Supercritical Carbon Dioxide Separations and Processes

, by Gopalan, Aravamudan S.; Wai, Chien M.; Jacobs, Hollie K.

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ISBN: 9780841238367 | 0841238367
Cover: Hardcover
Copyright: 9/11/2003

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Summary

Supplemental Materials

This book covers a broad range of topics involving supercritical carbon dioxide from theoretical studies to applications in separations, materials science and reactivity and catalysis.

Preface

Overview

1. An Introduction to Separations and Processes Using Supercritical Carbon Dioxide

(8)

Chien M. Wai, Aravamudan S. Gopalan, and Hollie K. Jacobs

Metals

2. Extraction of Uranium and Lanthanides from Their Oxides with a High-Pressure Mixture of TBP-HNO3-H2O-C02

(13)

Youichi Enokida, Ichiro Yamamoto, and Chien M. Wai

3. Supercritical Fluid Extraction of Actinides and Heavy Metals for Environmental Cleanup: A Process Development Perspective

(13)

Yuehe Lin and Neil G. Smart

4. Supercritical Fluid Extraction of Plutonium and Americium from Soil Using f3-Diketone and Tributyl Phosphate Complexants

(14)

Robert V. Fox and Bruce J. Mincher

5. Solubility and Modifications of Metal Chelates in Supercritical Carbon Dioxide

(17)

Bernd W. Wenclawiak, H. Beer, A. Ammann, and A. Wolf

6. Extracting Gold in Supercritical CO2: Fluorinated Molecular Baskets and Thiourea Ligands for Au

(13)

Jeremy D. Glennon, Josephine Treacy, Anne M. O'Keeffe, Mark O'Connell, Conor C. McSweeney, Andrew Walker, and Stephen J. Harris

7. Ligand-Assisted Extraction of Metals from Fly Ash with Supercritical CO2: A Comparison with Extraction in Aqueous and Organic Solutions

(24)

Christof Kersch, Daniela Trambitas, Geert F. Woerlee, and Geert J. Witkamp

Organics

8. Coupled Processing Options for Agricultural Materials Using Supercritical Fluid Carbon Dioxide

104

(26)

Jerry W. King

9. Supercritical Fluid Extraction of Bioactive Components from St. John's Wort (Hypericum perforatum L.) and Ginkgo biloba

130

(15)

Mari Mannila, Qingyong Lang, Chien M. Wai, Yanyan Cui, and Catharina Y.W. Ang

10. Hot Water Extraction Followed by Solid-Phase Microextraction of Active Ingredients in Rosemary: An Organic Solvent-Free Analytical Technique

145

(12)

Youxin Gan and Yu Yang

11. Cleanup of Disperse Dye Contaminated Water by Supercritical Carbon Dioxide Extraction

157

Jya-Jyun Yu and Kong-Hwa Chiu

12. Approaches to Soil Remediation with Green Procedures

112

(76)

Q. Wu, T. Yuan, and W.D. Marshall

Analytical and Modeling Methods

13. Time-Resolved Laser-Induced Fluorescence Characterization of Uranium Complexes and Processes in ScF CO2

188

(13)

R. Shane Addleman and Chien Wai

14. Solubilization Study by QCM in Liquid and Supercritical CO2 under Ultrasonar

201

(22)

Kwangheon Park, Moonsung Koh, Chunghyun Yoon, Hakwon Kim, and Hongdoo Kim

15. Uranyl Extraction by TBP from a Nitric Aqueous Solution to SC-CO2: Molecular Dynamics Simulations of Phase Demixing and Interfacial Systems

223

(22)

Rachel Schurhammer and Georges Wipff

16. Experimental Measurement and Modeling of the Vapor Liquid Equilibrium of β-Diketones with CO2

245

(14)

Chris M. Lubbers, Aaron M. Scurto, and Joan F. Brennecke

17. Thermodynamics of the Baylis-Hillman Reaction in Supercritical Carbon Dioxide

259

Anthony A. Clifford, Paul M. Rose, Katherine Lee, and Christopher M. Rayner

Novel Materials

18. Dissolving Carbohydrates in CO2: Renewable Materials as CO2-philes

210

(75)

Poovathinthodiyil Raveendran and Scott L. Wallen

19. Design and Performance of Surfactants for Carbon Dioxide

285

(24)

Julian Eastoe, Audrey Dupont, Alison Paul, David C. Steytler, and Emily Rumsey

20. Nanoparticle Formation in Rapid Expansion of Water-in Carbon Dioxide Microemulsion into Liquid Solvent

309

(15)

Mohammed J. Meziani, Pankaf Pathak, Lawrence F. Allard, and Ya-Ping Sun

21. Fine Particle Pharmaceutical Manufacturing Using Dense Carbon Dioxide Mixed with Aqueous or Alcoholic Solutions

324

(15)

Edward T.S. Huang, Hung-yi Chang, C.D. Liane, and R.E. Sievers

22. Nanocrystal Synthesis and Stabilization in Supercritical Solvents

339

(14)

Parag S. Shah, Keith P. Johnston, and Brian A. Korgel

23. Supercritical Melt Micronization Using the Particles from Gas-Saturated Solution Process

353

(17)

P. Münüklu, F. Wubbolts, Th. W. De Loos, G.J. Witkamp, and P.J. Jansens

24. Synthesis of Nanostructured Sorbent Materials Using Supercritical Fluids

370

(11)

Thomas S. Zemanian, Glen E. Fryxell, Oleksey Ustyugov, Jerome C. Birnbaum, and Yuehe Lin

25. Synthesis of Structured Polymeric Materials Using Compressed Fluid Solvents

381

(25)

A.I. Cooper, R. Butler, C.M. Davies, A.K. Hebb, K. Senoo, and C.D. Wood

Reactions in Supercritical Carbon Dioxide

26. Catalytic Hydrogenation of Olefins in Supercritical Carbon Dioxide Using Rhodium Catalysts Supported on Fluoroacrylate Copolymers

406

(13)

Roberto Flores, Zulema K. Lopez-Castillo, Aydin Akgerman, Ibrahim Kam, and John P. Fackler, Jr.

27. Hydrogenation Reactions in Supercritical CO2 Catalyzed by Metal Nanoparticles in a Water-in-Carbon Dioxide Microemulsion

419

(11)

Mariko Ohde, Hiroyuki Ohde, and Chien M. Wai

28. Hydroformylation of Olefins in Water-in-Carbon Dioxide Microemulsions

430

Xing Dong and Can Erkey

Indexes

Author Index

447

(2)

Subject Index

449

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Supercritical Carbon Dioxide Separations and Processes

Summary

Table of Contents

Supplemental Materials