- ISBN: 9780132280846 | 0132280841
- Cover: Paperback
- Copyright: 1/1/2010
Preface | p. xvi |
To the Student | p. xxiv |
Highlights of the Eleventh Edition | p. xxvi |
Student Media Resources | p. xxx |
Instructor Media Resources | p. xxxi |
Chemistry: A Science for All Seasons | p. 1 |
Science and Technology: The Roots of Knowledge | p. 2 |
The Baconian Dream and the Carsonian Nightmare | p. 3 |
Science: Testable, Reproducible, Explanatory, Predictive, and Tentative | p. 3 |
The Limitations of Science | p. 5 |
Science and Technology: Risks and Benefits | p. 6 |
Chemistry: Its Central Role | p. 8 |
Solving Society's Problems: Scientific Research | p. 9 |
Chemistry: A Study of Matter and Its Changes | p. 11 |
Classification of Matter | p. 14 |
The Measurement of Matter | p. 16 |
Density | p. 21 |
Energy: Heat and Temperature | p. 24 |
Critical Thinking | p. 26 |
Summary | p. 29 |
Review Questions | p. 30 |
Problems | p. 30 |
Additional Problems | p. 32 |
Collaborative Group Projects | p. 33 |
References and Readings | p. 33 |
Green Chemistry | p. 34 |
Atoms: Are They for Real? | p. 36 |
Atoms: The Greek Idea | p. 37 |
Lavoisier: The Law of Conservation of Mass | p. 38 |
Proust: The Law of Definite Proportions | p. 39 |
John Dalton and the Atomic Theory of Matter | p. 41 |
Out of Chaos: The Periodic Table | p. 44 |
Atoms: Real and Relevant | p. 46 |
Leucippus Revisited: Molecules | p. 46 |
Summary | p. 48 |
Review Questions | p. 48 |
Problems | p. 49 |
Additional Problems | p. 51 |
Collaborative Group Projects | p. 52 |
References and Readings | p. 53 |
Green Chemistry | p. 54 |
Atomic Structure: Images of the Invisible | p. 56 |
Electricity and the Atom | p. 57 |
Serendipity in Science: X-Rays and Radioactivity | p. 60 |
Three Types of Radioactivity | p. 61 |
Rutherford's Experiment: The Nuclear Model of the Atom | p. 62 |
The Atomic Nucleus | p. 63 |
Electron Arrangement: The Bohr Model | p. 66 |
Electron Arrangement: The Quantum Model | p. 70 |
Electron Configurations and the Periodic Table | p. 73 |
Which Model to Choose? | p. 75 |
Summary | p. 76 |
Review Questions | p. 77 |
Problems | p. 78 |
Additional Problems | p. 79 |
Collaborative Group Projects | p. 80 |
References and Readings | p. 80 |
Green Chemistry | p. 81 |
Nuclear Chemistry: The Heart of Matter | p. 84 |
Natural Radioactivity | p. 86 |
Nuclear Equations | p. 87 |
Half-Life | p. 92 |
Radioisotopic Dating | p. 93 |
Artificial Transmutation | p. 95 |
Uses of Radioisotopes | p. 96 |
Nuclear Medicine | p. 97 |
Penetrating Power of Radiation | p. 100 |
Energy from the Nucleus | p. 101 |
The Building of the Bomb | p. 103 |
Radioactive Fallout | p. 106 |
Nuclear Power Plants | p. 107 |
Thermonuclear Reactions | p. 107 |
The Nuclear Age | p. 108 |
Summary | p. 110 |
Review Questions | p. 111 |
Problems | p. 112 |
Additional Problems | p. 113 |
Collaborative Group Projects | p. 114 |
References and Readings | p. 115 |
Chemical Bonds: The Ties That Bind | p. 116 |
The Art of Deduction: Stable Electron Configurations | p. 118 |
Lewis (Electron-Dot) Symbols | p. 119 |
Sodium Reacts with Chlorine: Facts | p. 119 |
Sodium Reacts with Chlorine: The Theory | p. 120 |
Using Lewis Symbols: More Ionic Compounds | p. 121 |
