Corrosion Resistance of Steels Against Lyes

This must-have reference for all chemical engineers, material scientists and chemists working with steel or acidic media explains how to strengthen the corrosion resistance of steels as reaction, transport and storage devices against lyes (hydroxides) and organic acids.

The handbook contains comprehensive information, including tabulated data and references, on the corrosion properties of the following materials:

Unalloyed steels and cast steel
Unalloyed cast iron
High-alloy cast iron
High-silicon cast iron
Structural steels with up to 12% chromium
Ferritic chromium steels with more than 12% chromium
Ferritic-austenitic steels with more than 12% chromium
High-alloy multiphase steels
Ferritic/perlitic-martensitic steels
Ferritic-austenitic steels/duplex steels
Austenitic chromium-nickel steels
Austenitic chromium-nickel-molybdenum steels
Austenitic chromium-nickel steels with special alloying additions
Special iron-based alloys

The following corrosive media are considered:

Acetic Acid
Alkanecarboxylic Acids
Carbonic Acid
Formic Acid
Sulfonic Acids
Alkaline Earth Hydroxides
Ammonia and Ammonium Hydroxide
Lithium Hydroxide
Potassium Hydroxide
Sodium Hydroxide

Michael Schütze, born in 1952, studied materials sciences at the University of Erlangen-Nuremberg from 1972 to 1978, and then joined the Karl Winnacker Institute of DECHEMA as a research associate. He received his doctorate in engineering sciences from the Technical University of Aachen (RWTH) in 1983, and his lecturing qualification in 1991, becoming a member of the external teaching staff of the RWTH, where he has held a professorship since 1998 and has been director of the Karl Winnacker Institute since 1996. He is a recipient of the Friedrich Wilhelm Prize, the Rahmel Schwenk Medal and the Cavallaro Medal, a past chairman of the Gordon Research Conference on Corrosion, editor of the journal Materials and Corrosion, past president of the European Federation of Corrosion, and of the World Corrosion Organization, as well as chairman of the Working Party Corrosion by Hot Gases and Combustion Products of the European Federation of Corrosion.

Thomas L. Ladwein, born in 1955, studied chemistry and metallurgy at the Universities of Saarbrücken and Münster, and graduated with a Diploma in Chemistry in 1980 and a PhD in Sciences in 1984. After that he worked as a R&D and application engineer for a chemical fabricator specialized in refractory metals. In 1987 he joined the stainless steel divison of Thyssen AG (later ThyssenKrupp AG) and worked there in several positions in R&D, application engineering and technical marketing. Since 2003 he is full time professor for electrochemistry, corrosion and tribology at Aalen University of Applied Science. He works in various committees and working parties of DECHEMA, GfKORR (German Corrosion Society), VDEh (German Iron and Steel Institute) and NACE International. He is current chair of the NACE committee "STG 39: Process Industries - Materials Applications and Experiences" and chairman of the NACE European Area. In 2011 he received the Herbert H. Uhlig Award from NACE International.

Roman Bender, born in 1971, studied chemistry at the Justus Liebig University of Giessen from 1992 to 1997. He received his doctorate in natural sciences from the Technical University of Aachen (RWTH Aachen) in 2001. After receiving his diploma he joined the Karl Winnacker Institute of the DECHEMA in Frankfurt (Main) as a research associate, where he has been head of the materials and corrosion group since 2000, and editor-in-chief of the world's largest corrosion data collection, the DECHEMA Werkstofftabelle and the Corrosion Handbook. In 2008 Dr. Bender was appointed CEO of the GfKORR - the Society for Corrosion Protection.

