| Foreword |
|
xi | |
|
Professor Rafael Fernandez Rubio |
|
| Preface |
|
xv | |
|
Mining and the Water Environment |
|
|
1 | (64) |
|
Mining, society and the environment |
|
|
1 | (2) |
|
|
|
3 | (3) |
|
|
|
3 | (2) |
|
Who should read this book? |
|
|
5 | (1) |
|
|
|
5 | (1) |
|
Overview of mining and mine wastes |
|
|
6 | (48) |
|
|
|
6 | (1) |
|
|
|
7 | (22) |
|
|
|
29 | (10) |
|
|
|
39 | (3) |
|
|
|
42 | (12) |
|
Impacts of mining and mine waters on the water environment and infrastructure |
|
|
54 | (8) |
|
|
|
62 | (3) |
|
|
|
65 | (62) |
|
Sources of mine water contaminants and their natural attenuation |
|
|
65 | (11) |
|
Mineral weathering as a source of mine water contamination |
|
|
67 | (3) |
|
The weathering kinetics of pyrite and related sulfide minerals |
|
|
70 | (3) |
|
Biological and chemical methods for pollution prevention |
|
|
73 | (2) |
|
Mineral weathering as a source of natural attenuation |
|
|
75 | (1) |
|
Contaminant mobility: pH as a master variable |
|
|
76 | (1) |
|
Acidity, alkalinity and pH |
|
|
76 | (22) |
|
Strong acids and bases: defining acidity and alkalinity |
|
|
79 | (1) |
|
Weak acids: the CO2-H2O buffer system |
|
|
80 | (5) |
|
Buffering mine water quality: the relation between acidity and pH |
|
|
85 | (5) |
|
The proton condition: considering other weak acids in mine waters |
|
|
90 | (5) |
|
Vestigial and juvenile acidity |
|
|
95 | (2) |
|
The impact of biota on acidity and alkalinity |
|
|
97 | (1) |
|
Assessing contamination loads |
|
|
98 | (14) |
|
Methods for assessing the potential for contamination |
|
|
99 | (3) |
|
Mineral weathering rates: a scaling problem |
|
|
102 | (2) |
|
Relating mineral mass and weathering rates to evolution of discharge quality |
|
|
104 | (2) |
|
Assessing the longevity of contamination |
|
|
106 | (6) |
|
The geochemistry of metal ions in aquatic environments |
|
|
112 | (15) |
|
Hydrolysis and solubility of metal ions |
|
|
113 | (4) |
|
|
|
117 | (10) |
|
|
|
127 | (144) |
|
|
|
127 | (1) |
|
Issues and processes in mine water hydrology |
|
|
128 | (1) |
|
Mass continuity and hydrological fluxes |
|
|
129 | (18) |
|
Mass continuity as the core paradigm in hydrology |
|
|
129 | (1) |
|
Natural hydrological balances - the basic processes |
|
|
130 | (6) |
|
Complete descriptions of flow processes: the basis for hydrological modelling |
|
|
136 | (11) |
|
Hydrometry in mining environments |
|
|
147 | (22) |
|
|
|
147 | (1) |
|
Hydrometeorological parameters |
|
|
147 | (4) |
|
|
|
151 | (8) |
|
Measuring ground water heads |
|
|
159 | (6) |
|
Measuring ventilation water losses |
|
|
165 | (4) |
|
Physical impacts of mineral extraction on natural hydrological systems |
|
|
169 | (12) |
|
Excavation and fracturing |
|
|
169 | (1) |
|
Impacts of excavation on surface water systems |
|
|
170 | (6) |
|
Impacts of excavation on ground water systems |
|
|
176 | (5) |
|
Water inflows to active workings |
|
|
181 | (17) |
|
Seepages, drippers, feeders, inrushes and direct precipitation |
|
|
181 | (6) |
|
Water make and mine water budgets |
|
|
187 | (2) |
|
Deep mine water makes: some general observations |
|
|
189 | (4) |
|
Mining beneath water bodies |
|
|
193 | (1) |
|
Surface mine water makes: a question of stability |
|
|
194 | (4) |
|
Dewatering techniques and their design |
|
|
198 | (15) |
|
The necessity of dewatering |
|
|
198 | (1) |
|
|
|
199 | (5) |
|
|
|
204 | (2) |
|
|
|
206 | (5) |
|
Geotechnical alternatives/aids to dewatering |
|
|
211 | (2) |
|
Environmental impacts of dewatering and their mitigation |
|
|
213 | (5) |
|
|
|
213 | (3) |
|
|
|
216 | (2) |
|
Hydrological behaviour of waste rock piles, backfill and tailings dams |
|
|
218 | (12) |
|
Waste rock piles (spoil heaps) and surface mine backfill |
|
|
218 | (8) |
|
|
|
226 | (4) |
|
Mine abandonment and rebound processes |
|
|
230 | (18) |
|
Understanding mine water rebound: ponds and head-dependent inflows |
|
|
230 | (9) |
|
Predictive modelling of mine water rebound |
|
|
239 | (9) |
|
Abandoned mine hydrology after rebound is complete |
|
|
248 | (12) |
|
Abandoned surface mines: pit lakes |
|
|
248 | (5) |
|
|
|
253 | (1) |
|