Formulas and Names of Binary Ionic Compounds | p. 124 |
Covalent Bonds: Shared Electron Pairs | p. 126 |
Unequal Sharing: Polar Covalent Bonds | p. 127 |
Polyatomic Molecules: Water, Ammonia, and Methane | p. 130 |
Polyatomic Ions | p. 131 |
Rules for Writing Lewis Formulas | p. 132 |
Odd-Electron Molecules: Free Radicals | p. 135 |
Molecular Shapes: The VSEPR Theory | p. 136 |
Shapes and Properties: Polar and Nonpolar Molecules | p. 139 |
Intermolecular Forces and the States of Matter | p. 140 |
A Chemical Vocabulary | p. 144 |
Summary | p. 145 |
Review Questions | p. 147 |
Problems | p. 147 |
Additional Problems | p. 150 |
Collaborative Group Projects | p. 151 |
References and Readings | p. 151 |
Green Chemistry | p. 152 |
Chemical Accounting: Mass and Volume Relationships | p. 154 |
Chemical Sentences: Equations | p. 155 |
Volume Relationships in Chemical Equations | p. 158 |
Avogadro's Number: 6.02 x 10[superscript 23] | p. 160 |
The Mole: "A Dozen Eggs and a Mole of Sugar, Please" | p. 160 |
Mole and Mass Relationships in Chemical Equations | p. 165 |
The Gas Laws | p. 169 |
Solutions | p. 175 |
Summary | p. 180 |
Review Questions | p. 181 |
Problems | p. 182 |
Additional Problems | p. 185 |
Collaborative Group Projects | p. 187 |
References and Readings | p. 187 |
Green Chemistry | p. 188 |
Acids and Bases: Please Pass the Protons | p. 190 |
Acids and Bases: Experimental Definitions | p. 191 |
Acids, Bases, and Salts | p. 193 |
Acidic and Basic Anhydrides | p. 196 |
Strong and Weak Acids and Bases | p. 197 |
Neutralization | p. 198 |
The pH Scale | p. 199 |
Acid Rain | p. 202 |
Antacids: A Basic Remedy | p. 202 |
Acids and Bases in Industry and in Us | p. 203 |
Summary | p. 204 |
Review Questions | p. 206 |
Problems | p. 206 |
Additional Problems | p. 208 |
Collaborative Group Projects | p. 209 |
References and Readings | p. 209 |
Green Chemistry | p. 210 |
Oxidation and Reduction: Burn and Unburn | p. 212 |
Oxidation and Reduction: Three Views | p. 214 |
Oxidizing and Reducing Agents | p. 217 |
Electrochemistry: Cells and Batteries | p. 218 |
Corrosion | p. 222 |
Explosive Reactions | p. 223 |
Oxygen: An Abundant and Essential Oxidizing Agent | p. 223 |
Other Common Oxidizing Agents | p. 225 |
Some Reducing Agents of Interest | p. 226 |
A Closer Look at Hydrogen | p. 228 |
Oxidation, Reduction, and Living Things | p. 230 |
Summary | p. 231 |
Review Questions | p. 232 |
Problems | p. 233 |
Additional Problems | p. 234 |
Collaborative Group Projects | p. 235 |
References and Readings | p. 235 |
Green Chemistry | p. 236 |
Organic Chemistry: The Infinite Variety of Carbon Compounds | p. 238 |
The Unique Carbon Atom | p. 239 |
Alkanes | p. 240 |
Cyclic Hydrocarbons: Rings and Things | p. 244 |
Unsaturated and Hydrocarbons: Alkenes and Alkynes | p. 245 |
Aromatic Hydrocarbons: Benzene and Relatives | p. 247 |
Chlorinated Hydrocarbons: Many Uses, Some Hazards | p. 248 |
The Functional Group | p. 249 |
The Alcohol Family | p. 251 |
Phenols | p. 254 |
Ethers | p. 254 |
Aldehydes and Ketones | p. 256 |
Carboxylic Acids | p. 258 |
Esters: The Sweet Smell of RCOOR' | p. 259 |
Amines and Amides | p. 261 |
Heterocyclic Compounds: Alkaloids and Others | p. 263 |
