Hazardous Chemicals Control and Regulation in the European Market
, by Bender, Herbert F.; Eisenbarth, Philipp- ISBN: 9783527315413 | 3527315411
- Cover: Hardcover
- Copyright: 1/23/2007
Philipp Eisenbarth is a senior safety expert responsible for hazardous chemicals safety management, exposure assessment, personal protection equipment, also working for BASF. He is also a government advisor for the German ministry of economy on legislation regarding occupational safety of chemicals, and an expert on the corresponding European legislation.
Preface | p. V |
Regulations of the European Union Concerning Chemicals | p. 1 |
The European Institutions | p. 1 |
European Legislation | p. 3 |
Definitions | p. 5 |
References | p. 6 |
Toxicological Basics | p. 7 |
Incorporation Pathways | p. 7 |
Oral Incorporation | p. 9 |
Dermal Incorporation | p. 9 |
Inhalative Incorporation | p. 10 |
Metabolism | p. 11 |
Acute Effect | p. 13 |
Effect in the Case of Repeated Incorporation | p. 14 |
Sensitizing (Allergenic) Effect | p. 16 |
Toxic Properties and Developmental Defects | p. 18 |
Fertility Damage Effect | p. 21 |
Carcinogenic Effects | p. 22 |
Cancer-activating Factors | p. 23 |
Chemical Carcinogens | p. 26 |
Carcinogenic Potency | p. 27 |
Concentration | p. 27 |
Natural Carcinogens | p. 28 |
Mutagenic Properties | p. 29 |
Point Mutations | p. 29 |
Chromosome Mutations | p. 29 |
Genom Mutations | p. 31 |
Aerosols | p. 31 |
Respirable Particles "E" | p. 32 |
Alveolar Dust Parliamentary Party "A" | p. 32 |
Respirable Fibers | p. 32 |
Classification of Substances and Preparations | p. 37 |
The Dangerous Properties | p. 37 |
The Acute Toxic Properties | p. 38 |
Very Toxic Substances | p. 38 |
Toxic Substances | p. 41 |
Harmful Substances | p. 44 |
Corrosive Substances | p. 47 |
Irritant Substances | p. 49 |
Sensitization | p. 50 |
Other Toxicological Properties | p. 50 |
Special Toxicological Properties | p. 54 |
Classification Principles of the European Union | p. 54 |
Reproductive Toxicity | p. 55 |
Developmental Toxicity | p. 55 |
Impairment of Fertility | p. 53 |
Carcinogenic Property | p. 60 |
Mutagenic Property | p. 65 |
Environmental Toxicity Property | p. 67 |
Toxic to the Aquatic Environment | p. 67 |
Non-aquatic Toxic Property | p. 70 |
The Physico-chemical Properties | p. 71 |
Extremely Flammable | p. 71 |
Highly Flammable | p. 72 |
Flammable | p. 73 |
Oxidizing Property | p. 73 |
Explosive Property | p. 74 |
Additional Physical-chemical Properties | p. 75 |
Classification of Substances | p. 76 |
The Legal Classification (List Principle) | p. 76 |
Classification Following the Definition Principle | p. 78 |
Classification of Preparations | p. 78 |
Experimental Testing | p. 79 |
Conventional Method | p. 79 |
General Concentration Limits | p. 80 |
Substance-specific Concentration Limits | p. 83 |
Classification Calculation for Substances with Different Dangerous Ingredients | p. 84 |
References | p. 87 |
Duties and Obligations when Placing Products on the Market | p. 89 |
Labeling of Dangerous Substances and Preparations | p. 89 |
Labeling of Dangerous Substances | p. 90 |
Labeling of Dangerous Preparations | p. 96 |
Special Labeling | p. 96 |
Exceptions | p. 100 |