Preface IX

How to use the Handbook XI

Warranty disclaimer 1

Acetic Acid 3

Unalloyed steels and cast steel 3

Unalloyed cast iron 12

High-alloy cast iron, high-silicon cast iron 13

Structural steels with up to 12% chromium 19

Ferritic chromium steels with more than 12% chromium 19

Ferritic-austenitic steels with more than 12% chromium 19

Austenitic chromium-nickel steels 32

Austenitic chromium-nickel-molybdenum steels 51

Austenitic chromium-nickel steels with special alloying additions 68

Special iron-based alloys 73

Bibliography 77

Alkanecarboxylic Acids 95

Unalloyed steels and cast steel 95

Unalloyed cast iron 95

Austenitic chromium-nickel-molybdenum steels 100

Austenitic chromium-nickel steels with special alloying additions 100

Special iron-based alloys 100

High-alloy cast iron, high-silicon cast iron 101

Structural steels with up to 12% chromium 102

Ferritic chromium steels with more than 12% chromium 103

Ferritic-austenitic steels with more than 12% chromium 103

Austenitic chromium-nickel steels 104

Austenitic chromium-nickel-molybdenum steels 107

Austenitic chromium-nickel steels with special alloying additions 107

Special iron-based alloys 107

Bibliography 116

Carbonic Acid 119

Unalloyed and low-alloy steels/cast steel 119

Unalloyed cast iron and low-alloy cast iron 119

Ferritic chrome steels with < 13% Cr 146

Ferritic chromium steels with ≥ 13% Cr 147

High-alloy multiphase steels 147

Ferritic/perlitic-martensitic steels 147

Austenitic chromium-nickel steels 151

Austenitic CrNiMo(N) steels 169

Austenitic CrNiMoCu(N) steels 169

Bibliography 172

Formic Acid 175

Unalloyed steels and cast steel 175

Unalloyed cast iron 175

High-alloy cast iron, high-silicon cast iron 175

Structural steels with up to 12% chromium 176

Ferritic chromium steels with more than 12% chromium 176

Ferritic-austenitic steels with more than 12% chromium 179

Austenitic chromium-nickel steels 180

Austenitic chromium-nickel-molybdenum steels 180

Austenitic chromium-nickel steels with special alloying additions 180

Special iron-based alloys 183

Bibliography 185

Sulfonic Acids 187

Unalloyed steels and cast steel 187

High-alloy cast iron, high-silicon cast iron 191

Ferritic chromium steels with more than 12% chromium 191

Austenitic chromium-nickel steels 191

Austenitic chromium-nickel-molybdenum steels 194

Austenitic chromium-nickel steels with special alloying additions 196

Bibliography 197

Alkaline Earth Hydroxides 199

Unalloyed steels and cast steel 199

Unalloyed cast iron 218

High-alloy cast iron, high-silicon cast iron 218

Structural steels with up to 12% chromium 219

Ferritic chromium steels with more than 12% chromium 219

Ferritic-austenitic steels with more than 12% chromium 219

Austenitic chromium-nickel steels 219

Austenitic chromium-nickel-molybdenum steels 219

Austenitic chromium-nickel steels with special alloying additions 219

Bibliography 220

Ammonia and Ammonium Hydroxide 223

Unalloyed and low-alloy steels/cast steel 223

Unalloyed and low-alloyed cast iron 223

Highly alloyed cast iron 244

Cast ferrosilicon 244

Austenitic cast iron (amongst others) 244

Ferritic chrome steels with < 13% Cr 244

Ferritic chrome steels with ≥ 13% Cr 244

Ferritic/perlitic-martensitic steels 244

Ferritic-austenitic steels/duplex steels 244

Austenitic chromium-nickel steels 244

Austenitic chromium-nickel-molybdenum(N) steels and CrNiMoCu(N) steels 244

Bibliography 247

Lithium Hydroxide 251

Unalloyed steels and cast steel 251

Unalloyed cast iron 257

High-alloy cast iron, high-silicon cast iron 257

Ferritic chromium steel with more than 12% chromium 257

Austenitic chromium-nickel steels 258

Austenitic chromium-nickel-molybdenum steels 258

Bibliography 261

Potassium Hydroxide 263

Unalloyed steels and low-alloy steels/cast steel 263

Unalloyed cast iron and low-alloy cast iron 269

High-alloy cast iron 269

Cast ferrosilicon 269

Austenitic cast iron (among other things) 269

Ferritic chrome steels with < 13% Cr 270

Ferritic chrome steels with ≥ 13% Cr 271

Ferritic/Perlitic-martensitic steels 271

Ferritic-austenitic steels/duplex steels 271

Austenitic chromium-nickel steels 274

Austenitic CrNiMo(N) steels and CrNiMoCu(N) steels 277

Bibliography 286

Sodium Hydroxide 293

Unalloyed and low-alloy steels/cast steel 293

Unalloyed cast iron and low-alloy cast iron 316

High-alloy cast iron 319

Silicon cast iron 319

Austenitic cast iron (etc.) 319

Ferritic chromium steels with < 13% Cr 319

Ferritic chromium steels with ≥ 13% Cr 329

High-alloy multiphase steels 334

Ferritic/perlitic-martensitic steels 334

Ferritic-austenitic steels/duplex steels 334

Austenitic chromium-nickel steels 342

Austenitic chromium-nickel-molybdenum(N) steels 349

Austenitic CrNiMoCu(N) steels 361

Special iron-based alloys 362

Bibliography 363

Key to materials compositions 371

Index of materials 411

Subject index 421

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Corrosion Resistance of Steels Against Lyes and Organic Acids

Summary

Author Biography

Table of Contents

Supplemental Materials