Supramolecular Catalysis New Directions and

Supramolecular Catalysis

Provides a timely and detailed overview of the expanding field of supramolecular catalysis

The subdiscpline of supramolecular catalysis has expanded in recent years, benefiting from the development of homogeneous catalysis and supramolecular chemistry. Supramolecular catalysis allows chemists to design custom-tailored metal and organic catalysts by devising non-covalent interactions between the various components of the reaction.

Edited by two world-renowned researchers, Supramolecular Catalysis: New Directions and Developments summarizes the most significant developments in the dynamic, interdisciplinary field. Contributions from an international panel of more than forty experts address a broad range of topics covering both organic and metal catalysts, including emergent catalysis by self-replicating molecules, switchable catalysis using allosteric effects, supramolecular helical catalysts, and transition metal catalysis in confined spaces. This authoritative and up-to-date volume:

Covers ligand-ligand interactions, assembled multi-component catalysts, ligand-substrate interactions, and supramolecular organocatalysis and non-classical interactions
Presents recent work on supramolecular catalysis in water, supramolecular allosteric catalysis, and catalysis promoted by discrete cages, capsules, and other confined environments
Highlights current research trends and discusses the future of supramolecular catalysis
Includes full references and numerous figures, tables, and color illustrations

Supramolecular Catalysis: New Directions and Developments is essential reading for catalytic chemists, complex chemists, biochemists, polymer chemists, spectroscopists, and chemists working with organometallics.

Piet van Leeuwen is holder of the "IDEX Chaire d´Attractivité", Université de Toulouse, INSA. He has chaired and directed many activities in the field of catalysis in the Netherlands. He worked with Shell in Amsterdam for twenty six years in a wide variety of topics of homogeneous catalysis. During many years he was in charge of Shell´s fundamental efforts related to organometallic chemistry and homogeneous catalysis. In 1989 he founded the homogeneous catalysis group at the University of Amsterdam, which he directed until 2007.
His interest ranges from fundamental aspects to applied catalysis utilizing mainly late transition metals. New concepts to which he contributed include host-guest catalysis, dendrimer catalysis, effects of wide bite-angles, and in-situ spectroscopy. Main research areas are ligand effects in hydroformylation, carbonylation reactions, carbon-carbon bond formation reactions, microflow reactor systems for homogeneous catalysis, and e-learning. He has (co)authored more than 400 publications, about 35 patents, and is (co)author (co)editor of 9 books, of which stands out his popular textbook Homogeneous Catalysis; understanding the art. He has (co)supervised almost 50 PhD theses.

Matthieu Raynal got his engineering diploma from ENSIACET (Toulouse) and then moved to Université de Strasbourg to get his PhD degree under the supervision of Dr Pierre Braunstein in 2009. He conducted postdoctoral studies at the Université Pierre et Marie Curie (UPMC, Paris, France) and in the group of Prof. Piet W. N. M. van Leeuwen at the Institute of Chemical Research of Catalonia (ICIQ, Tarragona, Spain). In 2012, he was appointed as a CNRS researcher in the group of L. Bouteiller (Sorbonne Université). He is fascinated by how non-covalent interactions can be designed to control the outcome of a catalytic reaction, i.e. supramolecular catalysis. His current interests concern the development of supramolecular helical catalysts with particular efforts devoted to exalt their chirality amplification and switchable properties, the design of functional chiral assemblies and the better understanding of the structure-property relationship of supramolecular polymers.

Preface

Introduction

Ligand-Ligand Interactions

Supramolecular Construction of Bidentate Ligands through Self-assembly by Hydrogen Bonding

Self-Assembled bidentate ligands in transition metal catalysis; from fundamental invention to commercial application

Self-Assembled Nanostructures and Multi-Component Assemblies

Assembled Ionic Molecular Catalysts and Ligands

Self-Amplification of Enantioselectivity in Asymmetric Catalysis by Supramolecular Recognition and Stereodynamics

Interlocked Molecules in Asymmetric Catalysis

Catalytic Supramolecular Gels

Supramolecular helical catalysts

Self-Assembled multi-component supramolecular catalysts for asymmetric reactions

Ligand-Substrate Interactions

Harnessing non-covalent interactions for control of site-selectivity in transition metal-catalyzed C-H activation and cross-coupling

Supramolecular interactions in distal C-H activation of (hetero)arenes

Transition metal-catalyzed, site- and enantioselective oxygen and nitrogen transfer enabled by lactam hydrogen bonds

Supramolecular substrate orientation as strategy to control selectivity in transition metal catalysis

Phosphine Ligands with Acylguanidinium Groups as Substrate-directing Unit

Chemical reactions controlled by remote Zn…N interactions between substrates and catalysts

Catalysis Promoted By Discrete Cages, Capsules and Other Confined Environments

Artificial Enzymes Created Through Molecular Imprinting of Cross-Linked Micelles

Bioinspired catalysis using innately polarized Pd2L4 coordination cages

Supramolecular catalysis with a cubic coordination cage: contributions from cavity and external-surface binding

Transition metal catalysis in confined spaces

Catalysis by Metal Organic Cages: A Computational Perspective

N-heterocyclic carbene (NHC)-capped Cyclodextrins for cavity-controlled catalysis

Supramolecular Catalysis by Metallohosts Based on Glycoluril

Catalysis inside the hexameric resorcinare capsule: Towards addressing current challenges in synthetic organic chemistry

Supramolecular Organocatalysis Within the Nanospace of Resorcinarene Capsule

Resorcin[4]arene hexamer: from nanocontainer to nanocatalyst

Supramolecular Organocatalysis and Non-Classical Interactions

The Aryl-Pyrrolidine-tert-Leucine Motif as a New Privileged Chiral Scaffold: The Role of Non-Covalent Stabilizing Interactions

Chiral Triazole Foldamers in Enantioselective Anion-Binding Catalysis

Supramolecular Catalysis via Organic Solids: Templates to Mechanochemistry to Cascades

Exploration of halogen bonding for the catalysis of organic reactions

Chalcogen-Bonding Catalysis

Asymmetric Supramolecular Organocatalysis: the Fourth Pillar of Catalysis

Supramolecular Catalysis In Water

Metal Catalysis in Micellar Media

Surfactant assemblies as nanoreactors for organic transformations

Compartmentalized polymers for catalysis in aqueous media

Phosphines modified by cyclodextrins for supramolecular catalysis in water

Water-Soluble Yoctoliter Reaction Flasks

Chemical catalyst-promoted regioselective histone acylation

Protein-substrate supramolecular interactions for the shape selective hydroformylation of long chain a-olefins

Supramolecular assembly of DNA- and protein-based artificial metalloenzymes

Supramolecular Allosteric Catalysts and Replicators

Switchable Catalysis Using Allosteric Effects

Supramolecularly regulated enantioselective catalysts

Emergent catalysis by self-replicating molecules

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Supramolecular Catalysis New Directions and Developments

Summary

Author Biography

Table of Contents

Supplemental Materials