Chemistry on Modified Oxide and Phosphate Surfaces: Fundamentals and Applications

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ISBN: 9780123725547 | 0123725542
Cover: Hardcover
Copyright: 3/25/2009

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This title in the authoritative Interface Science and Technology Series presents the key features and applications of modified oxide and phosphate surfaces. * Examines both basic and applied aspects * Incorporates examples from recent publications

Preface	p. ix
Oxides and Phosphates	p. 1
Surfaces and Modified Surfaces	p. 3
Chemistry on Organofunctionalized Amorphous Oxides Surfaces	p. 5
Introduction	p. 5
Modified amorphous oxide surfaces as metal cation sequestrating agents	p. 8
Organofunctionalized metal-modified surfaces for chromatographic applications	p. 8
Modified amorphous oxides for luminescent devices	p. 9
A 3-trimethoxypropylthioethylamine-modified surface	p. 9
In situ synthesis of luminescent complexes on amorphous modified silica surfaces	p. 12
Modified amorphous oxide surfaces as electrochemical sensors	p. 20
Metal cation electrochemical sensors	p. 20
Paracetamol sensors	p. 20
Chemically modified oxide surfaces capable of molecular recognition	p. 24
The influence of magnesium trisilicate and silicon dioxide on the thermal degradation of ascorbic acid	p. 24
References	p. 31
Chemistry on Organofunctionalized Nanostructured Oxides' Surfaces	p. 33
Introduction	p. 33
Inorganic-organic hybrids	p. 34
Sol-gel lamellar silica	p. 34
Eu(ii)-doped lamellar silica	p. 35
Titania foam and thiol-functionalized nanoporous titania-silica	p. 38
Thiol-functionalized nanoporous titania-silica	p. 38
Titania foam	p. 40
The effects of nanostructure on adsorption features: metal chemisorption on hexagonal templated zirconia obtained thorough sol-gel process	p. 41
Surface modifications promoted by not bonded species	p. 45
Effects of metal salts, DMF, and DMSO on the anatase-rutile transition in sol-gel-synthesized TiO₂	p. 45
Hexagonal mesoporous silica	p. 48
References	p. 49
Chemistry on Conducting Polymer-Modified Oxide Surfaces	p. 51
Introduction	p. 51
Synthetic approach	p. 51
Effects of adsorbed conducting polymer on the oxide properties	p. 52
Effects of the oxide on the adsorbed polymer properties	p. 52
References	p. 56
Chemistry on Modified Layered Oxides	p. 57
Introduction	p. 57
Titanates and niobates	p. 57
Tungstates and molybdates	p. 58
Molybdenum oxide as a molecular sieve	p. 62
MoO₃ intercalation compounds with nic and hmta	p. 62
Adsorption of caffeine, dimethylglyoxime, and rodamin-B on lamellar molybdenum oxide	p. 68
Sol-gel modified molybdenum oxide	p. 72
Graphite oxide	p. 77
References	p. 78
Chemistry on Modified Phosphates	p. 79
Introduction	p. 79
Titanium and zirconium phosphates	p. 79
Vanadyl phosphate	p. 80
Synthesis and characterization of a VOPO4-NH3 hybrid	p. 80
More vanadyl phosphate compounds	p. 83
Barium and calcium phosphate	p. 84
Adsorption of glycine on "animal" (bone) phosphate	p. 84
Introduction	p. 84
Experimental	p. 84
Results and discussion	p. 85
A final example	p. 89
References	p. 89
Chemistry on Modified Clay Surfaces	p. 91
Introduction	p. 91
Vermiculite surface modified with carnauba wax for oil cleaning	p. 91
Water as a surface modifier: the hydrophobicity of vermiculite	p. 95
The effect of surface chemical composition on the acide corrosion of pedra sabão (soapstone)	p. 98
Thermal degradation of vegetable oils on clays (biodiesel production)	p. 103
Introduction	p. 103
Miscellaneous examples	p. 106
References	p. 107
Zeolites	p. 109
Introduction	p. 109
Some examples and applications	p. 110
References	p. 112
Further Reading	p. 113
Subject Index	p. 199
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Chemistry on Modified Oxide and Phosphate Surfaces: Fundamentals and Applications

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