Catalytic Selective Oxidation

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ISBN: 9780841226371 | 0841226377
Cover: Hardcover
Copyright: 5/5/1993

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Discusses the most recent advances in the theories and concepts of selective oxidation technology. Examines the synthesis, characterization, and performance of new catalytic materials used in the oxidation of hydrocarbons in the range of C[1 to C[4. Highlights the use of transition metal oxides in one of several redox states in industrial oxidation processes. Also presents state-of-the-art developments in engineering and applications to new processes.

Preface
Research Challenges in Selective Oxidation	p. 1
Adsorbate Bonding and Selectivity in Partial Oxidation	p. 16
Surface Oxide-Support Interactions in the Molecular Design of Supported Metal Oxide Selective Oxidation Catalysts	p. 31
Silica-Supported MoO[subscript 3] and V[subscript 2]O[subscript 5] Catalysts in Partial Oxidation of Methane to Formaldehyde: Factors Controlling Reactivity	p. 43
Oxygenation Reactions Catalyzed by Supported Sulfonated Metalloporphyrins	p. 58
Principles and New Approaches in Selective Catalytic Homogeneous Oxidation	p. 67
Nature of the Co-Mn-Br Catalyst in the Methylaromatic Compounds Process: Kinetic and Thermodynamic Studies	p. 81
Reactivity of Oxygen Adatoms on the Au(111) Surface	p. 90
Control of the Methanol Reaction Pathway by Oxygen Adsorbed on Mo(112)	p. 110
Structure Sensitivity in Selective Oxidation of Propene over Cu[subscript 2]O Surfaces	p. 122
Structure and Reactivity of Alkali-Promoted NiO Model Catalysts: Surface Vibrational Spectroscopic Characterization	p. 133
Active Crystal Face of Vanadyl Pyrophosphate for Selective Oxidation of n-Butane	p. 156
Selective and Nonselective Pathways in Oxidation and Ammoxidation of Methyl-Aromatic Compounds over Vanadia-Titania Catalysts: Fourier Transform Infrared Spectroscopic Studies	p. 168
Activation of Silver Powder for Ethylene Epoxidation at Vacuum and Atmospheric Pressures	p. 183
Structure and Reactivity of Tin Oxide-Supported Vanadium Oxide Catalysts	p. 204
V-P-O Catalysts in n-Butane Oxidation to Maleic Anhydride: Study Using an In Situ Raman Cell	p. 217
Vanadium Catalysts Supported on Titanium (Anatase) Characterized by Ammonia and Low-Temperature Oxygen Chemisorption	p. 231
Hydrocarbon Partial Oxidation Catalysts Prepared by the High-Temperature Aerosol Decomposition Process: Crystal and Catalytic Chemistry	p. 244
Synergy Effect of Multicomponent Co, Fe, and Bi Molybdates in Propene Partial Oxidation	p. 262
Selective Oxidation of Alkanes, Alkenes, and Phenol with Aqueous H[subscript 2]O[subscript 2] on Titanium Silicate Molecular Sieves	p. 273
Nature of Vanadium Species in Vanadium-Containing Silicalite and Their Behavior in Oxidative Dehydrogenation of Propane	p. 281
Oxidation of Highly Dispersed Platinum on Graphite Catalysts in Gaseous and Aqueous Media	p. 298
Promotion and Deactivation of Platinum Catalysts in Liquid-Phase Oxidation of Secondary Alcohols	p. 308
Toward Catalysis of Selective Epoxidation and Its Applicability to Multistage Organic Synthesis	p. 318
Oxidative Coupling of Methane over Praseodymium Oxide in the Presence and Absence of Tetrachloromethane	p. 326
Oxidative Coupling of Methane over Alkali-Promoted Simple Molybdate Catalysts	p. 340
Methane-Selective Oxidation of Silica-Supported Molybdenum(VI) Catalysts: Structure and Catalytic Performance	p. 354
Partial Oxidation of Ethane over Silica-Supported Molybdate Catalysts	p. 368
Selective Oxidative Dehydrogenation of Propane on Promoted Niobium Pentoxide	p. 380
Factors That Determine Selectivity for Dehydrogenation in Oxidation of Light Alkanes	p. 389
Optimal Distribution of Silver Catalyst for Epoxidation of Ethylene	p. 410
Synthesis Gas Formation by Direct Oxidation of Methane over Monoliths	p. 416
Partial Oxidation Using Membrane Reactors	p. 427
Selective Oxidation of Hydrocarbons by Supercritical Wet Oxidation	p. 438
Author Index	p. 449
Affiliation Index	p. 450
Subject Index	p. 450
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Catalytic Selective Oxidation

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