Solid-Liquid Electrochemical Interfaces

This book presents a range of applications for low-energy electron diffraction (LEED), Auger electron spectroscopy (AES), and X-ray photoelectron spectroscopy (XPS). It applies both scanning tunneling and atomic force microscopy to in situ studies of structures of substrates and adsorbatesduring electrochemical measurements. It then presents a theoretical approach to modeling the electrochemical interface.

Preface

xi

1. From Electrochemistry to Molecular-Level Research on the Solid--Liquid Electrochemical Interface: An Overview

1

(12)

Gregory Jerkiewicz

2. Molecular Dynamics Simulation of Interfacial Electrochemical Processes: Electric Double Layer Screening

13

(18)

Michael R. Philpott

James N. Glosli

3. Computer Simulation of the Structure and Dynamics of Water Near Metal Surfaces

31

(14)

E. Spohr

4. Fundamental Thermodynamic Aspects of the Underpotential Deposition of Hydrogen, Semiconductors, and Metals

45

(16)

Alireza Zolfaghari

Gregory Jerkiewicz

5. Micrometer-Scale Imaging of Native Oxide on Silicon Wafers by Using Scanning Auger Electron Spectroscopy

61

(10)

Mikio Furuya

6. Growth Kinetics of Phosphate Films on Metal Oxide Surfaces

71

(16)

T. S. Murrell

M. G. Nooney

L. R. Hossner

D. W. Goodman

7. The Effects of Bromide Adsorption on the Underpotential Deposition of Copper at the Pt(111)--Solution Interface

87

(19)

Nenad M. Markovic

C. A. Lucas

Hubert A. Gasteiger

Philip N. Ross, Jr.

8. Electron Spectroscopy Studies of Acidified Water Surfaces

106

(9)

D. Howard Fairbrother

H. S. Johnston

G. A. Somorjai

9. Electrochemical Digital Etching: Atomic Level Studies of CdTe(100)

115

(11)

T. A. Sorenson

B. K. Wilmer

J. L. Stickney

10. Adsorption of Bisulfate Anion on the Au(111), Pt(111), and Rh(111) Surfaces: A Comparative Study

126

(16)

S. Thomas

Y. -E. Sung

Andrzej Wieckowski

11. Ex Situ Low-Energy Electron Diffraction and Auger Electron Spectroscopy and Electrochemical Studies of the Underpotential Deposition of Lead on Cu(100) and Cu(111)

142

(14)

Gessie M. Brisard

Entissar Zenati

Hubert A. Gasteiger

Nenad M. Markovic

Philip N. Ross, Jr.

12. Anion Adsorption and Charge Transfer on Single-Crystal Electrodes

156

(15)

Roberto Gomez

Jose M. Orts

Juan M. Feliu

13. In Situ Scanning Tunneling Microscopy of Organic Molecules Adsorbed on Iodine-Modified Au(111), Ag(111), and Pt(111) Electrodes

171

(18)

K. Itaya

N. Batina

M. Kunitake

K. Ogaki

Y.-G. Kim

L. -J. Wan

T. Yamada

14. Structure of the GaAs(100) Surface During Electrochemical Reactions Determined by Electrochemical Atomic Force Microscopy

189

(13)

Kohei Uosaki

Michio Koinuma

Namiki Sekine

Shen Ye

15. Microfabrication and Characterization of Solid Surfaces Patterned with Enzymes or Antigen-Antibodies by Scanning Electrochemical Microscopy

202

(8)

H. Shiku

Y. Hara

T. Takeda

T. Matsue

I. Uchida

16. Electroactive Polymers: An Electrochemical and In Situ Scanning Probe Microscopy Study

210

(26)

P. Forrer

G. Repphun

E. Schmidt

H. Siegenthaler

17. X-ray Photoelectron Spectroscopy and Scanning Tunneling Microscopy Studies of Thin Anodic Oxide Overlayers on Metal and Alloy Single-Crystal Surfaces

236

(9)

P. Marcus

V. Maurice

18. Structure and Catalysis of Rh--Pt(100), Pt--Rh(110), Pt--Rh(100), and Pt--Rh(110) Surfaces Prepared by Electrochemical Metal Deposition

245

(29)

K. Tanaka

Y. Okawa

A. Sasahara

Y. Matsumoto

19. Electron Spectroscopy and Electrochemical Scanning Tunneling Microscopy of the Solid--Liquid Interface: Iodine-Catalyzed Dissolution of Pd(110)

274

(9)

Manuel P. Soriaga

W. F. Temesghen

J. B. Abreu

K. Sashikata

K. Itaya

20. Electrocatalysis of Formic Acid and Carbon Monoxide with Probe Adlayers of Carbon and Ethylidyne on Pt(111)

283

(14)

D. E. Sauer

R. L. Borup

E. M. Stuve

21. Photooxidation Reaction of Water on an n-TiO(2) Electrode: Investigation of a Previously Proposed New Mechanism by Addition of Alcohols to the Electrolyte

297

(13)

Y. Magari

H. Ochi

S. Yae

Y. Nakato

22. The Behavior of Pyrazine and Monoprotonated Pyrazine Adsorbed on Silver Electrodes: A Surface-Enhanced Raman Scattering Study

310

(13)

A. G. Brolo

D. E. Irish

23. Temperature Dependence of Growth of Surface Oxide Films on Rhodium Electrodes

323

(22)

Francis Villiard

Gregory Jerkiewicz

INDEXES

345

Author Index

345

(1)

Affiliation Index

345

(1)

Subject Index

346

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Solid-Liquid Electrochemical Interfaces

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Table of Contents

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