Ion Exchange and Solvent Extraction: A Series of Advances, Volume 16

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ISBN: 9780824754891 | 0824754891
Cover: Hardcover
Copyright: 3/1/2004

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Reflecting the sustained and diverse experimental momentum in the field of ion exchange, Volume 16 summarizes revolutionary advances on par with the consistently high-level research related by this series. This text discusses the kinetics, theoretical models, experimental results/supporting data, and applications for isothermal supersaturation, metal separation via pH-induced parametric pumping, and for ultrapure water (UPW). Topics also include the engineering of activated carbons and carbonaceous materials for removal of metal ions; hydrophobic ionizable organic compounds (HIOCs); the sorption/desorption mechanisms of organic micropollutants in water; and ion exchange process variables on perchlorate treatment.

Preface

iii

Contributors to Volume 16

xiii

Contents of Other Volumes

xiii

1. Adsorption and Ion-Exchange Properties of Engineered Activated Carbons and Carbonaceous Materials

(84)

Michael Streat, Danish J. Malik, and Basudeb Saha

I. Introduction

(3)

II. Preparation and Properties of Activated Carbon

(16)

III. Characterization of the Surface Chemical Groups in Engineered Carbons

(12)

IV. Activated Carbon Fibers and Woven Cloths

(3)

V. Sorption of Trace Metals onto Activated Carbon

(21)

VI. Summary of Metal Sorption

(1)

VII. Sorption of Herbicides on Activated Carbon and Hypercross-Linked Polymers

(20)

VIII. Summary of Herbicide Sorption on Activated Carbons and Hypercross-Linked Polymers

(1)

IX. Future Trends and Concluding Remarks

(3)

References

(4)

2. Entropy-Driven Selective Ion Exchange for Hydrophobic Ionizable Organic Compounds (HIOCs)

(34)

Ping Li and Arup K. SenGupta

I. Introduction

(2)

II. Nature of Solute-Sorbent and Solute-Solvent Interactions

(4)

III. Experimental Section

(4)

IV. Results and Discussion

(21)

V. Conclusions

116

(1)

References

117

(2)

3. Ion-Exchange Isothermal Supersaturation: Concept, Problems, and Applications

119

(92)

Dmitri N. Muraviev and Ruslan Khamkov

I. Introduction

119

(1)

II. Main Features of the IXISS Technique

120

(2)

III. Areas of Potential Application of the IXISS Effect-Wasteless Ion-Exchange Processes

122

(3)

IV. IXISS of Zwitterlyte Solutions

125

(13)

V. Aminecarboxylate Interaction of Zwitterlyte Molecules

138

(22)

VI. Application of IXISS of Amino Acids

160

(5)

VII. IXISS of Inorganic Substances

165

(14)

VIII. IXISS-Based Green Ion Exchange Technologies

179

(24)

IX. Concluding Remarks

203

(2)

References

205

(6)

4. Metal Separation by pH-Driven Parametric Pumping

211

(56)

Wolfgang H. Höll, Randall Kiefer, Cornelia Stöhr, and Christian Bartosch

I. Introduction

211

(1)

II. Basic Principles of pH-Induced Parametric Pumping

212

(4)

III. Development of pH-Induced Parametric Pumping

216

(6)

IV. Experimental Work

222

(3)

V. Application of Strongly Acidic Cation Exchangers

225

(19)

VI. Separation with Weakly Basic Anion Exchangers

244

(17)

VII. Summary and Outlook

261

(2)

List of Symbols

263

(1)

References

263

(4)

5. Selectivity Considerations in Modeling the Treatment of Perchlorate Using Ion-Exchange Processes

267

(72)

Anthony R. Tripp and Dennis A. Clifford

I. Introduction

267

(7)

II. Results and Discussion

274

(28)

III. Computer Modeling

302

(29)

IV. Process Recommendations

331

(2)

V. Summary and Conclusions

333

(3)

References

336

(3)

6. Ion-Exchange Kinetics for Ultrapure Water

339

(36)

Dennis F. Hussey and Gary L. Foutch

I. Introduction

339

(5)

II. Mass Transfer Coefficient-A Method to Evaluate Resin Effectiveness

344

(11)

III. Modeling Approach to UPW Kinetics

355

(14)

IV. Concluding Comments

369

(1)

Nomenclature

370

(2)

References

372

(3)

Index

375

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Ion Exchange and Solvent Extraction: A Series of Advances, Volume 16

Summary

Table of Contents

Supplemental Materials