Advances in Inorganic Chemistry: Iron-Sulfur

Advances in Inorganic Chemistrypresents timely and informative summaries of the current progress in a variety of subject areas within inorganic chemistry, ranging from bioinorganic to solid state. This acclaimed serial features reviews written by experts in the area and is an indispensable reference to advanced researchers. Each volume of Advances in Inorganic Chemistrycontains an index, and each chapter is fully referenced.

Biological and Synthetic [Fe3S4] Clusters

Michael K. Johnson

Randall E. Duderstadt

Evert C. Duin

Introduction

1

(1)

Historical Perspective

2

(3)

Occurrence and Function

5

(12)

Structures

17

(4)

Electronic, Magnetic, and Vibrational Properties

21

(34)

Cluster Conversions

55

(3)

Synthetic Model Compounds

58

(5)

Mixed Metal Clusters

63

(9)

Future Directions

72

(11)

References

73

(10)

The Structures of Rieske and Rieske-Type Proteins

Thomas A. Link

Introduction

83

(1)

Historical Background

84

(1)

Structural Aspects

85

(28)

Spectroscopy

113

(24)

Electrochemistry

137

(7)

Biosynthesis

144

(2)

Function

146

(5)

Outlook

151

(9)

References

152

(8)

Structure, Function, and Biosynthesis of the Metallosulfur Clusters in Nitrogenases

Barry E. Smith

Introduction

160

(2)

The Fe Proteins of Molybdenum Nitrogenase

162

(4)

The MoFe Proteins

166

(8)

Biosynthesis of Molybdenum Nitrogenase

174

(9)

The Mechanism of Molybdenum Nitrogenase

183

(19)

The Alternative Nitrogenases

202

(9)

Conclusions and Outlook

211

(8)

References

212

(7)

The Search for a ``Prismane'' Fe-S Protein

Alexander F. Arendsen

Peter F. Lindley

Introduction

219

(2)

Historical Discovery of ``Prismane'' Protein (Now Termed Feps)

221

(11)

Crystallographic Studies

232

(13)

Conclusion and Future Studies

245

(6)

References

247

(4)

NMR Spectra of Iron-Sulfur Proteins

Ivano Bertini

Claudio Luchinat

Antonio Rosato

Introduction

251

(1)

Electron Relaxation Times

252

(5)

Valence Delocalization

257

(8)

Considerations on the Reduction Potential

265

(1)

Solution Structure

266

(5)

Folding

271

(5)

Perspectives

276

(7)

References

277

(6)

Nickel-Iron-Sulfur Active Sites: Hydrogenase and CO Dehydrogenase

Juan C. Fontecilla-Camps

Stephen W. Ragsdale

Introduction

283

(2)

General Concepts Regarding Nickel and Iron-Sulfur

285

(1)

Hydrogenase

286

(19)

CODH/ACS

305

(21)

Conclusions

326

(9)

References

326

(9)

FeS Centers Involved in Photosynthetic Light Reactions

Barbara Schoepp

Myriam Brugna

Evelyne Lebrun

Wolfgang Nitschke

Introduction

335

(3)

2[4Fe-4S] Proteins

338

(6)

The Bridging Cluster FX

344

(1)

[2Fe-2S] Ferredoxins

344

(1)

High-Potential Iron-Sulfur Proteins

345

(2)

The Rieske Protein

347

(8)

Evolutionary Remarks

355

(6)

References

356

(5)

Simple and Complex Iron-Sulfur Proteins in Sulfate Reducing Bacteria

Isabel Moura

Alice S. Pereira

Pedro Tavares

Jose J. G. Moura

Introduction

361

(1)

Rubredoxin and Desulforedoxin

362

(4)

Desulfoferrodoxin

366

(1)

Rubrerythrin

367

(3)

Ferredoxins

370

(8)

Fuscoredoxin (Novel Fe-S Cluster)

378

(4)

APS Reductase

382

(3)

Pyruvate--Ferredoxin Oxidoreductase

385

(1)

Sulfite Reductase

386

(2)

Hydrogenase

388

(7)

Molybdopterin-Containing Enzymes in SRB

395

(10)

Concluding Remarks

405

(16)

References

410

(11)

Application of EPR Spectroscopy to the Structural and Functional Study of Iron-Sulfur Proteins

Bruno Guigliarelli

Patrick Bertrand

Introduction

421

(2)

EPR Characteristics and Relaxation Properties of the Centers

423

(27)

Application of EPR to the Structural Study of Iron-Sulfur Proteins

450

(24)

Application of EPR to the Functional Study of Iron-Sulfur Centers

474

(10)

Conclusion

484

(15)

Spin--Lattice Relaxation Processes

486

(1)

References

487

(12)

Index

499

(12)

Contents of Previous Volumes

511

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Advances in Inorganic Chemistry: Iron-Sulfur Proteins

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