Calixarenes for Separations

This book is a complete examination of the benefits and uses of calixarenes to provide frameworks for arranging binding functionalities in spatial arrangements that are ideal for binding specific substrates. These selective bindings are used as the basis for chemical separations, and calixarenes can be used for binding both cationic and anionic substrates, making this book a useful addition to any chemist's library.

Preface

xi

General

Calixarenes for Separations

2

(10)

C. David Gutsche

Calixarene-Cation Complexation

Extraction of Cesium by Calix[4]arene-crown-6: From Synthesis to Process

12

(14)

J.-F. Dozol

V. Lamare

N. Simon

R. Ungaro

A. Casnati

Development of Process Chemistry for the Removal of Cesium from Acidic Nuclear Waste by Calix[4]arene-crown-6 Ethers

26

(19)

Peter V. Bonnesen

Tamara J. Haverlock

Nancy L. Engle

Richard A. Sachleben

Bruce A. Moyer

Radiation Stability of Calixarene-Based Solvent System

45

(11)

R. A. Peterson

C. L. Crawford

F. F. Fondeur

T. L. White

Behavior of Calix[4]arene-bis-crown-6 under Irradiation: Electrospray-Mass Spectrometry Investigation and Molecular Dynamics Simulations on Cs+ and Na+ Complexes of a Degradation Compound

56

(15)

V. Lamare

J.-F. Dozol

F. Allain

H. Virelizier

C. Moulin

C. Jankowski

J.-C. Tabet

Interfacial Features of Assisted Liquid-Liquid Extraction of Uranyl and Cesium Salts: A Molecular Dynamics Investigation

71

(15)

M. Baaden

F. Berny

N. Muzet

L. Troxler

G. Wipff

Benzyl Phenol Derivatives: Extraction Properties of Calixarene Fragments

86

(21)

Laetitia H. Delmau

Jeffrey C. Bryan

Benjamin P. Hay

Nancy L. Engle

Richard A. Sachleben

Bruce A. Moyer

Calixarene-Containing Extraction Mixture for the Combined Extraction of Cs, Sr, Pu, and Am from Alkaline Radioactive Wastes

107

(5)

Igor V. Smirnov

Andrey Yu. Shadrin

Vasily A. Babain

Mikhail V. Logunov

Marina K. Chmutova

Vitaly I. Kal'tchenko

Calix[4]arenes with a Novel Proton-Ionizable Group: Synthesis and Metal Ion Separations

112

(13)

Richard A. Bartsch

Hong-Sik Hwang

Vladimir S. Talanov

Chunkyung Park

Galina G. Talanova

Separations of Soft Heavy-Metal Cations by Lower Rim-Functionalized Calix[4]arenes

125

(10)

Galina G. Talanova

Vladimir S. Talanov

Hong-Sik Hwang

Nazar S. A. Elkarim

Richard A. Bartsch

CMPO-Substituted Calixarenes

135

(15)

Volker Bohmer

Binding of Lanthanides(III) and Thorium(IV) by Phosphorylated Calixarenes

150

(15)

F. Arnaud-Neu

S. Barboso

D. Byrne

L. J. Charbonniere

M. J. Schwing-Weill

G. Ulrich

Lanthanide Calix[4]arene Complexes Investigated by NMR

165

(14)

B. Lambert

V. Jacques

J. F. Desreux

Bimetallic Lanthanide Supramolecular Edifices with Calixarenes

179

(16)

Jean-Claude G. Bunzli

Frederic Besancon

Frederic Ihringer

Molecular Recognition by Azacalix[3]arenes

195

(13)

Philip D. Hampton

Si Wu

Panadda Chirakul

Zsolt Bencze

Eileen N. Duesler

Metal Ion Complexation and Extraction Behavior of Some Acyclic Analogs of tert-Butyl-calix[4]arene Hydroxamate Extractants

208

(15)

Timothy N. Lambert

Matthew D. Tallant

Gordon D. Jarvinen

Aravamudan S. Gopalan

Calixarenes as Ligands in Environmentally-Benign Liquid-Liquid Extraction Media: Aqueous Biphasic Systems and Room Temperature Ionic Liquids

223

(15)

Ann E. Visser

Richard P. Swatloski

Deborah H. Hartman

Jonathan G. Huddleston

Robin D. Rogers

Calixarene-Anion Complexation

Calix[4]pyrrole-Functionalized Silica Gels: Novel Supports for the HPLC-Based Separation of Anions

238

(17)

Jonathan L. Sessler

John W. Genge

Philip A. Gale

Vladimir Kral

Lower Rim Amide- and Amine-Substituted Calix[4]arenes as Phase Transfer Extractants for Oxyions between an Aqueous and an Organic Phase

255

(15)

H. Fred Koch

D. Max Roundhill

Calixarene Complexation of Neutral Molecules

Deep Cavities and Capsules

270

(13)

Dmitry M. Rudkevich

Julius Rebek, Jr.

Calixarene Metalloreceptors: Demonstration of Size and Shape Selectivity Inside a Calixarene Cavity

283

(13)

Stephen J. Loeb

Beth R. Cameron

Synthesis and Structural Analysis of Thiacalixarene Derivatives

296

(17)

Mir Wais Hosseini

Synthesis and Fullerene Complexation Studies of p-Allylcalix[5]arenes

313

(12)

Charles G. Gibbs

Jian-she Wang

C. David Gutsche

Hydrogen-Bonded Cavities Based upon Resorcin[4]arenes by Design

325

(16)

Leonard R. MacGillivray

Jerry L. Atwood

Author Index

341

(1)

Subject Index

342

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Calixarenes for Separations

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Table of Contents

Supplemental Materials