Controlled/Living Radical Polymerization Progress in ATRP, NMP and RAFT

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ISBN: 9780841237070 | 0841237077
Cover: Hardcover
Copyright: 7/20/2000

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This book examines recent progress in controlled/living radical polymerization. The volume focuses on three synthetic methods: atom transfer radical polymerization, nitroxide mediated polymerization and degenerative transfer via addition fragmentation. In addition, the volume covers the preparation and characterization of many never before seen materials using ATRP, NMP and RAFT.

Preface

Advances in Conventional and Controlled Radical Polymerization

Comparison and Classification of Controlled/Living Radical Polymerizations

(25)

Krzysztof Matyjaszewski

Kinetics of Living Radical Polymerization

(12)

Takeshi Fukuda

Atsushi Goto

Initiation and Termination Rates Associated with Free-Radical Polymerization in Extended Ranges of Temperature and Pressure

(18)

Michael Buback

Stereochemistry in Radical Polymerization of Vinyl Esters

(11)

Yoshio Okamoto

Kazunobu Yamada

Tamaki Nakano

Electron Paramagnetic Resonance Study of Conventional and Controlled Radical Polymerizations

(14)

Atsushi Kajiwara

Krzysztof Matyjaszewski

Mikiharu Kamachi

Models for Free-Radical Copolymerization Propagation Kinetics

(11)

Michelle L. Coote

Thomas P. Davis

Leo Radom

Topochemical Polymerization of Diene Monomers in the Crystalline State to Control the Stereochemistry of the Polymers

(15)

Akikazu Matsumoto

Toru Odani

Nitroxide-Mediated Polymerization

Use of Phosphonylated Nitroxides and Alkoxyamines in Controlled/``Living'' Radical Polymerization

108

(15)

C. Le Mercier

J.-F. Lutz

S. Marque

F. Le Moigne

P. Tordo

P. Lacroix-Desmazes

B. Boutevin

J.-L. Couturier

O. Guerret

R. Martschke

J. Sobek

H. Fischer

Progress Toward a Universal Initiator for Nitroxide Mediated `Living' Free Radical Procedures

123

(15)

Didier Benoit

Eva Harth

Brett Helms

Ian Rees

Robert Vestberg

Marlene Rodlert

Craig J. Hawker

Nitroxide-Mediated Controlled Free-Radical Emulsion and Miniemulsion Polymerizations of Styrene

138

(14)

M. Lansalot

C. Farcet

B. Charleux

J.-P. Vairon

R. Pirri

P. Tordo

Triazolinyl Radicals: Toward a New Mechanism in Controlled Radical Polymerization

152

(16)

Markus Klapper

Thorsten Brand

Marco Steenbock

Klaus Mullen

Atom Transfer Radical Polymerization

Living Radical Polymerization of Styrene: RuCl2(PPh3)3 and Alkyl Iodide-Based Initiating Systems

168

(14)

Yuzo Kotani

Masami Kamigaito

Mitsuo Sawamoto

Copper-Mediated Living Radical Polymerization Utilizing Biological and End Group Modified Poly(ethylene-co-butylene) Macroinitiators

182

(15)

David M. Haddleton

Adam P. Jarvis

Carl Waterson

Stefan A. F. Bon

Alex M. Heming

Atom Transfer Radical Copolymerization of Styrene and Butyl Acrylate

197

(14)

Gregory Chambard

Bert Klumperman

The Copper Catalyst in Atom Transfer Radical Polymerizations: Structural Observations

211

(12)

Guido Kickelbick

Ulrich Reinohl

Teja S. Ertel

Helmut Bertagnolli

Krzysztof Matyjaszewski

Atom Transfer Radical Polymerization Mediated by Ruthenium(II)-Arene Complexes

223

(11)

Francois Simal

Dominique Jan

Albert Demonceau

Alfred F. Noels

Polychloroalkanes as ATRP Initiators: Fundamentals and Application to the Synthesis of Block Copolymers from the Combination of Conventional Radical Polymerization and ATRP

234

(14)

M. Destarac

B. Boutevin

Krzysztof Matyjaszewski

Controlled Radical Polymerization Utilizing Preformed Metal Complexes Based on Substituted Bipyridines and Terpyridines

248

(15)

U. S. Schubert

G. Hochwimmer

C. E. Spindler

O. Nuyken

Reverse Atom Transfer Radical Polymerization Using AIBN or BPO as Initiator

263

(15)

Wenxin Wang

Deyue Yan

Other Methods for Controlled Radical Polymerization

Synthesis of Defined Polymers by Reversible Addition-Fragmentation Chain Transfer: The RAFT Process

278

(19)

Ezio Rizzardo

John Chiefari

Roshan T. A. Mayadunne

Graeme Moad

San H. Thang

Preparation of Macromonomers via Chain Transfer with and without Added Chain Transfer Agent

297

(16)

John Chiefari

Justine Jeffery

Roshan T. A. Mayadunne

Graeme Moad

Ezio Rizzardo

San H. Thang

End-Group Control in Catalytic Chain Transfer Polymerization

313

(21)

Johan P. A. Heuts

David A. Morrison

Thomas P. Davis

New Materials by Controlled Radical Polymerization

Synthesis of Polystyrene-Polyacrylate Block Copolymers by Nitroxide-Mediated Radical Polymerization

334

(13)

Sophie Robin

Yves Gnanou

Functionalized Polymers by Atom Transfer Radical Polymerization

347

(14)

Scott G. Gaynor

Krzysztof Matyjaszewski

Copolymerization of n-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers by Conventional and Atom Transfer Radical Copolymerization

361

(11)

Sebastian G. Roos

Axel H. E. Muller

Krzysztof Matyjaszewski

Quantitative Derivatizations of 1-Chloro-1-phenylethyl Chain End of Polystyrene Obtained by Quasiliving Atom Transfer Radical Polymerization

372

(12)

Bela Ivan

Tamas Fonagy

Synthesis of Alternating Copolymers of N-Substituted Maleimides with Styrene via Atom Transfer Radical Polymerization

384

(10)

Fu-Mian Li

Guang-Qiang Chen

Ming-Qiang Zhu

Peng Zhou

Fu-Sheng Du

Zi-Chen Li

Controlled Radical Copolymerization of Styrene and Acrylonitrile

394

(14)

S. Brinkmann-Rengel

N. Niessner

Synthesis of Oligomers by Stable Free Radical Polymerization of Acrylates, Methacrylates, and Styrene with Alkoxyamine Initiators

408

(19)

Helmut Keul

Dirk Achten

Birte Reining

Hartwig Hocker

Potential Impact of Controlled Radical Polymerization on Markets for Polymeric Materials

427

(18)

James Spanswick

Elizabeth A. Branstetter

William F. Huber, Jr.

Indexes

Author Index

443

(2)

Subject Index

445

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Controlled/Living Radical Polymerization Progress in ATRP, NMP and RAFT

Summary

Table of Contents

Supplemental Materials