Chemical and Energy Process Engineering

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ISBN: 9781420087550 | 142008755X
Cover: Hardcover
Copyright: 8/27/2008

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"Emphasizing basic mass and energy balance principles, Chemical and Energy Process Engineering prepares the next generation of process engineers through an exemplary survey of energy process engineering, basic thermodynamics, and the analysis of energy efficiency. By emphasizing the laws of thermodynamics and the law of mass/matter conservation, the author builds a strong foundation for performing industrial process engineering calculations. The book's systematic treatment applies these core principles on a macro-level scale, allowing for more manageable calculations."--BOOK JACKET.

Notation, concepts and numbers	p. 1
Notation	p. 1
Always check the units!	p. 7
Some conversion factors	p. 8
Some important numbers	p. 15
Some important concepts	p. 18
Unit operations	p. 21
Batch and continuous process	p. 27
A little about economy	p. 29
Some fun and useful energy exercises	p. 31
Global energy consumption	p. 37
Derivation of balance equations	p. 39
The balance principle	p. 39
The balance equation	p. 42
Mass balances without accumulation	p. 47
Recycle	p. 55
Systematic formulation and solution of mass balances	p. 58
Use of spreadsheet program	p. 59
Examples of recycle without reaction	p. 62
Flash calculations	p. 64
Summary: Procedure for deriving balance equations	p. 66
Degrees of freedom and solvability	p. 66
Simulation versus design	p. 75
Summary	p. 76
Mass balances with reaction	p. 77
Introduction	p. 77
The component balance	p. 77
Steady-state component balance	p. 78
Conversion and extent of reaction	p. 79
Selectivity and yield	p. 82
Reaction and recycle	p. 85
Atomic balances	p. 86
Independent reactions and matrix formulation	p. 88
Reaction with chemical equilibrium	p. 91
Summary	p. 94
The energy balance	p. 95
The general energy balance (open system)	p. 95
Energy forms	p. 96
Work forms	p. 98
Alternative formulations of the energy balance	p. 100
Calculation of enthalpy	p. 105
Energy balance for mixing processes	p. 107
Valve: Isenthalpic pressure relief	p. 114
Real fluids: Thermodynamic state diagrams	p. 115
Energy balance with chemical reaction	p. 118
Energy balance with kinetic and potential energy	p. 125
Summary of energy balance	p. 128
Heat exchange	p. 129
Introduction	p. 129
Calculation (design) of heat exchangers	p. 131
Simulation of heat exchangers	p. 139
Compression and expansion	p. 143
Introduction	p. 143
Compression (increase of pressure)	p. 144
Expansion in turbine	p. 144
Reversible shaft work	p. 145
Reversible shaft work for ideal gas	p. 148
Actual work and examples	p. 149
Pump work	p. 154
Compression and expansion of real gases	p. 155
Entropy and equilibrium	p. 161
The laws of thermodynamics	p. 161
Calculation of entropy	p. 163
Equilibrium	p. 173
Introduction to vapor/liquid equilibrium	p. 179
Flash calculations	p. 189
Work from heat	p. 197
Thermodynamics	p. 197
Heat engine and the first law	p. 198
Heat engine and the second law	p. 199
Reverse heat engine: Refrigeration and heat pump	p. 203
Efficiency	p. 209
Ideal work and exergy	p. 212
Gas power plant	p. 225
Summary	p. 236
Mechanical energy balance	p. 237
The "regular" energy balance	p. 237
Mechanical energy	p. 238
Reversible shaft work and friction	p. 238
The mechanical energy balance	p. 239
Compressible flow in pipe (gases)	p. 247
A remark on friction	p. 249
Summary	p. 250
Chemical reaction engineering	p. 253
Reaction kinetics	p. 253
Reactor calculations and reactor design	p. 260
Process dynamics	p. 273
Introduction	p. 273
Modeling: Dynamic balances	p. 274
Dynamic analysis and time response	p. 284
Linearization	p. 301
Dynamic simulation with examples	p. 303
Process control	p. 322
Summary	p. 325
Some thermodynamics and physical chemistry	p. 327
Concept of mol	p. 327
Balancing chemical reactions	p. 328
Thermodynamic concepts	p. 329
Thermodynamic diagrams	p. 333
Equations of state	p. 334
Work, heat and energy	p. 343
Volume change work for closed system	p. 346
Internal energy	p. 347
Enthalpy	p. 348
Heat capacity	p. 349
Adiabatic reversible expansion of ideal gas	p. 350
Pressure independence of U and H for ideal gas: Joule's experiment	p. 353
Calculation of enthalpy	p. 354
Thermochemistry	p. 357
Alternative reference states	p. 364
More thermodynamics: Entropy and equilibrium	p. 369
Entropy and the second law of thermodynamics	p. 369
Definition of entropy	p. 370
Carnot cycle for ideal gas	p. 373
Calculation of the system's entropy	p. 377
Mixtures (variable composition)	p. 381
Equilibrium	p. 383
The fundamental equation of thermodynamics and total differentials	p. 389
Differential balances: Examples	p. 393
Emptying of gas tank	p. 393
Logarithmic mean temperature difference	p. 394
Batch (Rayleigh) distillation	p. 396
Summary of the whole book	p. 399
Additional problems	p. 405
Test exam	p. 405
Solution	p. 407
Some more exercises	p. 411
Data	p. 415
Solutions to starred exercises	p. 423
Index	p. 425
Table of Contents provided by Ingram. All Rights Reserved.

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