Bio-inorganic Hybrid Nanomaterials

This ready reference is the first to collate the interdisciplinary knowledge from materials science, bioengineering and nanotechnology to give an in-depth overview of the topic. As such, it provides broad coverage of combinations between inorganic materials and such key biological structures as proteins, enzymes, DNA, or biopolymers. With its treatment of various application directions, including bioelectronic interfacing, tissue repair, porous membranes, sensors, nanocontainers, and DNA engineering, this is essential reading for materials engineers, medical researchers, catalytic chemists, biologists, and those working in the biotechnological and semiconductor industries.

Eduardo Ruiz-Hitzky is the director of the Department of Porous Materials and Intercalation Compounds at the Materials Science Institute of Madrid (CSIC), Spain. His research work during the last 30 years has focused on organic-inorganic hybrids and bio-nanocomposite materials. Professor Ruiz-Hitzky has authored over 150 scientific publications and edited two journal special issues, one of them (now in preparation) on bio-nanohybrid materials. He has received several scientific awards from different countries, including the AIPEA Medal from the International Association for the Study of Clays (Tokyo, 2005).

Katsuhiko Ariga is the director of the Supermolecules Group at the National Institute for Materials Science (NIMS), Japan. His research work during the last 20 years has focused on fabrication of nanostructured materials through specific interaction at interfaces, creating novel hybrids of inorganic, organic and biological materials. Dr. Katsuhiko Ariga has authored over 230 scientific publications and received more than 3600 citations. He has published three text books on supramolecular chemistry and served as an editor of one book and one journal special issue on nanomaterials.

Yuri M. Lvov is Chemistry Professor and Pipes Endowed Chair on Micro and Nanosystems at Louisiana Tech University, USA. Earlier, he worked in the Center for Biomolecular Science and Engineering at the Naval Research Laboratory. He is author of more than 150 scientific publications on ultrathin films, biomaterials, clay nanocomposites, and nanocapsules for sustained drug release. Professor Yuri Lvov was among the pioneers of the layer-by-layer nanoassembly technique based on alternate adsorption of oppositely charged components with more than 4000 citations of these works.

Preface
Contributors
An Introduction to Bio-nanohybrid Materials
Introduction: The Assembly of Biological Species to Inorganic Solids
Bio-nanohybrids Based on Silica Particles and Siloxane Networks
Calcium Phosphates and Carbonates in Bioinspired and Biomimetic Materials
Clay Minerals and Organoclay Bio-nanocomposites
Bio-Nanohybrids Based on Metal and Metal Oxide Nanoparticles
Carbon-based Bio-nanohybrids
Bio-nanohybrids Based on Layered Transition Metal Solids
Trends and Perspectives
References
Biomimetic Nanohybrids Based on Organosiloxane Units
Introduction
Monolayer on Solid Support
Layered Alkylsiloxane
Organic–Inorganic Hybrid Vesicle Cerasome
Mesoporous Silica Prepared by the Lizard Template Method
Future Perspectives
References
Entrapment of Biopolymers into Sol–Gel-derived Silica Nanonocomposites
Introduction
Sol–Gel Processes
Biocompatible Approaches
One-Stage Approach Based on a Silica Precursor with Ethylene Glycol Residues
Perspectives
References
Immobilization of Biomolecules on Mesoporous Structured Materials
Introduction
Immobilization of Protein on Mesoporous Silica
Immobilization of Protein on Mesoporous Carbon and Related Materials
Immobilization of Other Biopolymers on Mesoporous Materials
Immobilization of Small Biomolecules on Mesoporous Materials
Advanced Functions of Nanohybrids of Biomolecules and Mesoporous Materials
Future Perspectives
References
Bio-controlled Growth of Oxides and Metallic Nanoparticles
Introduction
Biomimetic Approaches
In vitro Synthesis of Hybrid Nanomaterials
Perspectives: Towards a Green Nanochemistry
References
Biomineralization of Hydrogels Based on Bioinspired Assemblies for Injectable Biomaterials
Introduction
Fundamental Concept of Bioinspired Approach
Alternate Soaking Process for Biomineralization and their Bio-functions
Electrophoresis Process for Biomineralization
Conclusions
References
Bioinspired Porous Hybrid Materials via Layer-by-Layer Assembly
Introduction
Porous Materials
LbL Assembly
LbL Assembly on MS Substrates
LbL Assembly on Macroporous Substrates
Summary and Outlook
References
Bio-inorganic Nanohybrids Based on Organoclay Self-assembly
Introduction
Synthesis and Characterization of Organically Functionalized 2:1 Magnesium Phyllosilicates
MagnesiumOrganophyllosilicates withHigher-order Organization
Intercalation of Biomolecules within Organically Modified Magnesium Phyllosilicates
Hybrid Nanostructures Based on Organoclay Wrapping of Single Biomolecules
Functional Mesolamellar Bio-inorganic Nanocomposite Films
S
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Bio-inorganic Hybrid Nanomaterials Strategies, Synthesis, Characterization and Applications

Summary

Author Biography

Table of Contents

Supplemental Materials