Helicenes Synthesis, Properties, and Applications

A thorough introduction to everything there is to know about this fascinating compound class

The intriguing nature of this highly interesting compound class has inspired much research over the last decade, and much of what has been produced is highly interdisciplinary, with applications found in catalysis, material science, and spectroscopy. Indeed, the field has reached maturity such that elegant synthetic methods are now available and novel applications in arenas such as enantioselective catalysis and optoelectronics are appearing.

Helicenes provides not only an introduction to the synthesis of the fascinating compound class of helicenes, but also describes the properties and, most importantly, their applications. The book thoroughly explains several synthetic routes from classical to state-of-the-art methods. In addition, the different classes of helicene-based molecules – organic, organometallic, oligo-meric, and multidimensional – are covered.

Helicenes readers will also find:

• Edited by world-leading experts in the field of chirality
• A comprehensive and well-structured approach that deals with every aspect of this compound class
• Discussions of the applications of helicenes in organic synthesis, photophysics, material science, optoelectronic devices, on-surface chemistry, and theoretical calculations
• A special focus on the applications of helicenes in catalysis, optoelectronics, non-linear optics, and chiroptical spectroscopy
• Chapters focusing on helicenes as theoretical helically chiral models

Helicenes is an essential reference for organic chemists, materials scientists, spectroscopists, polymer chemists, inorganic chemists, and catalytic chemists, as well as students in these fields and libraries supplying them.

Jeanne Crassous, PhD, is Director of Research at the CNRS (University of Rennes). She is a distinguished member of French Chemical Society (Société Chimique de France, SCF).

Irena Stara, PhD, is a senior scientists and project leader at the IOCB Prague, chair of the board of trustees of the Experientia Foundation, member of the Internaitonal Advisor Board of the Inertnational Symposiums on Novel Aromatics and member of the Advisor Board for the French-Czech Vltava Chemistry Meetings.

Ivo Stary, MSc, PhD, is a senior group leader at the IOCB Prague.

Photochemical Approach to Helicenes

Synthesis of Helicenes by [2+2+2] Cycloisomerization

Enantioselective Synthesis of Helicenes

Cationic Azahelicenes

Organometallic and Coordination Chemistry of Helicenes

Tetrathiahelicenes: An Infinite Source of Inspiration

Synthesis and Properties of Helicenes with Small Numbers of Benzene Rings

Halogenated Helicenes as Precursors for Multihelicenic Platforms

Helical Nanographenes: Synthetic and Chiroptical Achievements

Helicenic Electron Acceptors

Chiroptical Properties of Helicenes - Historical Perspective and Structure-property Relationships

Photophysical and Chiroptical Properties of Helicene-based Systems: Experiment vs. Theory

Helicene Derivatives with Circularly Polarized Luminescence

Helicenes and Nonlinear Optical Properties: A Good Match?

Helicenes for Optoelectronic Devices and Applications

Miscellaneous Applications of Helicenes: Surface Science and Asymmetric Catalysis

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