The environmental impacts of abandoned mine discharges |
|
|
254 | (3) |
|
The longevity of pollution from abandoned mines |
|
|
257 | (3) |
|
Hydrological interventions in mine water remediation |
|
|
260 | (11) |
|
|
|
260 | (1) |
|
Passive prevention of pollutant release |
|
|
260 | (8) |
|
Use of pumps in mine water control |
|
|
268 | (3) |
|
Active Treatment of Polluted Mine Waters |
|
|
271 | (40) |
|
What is active treatment? |
|
|
271 | (3) |
|
Oxidation, dosing with alkali and sedimentation (ODAS) |
|
|
274 | (21) |
|
|
|
274 | (1) |
|
|
|
274 | (1) |
|
Purpose of oxidation in mine water treatment |
|
|
274 | (1) |
|
|
|
275 | (1) |
|
|
|
275 | (1) |
|
|
|
275 | (2) |
|
|
|
277 | (1) |
|
Biochemical oxidation by RBC |
|
|
278 | (1) |
|
|
|
278 | (1) |
|
|
|
279 | (1) |
|
Rationale for dosing with alkali |
|
|
279 | (1) |
|
Pre-aeration to strip excess CO2 before alkali addition |
|
|
279 | (1) |
|
Alkaline reagents for mine water dosing |
|
|
280 | (3) |
|
Quantities of alkali needed for dosing |
|
|
283 | (3) |
|
|
|
286 | (1) |
|
Sedimentation to remove inert solids from suspension |
|
|
286 | (1) |
|
Sedimentation for removal of iron and other metals |
|
|
287 | (3) |
|
Further considerations in sedimentation basin design |
|
|
290 | (1) |
|
Limitations of the conventional ODAS approach |
|
|
291 | (1) |
|
Advanced ODAS methodologies |
|
|
292 | (3) |
|
Sulfidization and biodesalination |
|
|
295 | (4) |
|
Principles of active sulfate reduction technology |
|
|
295 | (1) |
|
Varieties of sulfidization technology |
|
|
295 | (1) |
|
|
|
296 | (3) |
|
Sorption and ion exchange |
|
|
299 | (1) |
|
|
|
300 | (1) |
|
Other active treatment processes |
|
|
300 | (2) |
|
Sludge Management - A Key Issue in Mine Water Treatment |
|
|
302 | (9) |
|
Sludge - a resource or a waste product? |
|
|
302 | (1) |
|
Waste sludges arising from mine water treatment |
|
|
303 | (1) |
|
|
|
303 | (1) |
|
Increasing sludge density |
|
|
304 | (7) |
|
Passive Treatment of Polluted Mine Waters |
|
|
311 | (86) |
|
What is passive treatment? |
|
|
311 | (3) |
|
A brief history of passive mine water treatment |
|
|
314 | (1) |
|
Chemical and microbial basis for passive treatment |
|
|
315 | (18) |
|
|
|
315 | (1) |
|
Removal of Fe in passive systems |
|
|
316 | (4) |
|
Removal of Al3+ in passive systems |
|
|
320 | (1) |
|
Removal of manganese in passive systems |
|
|
321 | (1) |
|
Generation of alkalinity in passive treatment systems |
|
|
322 | (2) |
|
Interaction of metal removal and acid neutralization processes |
|
|
324 | (2) |
|
Removal processes for other contaminants |
|
|
326 | (1) |
|
Rates of contaminant removal in passive systems: towards design criteria |
|
|
327 | (6) |
|
Passive treatment technologies |
|
|
333 | (50) |
|
A typology of passive mine water treatment systems |
|
|
333 | (1) |
|
Inorganic media passive systems (IMPs) |
|
|
334 | (1) |
|
|
|
334 | (1) |
|
Anoxic Limestone Drains (ALDs) |
|
|
335 | (5) |
|
Oxic limestone drains (OLDs) and open-channel limestone reactors (OCLRs) |
|
|
340 | (3) |
|
Carbonate-based reactors for removal of Mn, Zn, Cd and As |
|
|
343 | (1) |
|
|
|
344 | (5) |
|
Wetland-type passive systems |
|
|
349 | (1) |
|
|
|
349 | (1) |
|
|
|
350 | (1) |
|
Aerobic Wetlands (Reed beds) |
|
|
350 | (15) |
|
|
|
365 | (5) |
|
Reducing and alkalinity producing systems (RAPS) |
|
|
370 | (5) |
|
Subsurface-flow bacterial sulfate reduction systems (SFBs) |
|
|
375 | (1) |
|
In situ permeable reactive barriers (PRBs) |
|
|
375 | (6) |
|
Anaerobic reactors for surface mine water discharges |
|
|
381 | (2) |
|
Passive treatment process selection and staging |
|
|
383 | (14) |
|
|
|
383 | (2) |
|
Illustrative case studies |
|
|
385 | (1) |
|
Aerobic wetland treatment of a net-alkaline water contaminated with Fe |
|
|
385 | (2) |
|
Compost wetland treatment of an acidic, Al-rich waste rock pile leachate |
|
|
387 | (6) |
|
Use of RAPS and wetlands to treat an acidic discharge rich in Fe and Al |
|
|
393 | (4) |
| Appendix I Glossary of mining and related terms relevant to mine water science and engineering |
|
397 | (12) |
| References |
|
409 | (26) |
| Index |
|
435 | |