Surface Chemistry and Electrochemistry of

An eclectic mix of studies on chemical and electrochemical behaviour of membrane surfaces. The book looks at membranes - both organic and inorganic - from a host of different perspectives and in the context of many diverse disciplines. It explores the behaviours of both synthetic and biological membranes, employing physical, chemical and physiochemical perspectives, and blends state-of-the-art research of many disciplines into a coherent whole.

Preface

iii

Contributors

ix

Part I Chemical and Physical Structure of Synthetic Membranes and Membrane Surfaces

Atomic Force Microscope Studies of Membrane Surfaces

1

(38)

W. Richard Bowen

Nidal Hilal

Robert W. Lovitt

Chris J. Wright

A Multidisciplinary Approach Towards Pore Size Distributions of Microporous and Mesoporous Membranes

39

(52)

Antonio Hernandez

Jose Ignacio Calvo

Pedro Pradanos

Laura Palacio

Surface Functionalization of Polymer Membranes

91

(34)

Jacqueline Marchand-Brynaert

Formation Process, Analysis and Structure of Silica Polymers, Fractal Aggregates and Membranes

125

(42)

Balagopal N. Nair

Klaas Keizer

Norbert Maene

Tatsuya Okubo

Shin-I chi Nakao

Part II Transport Phenomena in Synthetic Membranes: Reverse Osmosis, Ultrafiltration Gas Pervaporation, Diffusion, Osmosis

Fundamentals of Transport Phenomena in Polymer Solution--Diffusion Membranes

167

(36)

J. H. Petropoulos

M. Sanopoulou

K. G. Papadokostaki

Irreversible Thermodynamic Models for Pervaporation and Ultrafiltration

203

(22)

A. Steinchen

Protein Adsorption on Ultrafiltration Membrane Surfaces and Effects on Transport

225

(22)

V. G. J. Rodgers

Diffusion of Dyes in Porous Membranes with Parallel Pore and Surface Diffusion

247

(24)

Masako Maekawa

Osmotic Properties of Polyelectrolyte Gels

271

(42)

Dietrich Woermann

Part III Electrochemical Transport Processes Through Synthetic Membranes and Membrane Surfaces

Electrochemical Characterization of Membranes and Membrane Surfaces by EMF Measurements

313

(86)

Torben Smith Sorensen

Sergio Roberto Rivera

Transport Numbers of Ions in Charged Membrane Systems

399

(38)

Jose A. Manzanares

Kyosti Kontturi

Ion Equilibrium and Transport in Weak Amphoteric Membranes

437

(18)

Patricio Ramirez

Salvador Mafe

Water, Ion and Entropy Transport in Ion-Exchange Membranes

455

(28)

Signe Kjelstrup

Tatsuhiro Okada

Magnar Ottoy

Irreversible Thermodynamics of Membrane Surface Transport with Application to Polymer Fuel Cells

483

(28)

Signe Kjelstrup

Preben J. S. Vie

Dick Bedeaux

Electroosmotic Transport Through Ion-Exchange Membranes

511

(32)

C. Ruiz Bauza

V. M. Barragan Garcia

Anion-Exchange Membranes with Viologen Cross-Links Showing Photovoltaic Effects and with Permselective Properties Determined by Photoirradiation

543

(48)

Toshikatsu Sata

Electroconvective Mechanisms in Concentration Polarization at Electrodialysis Membranes

591

(32)

I. Rubinstein

B. Zaltzman

Part IV Impedance and Dielectric Dispersion of Synthetic and Biological Membranes and Membrane Surfaces

Interfacial Electrodynamics of Membranes and Polymer Films

623

(126)

Torben Smith Sorensen

The Characterization of Membranes and Membrane Surfaces Using Impedance Spectroscopy

749

(44)

Hans G. L. Coster

Terry C. Chilcott

Impedance of Multilayer Membrane Systems

793

(44)

Emilij K. Zholkovskij

Part V Biomembranes and Biomembrane Surfaces

The Role of Water in the Surface Properties of Lipid Bilayers and Its Influence on Permeability

837

(34)

E. Anibal Disalvo

Surface Electrostatics of Biological Membranes and Ion Binding

871

(52)

Suren A. Tatulian

Ion Transport Across a Membrane with Soft Polar Interfaces

923

(32)

Victor Levadny

Vicente Aguilella

Marina Belaya

Nonlinear Instability of Biological Membrane Surfaces with Application to Bioadhesion

955

(38)

Dominique Gallez

Index

993

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Surface Chemistry and Electrochemistry of Membranes

Summary

Table of Contents

Supplemental Materials