| Preface |
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ix | |
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1 | (10) |
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A personal look at the history of aqueous organometallic catalysis |
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1 | (4) |
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General characteristics of aqueous organometallic catalysis |
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5 | (6) |
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9 | (2) |
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Ligands used for aqueous organometallic catalysis |
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11 | (36) |
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Tertiary phosphine ligands with sulfonate or alkylene sulfate substituents |
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12 | (9) |
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13 | (3) |
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Nucleophilic phosphinations, Grignard-reactions and catalytic cross-coupling for preparation of sulfonated phosphines |
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16 | (4) |
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20 | (1) |
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Tertiary phosphine ligands with nitrogen-containing substituents |
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21 | (3) |
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Phosphine ligands with carboxyl substituents |
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24 | (1) |
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Hydroxyl-substituted water-soluble tertiary phosphines |
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25 | (2) |
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Macroligands in aqueous organometallic catalysis |
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27 | (5) |
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Bis[2-(diphenylphosphino)ethyl]amine - a versatile starting material for chelating bisphosphines |
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32 | (1) |
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Tertiary phosphines with phosphonate and phosphonium substituents |
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32 | (1) |
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Water-soluble ligands for aqueous organometallic catalysis - latest developments |
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32 | (7) |
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Solubilities of tertiary phosphines and their complexes in water |
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39 | (8) |
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40 | (7) |
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47 | (102) |
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49 | (31) |
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Catalysts with simple ions as ligands |
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49 | (1) |
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Ruthenium salts as hydrogenation catalysts |
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49 | (1) |
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Hydridopentacyanocobaltate(III) |
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50 | (1) |
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Water-soluble hydrogenation catalysts other than simple complex ions |
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51 | (1) |
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Catalysts containing phosphine ligands |
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51 | (7) |
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Hydrogenation of olefins with miscellaneous water-soluble catalysts without phosphine ligands |
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58 | (1) |
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Mechanistic features of hydrogenation of olefins in aqueous systems |
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58 | (8) |
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Water-soluble hydrogenation catalysts with macromolecular ligands |
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66 | (1) |
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Enantioselective hydrogenations of prochiral olefins |
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67 | (8) |
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Effect of amphiphiles on the enantioselective hydrogenation of prochiral olefins in water |
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75 | (5) |
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Hydrogenation of arenes and heteroarenes in aqueous systems |
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80 | (7) |
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Hydrogenation of aldehydes and ketones |
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87 | (11) |
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Hydrogenation of miscellaneous organic substrates |
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98 | (4) |
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Hydrogenation of nitro compounds and imines |
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98 | (4) |
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Transfer hydrogenation and hydrogenolysis |
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102 | (11) |
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Hydrogenation of carbon dioxide in aqueous solution |
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113 | (9) |
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Hydrogenations of biological interest |
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122 | (9) |
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Hydrogenation of biological membranes |
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122 | (5) |
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Regeneration of dihydronicotinamide cofactors |
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127 | (4) |
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The water gas shift reaction and hydrogenations with CO-H2O mixtures |
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131 | (18) |
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The water gas shift reaction |
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131 | (4) |
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Hydrogenations with CO + H2O |
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135 | (3) |
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138 | (11) |
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149 | (42) |
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149 | (3) |
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Rhodium-catalyzed biphasic hydroformylation of olefins. The Ruhrchemie-Rhone Poulenc process for manufacturing butyraldehyde |
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152 | (4) |
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Aqueous/organic biphasic hydroformylation butenes and other alkenes |
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156 | (1) |
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Basic research in aqueous organometallic hydroformylation; ligands and catalysts |
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157 | (4) |
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Mechanistic considerations |
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161 | (5) |
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161 | (3) |
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164 | (2) |
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Asymmetric hydroformylation in aqueous media |
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166 | (1) |
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Surfactants in aqueous hydroformylation |
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167 | (5) |
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Water soluble polymeric ligands in aqueous hydroformylation |
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172 | (4) |
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Aqueous extractions for efficient catalyst recovery |
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176 | (3) |
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179 | (5) |
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Miscellaneous aspects of aqueous-organic biphasic hydroformylation |
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184 | (7) |
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Interphase engineering using ``promoter ligands'' |
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184 | (1) |
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Gas-liquid-liquid reaction engineering |
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185 | (1) |
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185 | (6) |
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191 | (18) |
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191 | (1) |
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Carbonylation of organic halides |
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192 | (5) |
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Carbonylation of methane, alkenes and alkynes |
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197 | (5) |
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Carbonylation of alcohols |
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202 | (7) |
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205 | (4) |
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Carbon-carbon bond formation |
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209 | (28) |
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210 | (4) |
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Suzuki couplings in aqueous media |
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214 | (4) |
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Sonogashira couplings in aqueous media |
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218 | (3) |
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Allylic alkylations in aqueous media |
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221 | (4) |
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Catalytic removal of allylic protecting groups |
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225 | (2) |
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Stille couplings in aqueous media |
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227 | (3) |
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Other catalytic C-C bond formations |
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230 | (7) |
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230 | (3) |
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Nucleophilic additions to 1,3-dienes; the synthesis of geranylacetone |
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233 | (1) |
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234 | (3) |
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Dimerization, oligomerization and polymerization of alkenes and alkynes |
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237 | (20) |
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Dimerization and polymerization of ethylene |
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237 | (2) |
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239 | (4) |
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Ring-opening metathesis polymerizations in aqueous media |
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243 | (4) |
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247 | (3) |
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Alternating copolymerization of alkenes and carbon monoxide |
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250 | (7) |
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253 | (4) |
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Catalytic oxidations in aqueous media - recent developments |
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257 | (8) |
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257 | (3) |
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Oxidations with O2 and H2O2 |
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260 | (5) |
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262 | (3) |
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Miscellaneous catalytic reactions in aqueous media |
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265 | (14) |
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Aqueous organometallic catalysis under traditional conditions |
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265 | (9) |
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274 | (5) |
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275 | (4) |
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Host-guest chemistry in aqueous organometallic catalysis |
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279 | (12) |
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Cyclodextrins and the formation of inclusion compounds |
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279 | (2) |
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Application of cyclodextrins and other host molecules in aqueous organometallic catalysis |
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281 | (10) |
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289 | (2) |
| Index |
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291 | (7) |
| Key to the abbreviations |
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298 | |