Summary | p. 264 |
Review Questions | p. 266 |
Problems | p. 266 |
Additional Problems | p. 268 |
Collaborative Group Projects | p. 269 |
References and Readings | p. 269 |
Green Chemistry | p. 270 |
Polymers: Giants Among Molecules | p. 272 |
Polymerization: Making Big Ones Out of Little Ones | p. 273 |
Natural Polymers | p. 273 |
Celluloid: Billiard Balls and Collars | p. 274 |
Polyethylene: From the Battle of Britain to Bread Bags | p. 274 |
Addition Polymerization: One + One + One + ... Gives ONE! | p. 277 |
Rubber and Other Elastomers | p. 281 |
Condensation Polymers: Splitting Out Water | p. 283 |
Properties of Polymers | p. 288 |
Disposal of Plastics | p. 289 |
Plastics and Fire Hazards | p. 290 |
Plasticizers and Pollution | p. 290 |
Plastics and the Future | p. 291 |
Summary | p. 293 |
Review Questions | p. 294 |
Problems | p. 294 |
Additional Problems | p. 295 |
Collaborative Group Projects | p. 296 |
References and Readings | p. 297 |
Green Chemistry | p. 298 |
Chemistry of Earth: Metals and Minerals | p. 300 |
Spaceship Earth: The Materials Manifest | p. 301 |
The Lithosphere: Organic and Inorganic | p. 302 |
Meeting Our Needs: From Sticks to Bricks | p. 303 |
Silicates and the Shapes of Things | p. 304 |
Modified Silicates: Ceramics, Glass, and Cement | p. 306 |
Metals and Ores | p. 308 |
Running Out of Everything: Earth's Dwindling Resources | p. 311 |
Land Pollution: Solid Wastes | p. 312 |
The Three R's of Garbage: Reduce, Reuse, Recycle | p. 313 |
How Crowded Is Our Spaceship? | p. 315 |
Summary | p. 316 |
Review Questions | p. 316 |
Problems | p. 317 |
Additional Problems | p. 318 |
Collaborative Group Projects | p. 319 |
References and Readings | p. 319 |
Green Chemistry | p. 320 |
Air: The Breath of Life | p. 322 |
Earth's Atmosphere: Divisions and Composition | p. 323 |
Chemistry of the Atmosphere | p. 324 |
Temperature Inversion | p. 326 |
Natural Pollution | p. 326 |
The Air Our Ancestors Breathed | p. 327 |
Pollution Goes Global | p. 327 |
Coal + Fire to Industrial Smog | p. 328 |
Automobile Emissions | p. 331 |
Photochemical Smog: Making Haze While the Sun Shines | p. 333 |
Acid Rain: Air Pollution to Water Pollution | p. 335 |
The Inside Story: Indoor Air Pollution | p. 336 |
Ozone: The Double-Edged Sword | p. 338 |
Carbon Dioxide and the Greenhouse Effect | p. 342 |
The Ultimate Pollutant: Heat | p. 345 |
Who Pollutes? How Much? | p. 345 |
Paying the Price | p. 347 |
Summary | p. 348 |
Review Questions | p. 349 |
Problems | p. 349 |
Additional Problems | p. 350 |
Collaborative Group Projects | p. 351 |
References and Readings | p. 351 |
Green Chemistry | p. 352 |
Water: Rivers of Life; Seas of Sorrows | p. 354 |
Water: Some Unique Properties | p. 355 |
Water, Water, Everywhere | p. 358 |
The Water Cycle and Natural Contaminants | p. 358 |
Chemical and Biological Contamination | p. 360 |
An Example of Industrial Pollution: Building a Car | p. 362 |
Groundwater Contamination to Tainted Tap Water | p. 364 |
Making Water Fit to Drink | p. 365 |
Water Treatment Plants | p. 368 |
From Wastewater to Drinking Water | p. 370 |
The Newest Soft Drink: Bottled Water | p. 371 |
Alternative Sewage Treatment Systems | p. 372 |