Safety Data Sheets | p. 100 |
Exceptions | p. 101 |
Headings | p. 102 |
Restrictions on Marketing | p. 112 |
Restriction Directive 76/769/EEC | p. 112 |
The Biocidal Product Directive 98/8/EC | p. 125 |
Regulation 304/2003/EC: Export and Import of Dangerous Chemicals | p. 127 |
Regulation 3677/90/EEC | p. 131 |
Regulation 2037/2000/EC | p. 131 |
POP Regulation 850/2004/EC | p. 136 |
References | p. 138 |
Notification of Substances | p. 139 |
Full Notification | p. 139 |
Base Set (Basic Set of Test Requirements) | p. 140 |
Reduced Requirements for Intermediates | p. 141 |
Additional Test Program of Level 1 | p. 142 |
Additional Test Program of Level 2 | p. 142 |
Restricted Notification and Exceptions | p. 143 |
Limited Quantities | p. 143 |
Polymers | p. 143 |
Exceptions to the Requirement for Notification | p. 144 |
Renotification of the Same Substance | p. 145 |
Follow-up Information | p. 145 |
References | p. 146 |
Occupational Safety and Health at the Workplace | p. 147 |
First European Framework Directive 80/1107/EEC on Chemical, Physical, and Biological Agents at Work and Selected Individual Directives Derived therefrom | p. 148 |
"Lead Directive" 82/605/EEC | p. 149 |
"Asbestos Directive" 83/477/EEC | p. 151 |
Directive 88/364/EEC on Banning Certain Agents | p. 153 |
Directive 91/322/EEC on Indicative Limit Values | p. 153 |
European Framework Directive 89/391/EEC on the Improvement of Safety and Health of Workers at Work, and Selected Individual Directives Derived Therefrom | p. 154 |
Work Equipment Directive 89/655/EEC | p. 156 |
Personal Protective Equipment Directive 89/656/EEC | p. 157 |
Biological Agents Directive 2000/54/EC | p. 158 |
Safety Sign Directive 92/58/EEC | p. 159 |
Explosive Atmospheres Directive 1999/92/EC | p. 164 |
"Chemical Agents" Directive 98/24/EC | p. 166 |
"Carcinogens and Mutagens" Directive 2004/37/EC | p. 181 |
Limit Values at the Workplace | p. 187 |
Indicative Occupational Exposure Limit Values (IOELV) | p. 189 |
Binding Occupational Exposure Limit Values (BOELV) | p. 197 |
Biological Limit Values (BLV) | p. 199 |
"Pregnant and Breastfeeding Women" Directive 92/85/EEC | p. 200 |
"Young People Protection" Directive 94/33/EC | p. 204 |
Personal Protective Equipment (PPE) | p. 207 |
Eye and Face Protection | p. 208 |
Safety Glasses | p. 210 |
Face Shields | p. 212 |
Gloves for Chemical Protection | p. 213 |
General Guidelines for the Use of Gloves | p. 215 |
Selection of Safety Gloves | p. 216 |
Marking of Gloves | p. 220 |
Protective Clothing | p. 223 |
Respiratory Protection | p. 226 |
Filtering Respiratory Devices | p. 230 |
Self-contained Breathing Apparatus | p. 245 |
Respiratory Devices for Self-rescue | p. 252 |
Exposure Measurements | p. 256 |
General Methodology of Exposure Measurements | p. 258 |
Evaluation of Chemicals Present at the Workplace | p. 259 |
Exposure-relevant Work Activities | p. 260 |
Measurement Plan | p. 260 |
Performing Exposure Measurements | p. 261 |
Analysis | p. 263 |
Assessment | p. 263 |
Safety Measures | p. 264 |
Continuous Exposure Control | p. 265 |
Direct-reading Measurement Techniques | p. 267 |
Tubes with Direct Indication | p. 267 |
Paper Badges with Direct Indication | p. 273 |
Electrochemical Sensors | p. 275 |
