtures

496

(24)

Christophe Detrembleur

Michael Claes

Robert Jerome

RAFT and Other Degenerative Transfer Processes

Kinetics and Mechanism of RAFT Polymerization

520

(16)

Graeme Moad

Roshan T. A. Mayadunne

Ezio Rizzardo

Melissa Skidmore

San H. Thang

On the Importance of Xanthate Substituents in the MADIX Process

536

(15)

Mathias Destarac

Daniel Taton

Samir Z. Zard

Twana Saleh

Yvan Six

Influences of the Structural Design of RAFT Agents on Living Radical Polymerization Kinetics

551

(19)

Thomas P. Davis

Christopher Barner-Kowollik

T. L. Uyen Nguyen

Martina H. Stenzel

John F. Quinn

Philipp Vana

Vinylidene Chloride Copolymerization with Methyl Acrylate by Degenerative Chain Transfer

570

(16)

P. Lacroix-Desmazes

R. Severac

B. Boutevin

RAFT Polymerization in Homogeneous Aqueous Media

586

(17)

Andrew B. Lowe

Brent S. Sumerlin

Michael S. Donovan

David B. Thomas

Pierre Hennaux

Charles L. McCormick

RAFT Polymers: Novel Precursors for Polymer--Protein Conjugates

603

(16)

Christine M. Schilli

Axel H. E. Muller

Ezio Rizzardo

San H. Thang

(Bill) Y. K. Chong

New Concepts for Controlled Radical Polymerization: The DPE System

619

(12)

P. C. Wieland

O. Nuyken

Y. Heischkel

B. Raether

C. Strissel

Organotellurium-Mediated Living Radical Polymerization

631

(14)

Shigeru Yamago

Kazunori Iida

Jun-ichi Yoshida

Indexes

Author Index

645

(2)

Subject Index

647

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Advances in Controlled/Living Radical Polymerization

Summary

Table of Contents

Supplemental Materials