We're the Solution to Water Pollution | p. 372 |
Summary | p. 373 |
Review Questions | p. 374 |
Problems | p. 374 |
Additional Problems | p. 375 |
Collaborative Group Projects | p. 376 |
References and Readings | p. 377 |
Green Chemistry | p. 378 |
Energy: A Fuels Paradise | p. 380 |
Heavenly Sunlight Flooding Earth with Energy | p. 381 |
Energy and Chemical Reactions | p. 384 |
Energy and the First Law: Energy Is Conserved | p. 387 |
Energy and the Second Law: Things Are Going to Get Worse | p. 387 |
People Power: Early Uses of Energy | p. 389 |
Reserves and Consumption Rates of Fossil Fuels | p. 390 |
Coal: The Carbon Rock of Ages | p. 391 |
Natural Gas: Mostly Methane | p. 394 |
Petroleum: Liquid Hydrocarbons | p. 394 |
Convenient Energy: Electricity | p. 399 |
Nuclear Fission | p. 401 |
Nuclear Fusion: The Sun in a Magnetic Bottle | p. 405 |
Harnessing the Sun: Solar Energy | p. 406 |
Biomass: Photosynthesis for Fuel | p. 408 |
Hydrogen: Light and Powerful | p. 409 |
Other Renewable Energy Sources | p. 411 |
Energy: How Much Is Too Much? | p. 413 |
Summary | p. 414 |
Review Questions | p. 415 |
Problems | p. 416 |
Additional Problems | p. 418 |
Collaborative Group Projects | p. 419 |
References and Readings | p. 419 |
Green Chemistry | p. 420 |
Biochemistry: A Molecular View of Life | p. 422 |
The Cell | p. 423 |
Energy in Biological Systems | p. 424 |
Carbohydrates: A Storehouse of Energy | p. 425 |
Fats and Other Lipids | p. 428 |
Proteins: Polymers of Amino Acids | p. 431 |
The Peptide Bond: Peptides and Proteins | p. 432 |
Structure of Proteins | p. 434 |
Enzymes: Exquisite Precision Machines | p. 438 |
Nucleic Acids: Parts and Structure | p. 440 |
DNA: Self-Replication | p. 444 |
RNA: Protein Synthesis and the Genetic Code | p. 445 |
The Human Genome | p. 447 |
Summary | p. 450 |
Review Questions | p. 451 |
Problems | p. 452 |
Additional Problems | p. 454 |
Collaborative Group Projects | p. 455 |
References and Readings | p. 455 |
Green Chemistry | p. 456 |
Food: Molecular Gastronomy | p. 458 |
Carbohydrates in the Diet | p. 460 |
Fats and Cholesterol | p. 461 |
Proteins: Muscle and Much More | p. 466 |
Minerals: Important Inorganic Chemicals and Life | p. 468 |
The Vitamins: Vital, But Not All Are Amines | p. 469 |
Other Essentials: Fiber and Water | p. 471 |
Starvation and Fasting | p. 472 |
Additives to Enhance Our Food | p. 473 |
Poisons in Our Food | p. 481 |
A World Without Food Additives | p. 483 |
Green Plants: Sun-Powered Food-Making Machines | p. 483 |
Farming with Chemicals: Fertilizers | p. 485 |
The War Against Pests | p. 490 |
Biological Insect Controls | p. 494 |
Herbicides and Defoliants | p. 497 |
Sustainable Agriculture | p. 498 |
Some Malthusian Mathematics | p. 500 |
Can We Feed a Hungry World? | p. 502 |
Summary | p. 503 |
Review Questions | p. 504 |
Problems | p. 505 |
Additional Problems | p. 507 |
Collaborative Group Projects | p. 508 |
References and Readings | p. 508 |
Green Chemistry | p. 510 |
Household Chemicals: Helps and Hazards | p. 512 |
A History of Cleaning | p. 513 |
Fat + Lye to Soap | p. 514 |
Synthetic Detergents | p. 518 |
Laundry Detergent Formulations | p. 519 |
Dishwashing Detergents | p. 523 |