Analytical Instruments | p. 277 |
Indirect Analytical Procedures for Gases and Vapors | p. 280 |
Personal Air Sampling for Gases and Vapors (Active Sampling) | p. 280 |
Passive Sampling | p. 283 |
Determination of Solid Particles | p. 284 |
Total Dust Measurements | p. 285 |
Measurement of Fine Dust (Respirable Particles) | p. 287 |
Fiber Measurements | p. 289 |
Safe Storage of Chemicals | p. 290 |
Important Terms, Definitions, and Physical Properties of Combustible Chemicals | p. 290 |
General Principles of Safe Storage of Chemicals | p. 295 |
Rules on Mixed Storage | p. 299 |
Storage Classes | p. 299 |
Allocation of Chemicals to Storage Classes | p. 305 |
Rules for Mixed Storage | p. 305 |
References | p. 312 |
Transportation of Dangerous Goods | p. 319 |
International Transportation Legislation | p. 320 |
Shipping | p. 320 |
Aircraft | p. 320 |
Road and Rail | p. 321 |
Classification of Dangerous Goods | p. 321 |
Definitions | p. 322 |
Class 1: Explosive Substances and Articles | p. 324 |
Class 2: Gases | p. 326 |
Class 3: Flammable Liquids | p. 329 |
Class 4.1: Flammable Solids, Self-reactive Substances and Solid Desensitized Explosives | p. 330 |
Class 4.2: Substances Liable to Spontaneous Combustion | p. 332 |
Class 4.3: Substances which, in Contact with Water, Emit Flammable Gases | p. 334 |
Class 5.1: Oxidizing Substances | p. 335 |
Class 5.2: Organic Peroxides | p. 336 |
Class 6.1: Toxic Substances | p. 337 |
Class 6.2: Infectious Substances | p. 338 |
Class 7 Radioactive Material | p. 339 |
Class 8: Corrosive Substances | p. 340 |
Class 9: Miscellaneous Dangerous Substances and Articles | p. 342 |
Globally Harmonized System for the Classification and Labeling of Chemicals (GHS) | p. 343 |
Labeling | p. 344 |
Classification | p. 345 |
Explosives | p. 345 |
Flammable Gases | p. 345 |
Flammable Aerosols | p. 346 |
Oxidizing Gases | p. 346 |
Gases Under Pressure | p. 347 |
Flammable Liquids | p. 348 |
Flammable Solids | p. 348 |
Self-reactive Substances | p. 349 |
Pyrophoric Liquids | p. 350 |
Pyrophoric Solids | p. 351 |
Self heating Substances | p. 351 |
Substances which, on Contact with Water, Emit Flammable Gases | p. 352 |
Oxidizing Liquids | p. 352 |
Oxidizing Solids | p. 353 |
Organic Peroxides | p. 354 |
Corrosive to Metals | p. 355 |
Acute Toxicity | p. 356 |
Skin Corrosion/Irritation | p. 359 |
Serious Eye Damage/Eye Irritation | p. 359 |
Respiratory Sensitizer | p. 361 |
Skin Sensitizer | p. 361 |
Mutagenicity | p. 362 |
Carcinogenicity | p. 362 |
Toxic to Reproduction | p. 363 |
Target Organ Systemic Toxicity Following Single Exposure | p. 364 |
Target Organ Systemic Toxicity Following Repeated Exposure | p. 364 |
Acute Hazards to the Aquatic Environment | p. 365 |
Chronic Hazards to the Aquatic Environment | p. 367 |
References | p. 369 |
REACH | p. 371 |
Introduction | p. 371 |
Registration | p. 373 |
Pre-registration | p. 374 |
Information Requirements | p. 374 |
Chemical Safety Report | p. 376 |
Intermediates | p. 378 |
Safety Data Sheet | p. 380 |
Interaction in the Supply Chain | p. 381 |
Evaluation | p. 382 |
Authorization | p. 383 |
References | p. 384 |
Subject Index | p. 385 |
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