Fabric Softeners: Quaternary Ammonium Salts | p. 524 |
Laundry Bleaches: Whiter Whites | p. 524 |
All-Purpose Cleaning Products | p. 525 |
Special-Purpose Cleaners | p. 525 |
Organic Solvents in the Home | p. 526 |
Paints | p. 527 |
Waxes | p. 528 |
Cosmetics: Personal Care Chemicals | p. 528 |
Toothpaste: Soap with Grit and Flavor | p. 532 |
Perfumes, Colognes, and Aftershaves | p. 533 |
Some Hairy Chemistry | p. 535 |
The Well-Informed Consumer | p. 539 |
Summary | p. 540 |
Review Questions | p. 541 |
Problems | p. 542 |
Additional Problems | p. 543 |
Collaborative Group Projects | p. 544 |
References and Readings | p. 545 |
Green Chemistry | p. 546 |
Fitness and Health: Some Chemical Connections | p. 548 |
Calories: Quantity and Quality | p. 549 |
Vitamins and Minerals | p. 551 |
Body Fluids and Electrolytes | p. 554 |
Weight-Loss Diets | p. 555 |
Exercise for Weight Loss | p. 557 |
Measuring Fitness | p. 559 |
Some Chemistry of Muscles | p. 561 |
Drugs and the Athlete | p. 564 |
Exercise and the Brain | p. 565 |
No Smoking | p. 566 |
Summary | p. 569 |
Review Questions | p. 570 |
Problems | p. 570 |
Additional Problems | p. 571 |
Collaborative Group Projects | p. 572 |
References and Readings | p. 573 |
Green Chemistry | p. 574 |
Drugs: Chemical Cures, Comforts, and Cautions | p. 576 |
Scientific Drug Design | p. 578 |
Pain Relievers: Nonsteroidal Anti-Inflammatory Drugs (NSAIDS) | p. 578 |
Chemistry, Allergies, and the Common Cold | p. 581 |
Antibacterial Drugs | p. 583 |
Viruses and Antiviral Drugs | p. 587 |
Chemicals Against Cancer | p. 589 |
Hormones: The Regulators | p. 592 |
Chemistry and Social Revolution: The Pill | p. 596 |
Drugs for the Heart | p. 599 |
Drugs and the Mind | p. 601 |
Some Chemistry of the Nervous System | p. 601 |
Brain Amines: Depression and Mania | p. 602 |
Anesthetics | p. 605 |
Depressant Drugs | p. 608 |
Narcotics | p. 610 |
Antianxiety Agents | p. 613 |
Stimulant Drugs | p. 616 |
Psychedelic Drugs | p. 618 |
Drug Problems | p. 620 |
The Placebo Effect | p. 621 |
New Uses for Old Drugs | p. 621 |
Summary | p. 622 |
Review Questions | p. 623 |
Problems | p. 624 |
Additional Problems | p. 625 |
Collaborative Group Projects | p. 625 |
References and Readings | p. 627 |
Green Chemistry | p. 628 |
Poisons: Chemical Toxicology | p. 630 |
Natural Poisons | p. 631 |
Corrosive Poisons: A Closer Look | p. 633 |
Poisons Affecting Oxygen Transport and Oxidative Processes | p. 634 |
Make Your Own Poison: Fluoroacetic Acid | p. 635 |
Heavy Metal Poisons | p. 635 |
More Chemistry of the Nervous System | p. 638 |
The Lethal Dose | p. 640 |
The Liver as a Detox Facility | p. 642 |
Chemical Carcinogens: Slow Poisons | p. 643 |
Three Ways to Test for Carcinogens | p. 645 |
Birth Defects: Teratogens | p. 646 |
Hazardous Wastes | p. 647 |
What Price Poisons? | p. 649 |
Summary | p. 650 |
Review Questions | p. 651 |
Problems | p. 651 |
Additional Problems | p. 652 |
Collaborative Group Projects | p. 653 |
References and Readings | p. 653 |
Green Chemistry | p. 654 |
Review of Measurement and Mathematics | p. A-1 |
Glossary | p. A-16 |
Answers | p. A-25 |
Photo Credits | PC-1 |
Index | p. I-1 |
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