CO2 Conversion and Utilization

This book focuses on the chemistry and processes for conversion and utilization of carbon dioxide. Topics include CO[2 utilization, its conversion to industrial chemicals and fuels, its coversion via synthesis gas, and new catalysts and chemical processes for conversion.

Preface

xi

General Overview

CO2 Conversion and Utilization: An Overview

2

(29)

Chunshan Song

CO2 Mitigation and Fuel Production

31

(8)

M. Steinberg

CO2 Emission Reductions: An Opportunity for New Catalytic Technology

39

(15)

Leo E. Manzer

Synthesis of Organic Chemicals

Key Issues in Carbon Dioxide Utilization as a Building Block for Molecular Organic Compounds in the Chemical Industry

54

(17)

Michele Aresta

Angela Dibenedetto

Selective Conversion of Carbon Dioxide and Methanol to Dimethyl Carbonate Using Phosphoric Acid-Modified Zirconia Catalysts

71

(14)

Yoshiki Ikeda

Yutaka Furusawa

Keiichi Tomishige

Kaoru Fujimoto

Utilization of Carbon Dioxide for Direct, Selective Conversion of Methane to Ethane and Ethylene with Calcium-Based Binary Catalysts

85

(17)

Ye Wang

Yasuo Ohtsuka

Copolymerization of Carbon Dioxide, Propylene Oxide, and Cyclohexene Oxide by an Yttrium--Metal Coordination Catalyst System

102

(10)

Chung-Sung Tan

Char-Fu Chang

Tsung-Ju Hsu

The Role of CO2 for the Gas-Phase O2 Oxidation of Alkylaromatics to Aldehydes

112

(18)

Jin S. Yoo

CO2 Reduction over Heterogeneous Catalysts

Effective Conversion of CO2 to Valuable Compounds by Using Multifunctional Catalysts

130

(23)

Tomoyuki Inui

Supported Copper and Managanese Catalyst for Methanol Synthesis from CO2-Containing Syngas

153

(13)

K. Omata

G. Ishiguro

K. Ushizaki

M. Yamada

Catalytic Reduction of CO2 into Liquid Fuels: Simulating Reactions under Geologic Formation Conditions

166

(16)

D. Mahajan

C. Song

A.W. Scaroni

Synthesis Gas Production from CO2 Reforming

Methane Dry Reforming over Carbide, Nickel-Based, and Noble Metal Catalysts

182

(15)

Abolghasem Shamsi

A Highly Active and Carbon-Resistant Catalyst for CH4 Reforming with CO2: Nickel Supported on an Ultra-Fine ZrO2

197

(8)

Jun-Mei Wei

Bo-Qing Xu

Jin-Lu Li

Zhen-Xing Cheng

Qi-Ming Zhu

CO2 Reforming of Methane over Ru-Loaded Lanthanoid Oxide Catalysts

205

(19)

Kiyoharu Nakagawa

Shigeo Hideshima

Noriyasu Akamatsu

Na-oko Matsui

Na-oki Ikenaga

Toshimitsu Suzuki

CO2 Reforming and Simultaneous CO2 and Steam Reforming of Methane to Syngas over CoxNi1-xO Supported on Macroporous Silica--Alumina Precoated with MgO

224

(17)

V. R. Choudhary

A. S. Mamman

B.S. Uphade

R. E. Badcock

Low-Temperature CH4 Decomposition on High-Surface Area Carbon Supported Co Catalysts

241

(17)

Z.-G. Zhang

K. Haraguchi

T. Yoshida

Effects of Pressure and Reactor Type on CO2 Reforming

Effects of Pressure on CO2 Reforming of CH4 over Ni/Na-Y and Ni/Al2O3 Catalysts

258

(17)

Chunshan Song

Srinivas T. Srimat

Satoru Murata

Wei Pan

Lu Sun

Alan W. Scaroni

John N. Armor

A Comparative Study on CH4-CO2 Reforming over Ni/SiO2--MgO Catalyst Using Fluidized-and Fixed-Bed Reactors

275

(14)

A. Effendi

Z.-G. Zhang

T. Yoshida

Effects of Pressure on CO2 Reforming of CH4 over Rh/Na-Y and Rh/Al2O3 Catalysts

289

(14)

Srinivas T. Srimat

Chunshan Song

Methane Reforming with Carbon Dioxide and Oxygen under Atmospheric and Pressurized Conditions Using Fixed-and Fluidized-Bed Reactors

303

(13)

Keiichi Tomishige

Yuichi Matsuo

Mohammad Asadullah

Yusuke Yoshinaga

Yasushi Sekine

Kaoru Fujimoto

Computational Analysis of Energy Aspects of CO2 Reforming and Oxy-CO2 Reforming of Methane at Different Pressures

316

(14)

Wei Pan

Chunshan Song

Photocatalytic and Electrochemical Reduction

Photocatalytic Reduction of CO2 with H2O on Various Titanium Oxide Catalysts

330

(14)

Hiromi Yamashita

Keita Ikeue

Masakazu Anpo

Electrochemical Reduction of CO2 with Gas-Diffsuion Electrodes Fabricated Using Metal and Polymer-Confined Nets

344

(20)

K. Ogura

H. Yano

M. Nakayama

Use of Supercritical CO2 Fluid

Use of Dense-Phase Carbon Dioxide in Catalysis

364

(23)

Bala Subramaniam

Daryle H. Busch

The Possibility of Coupling Supercritical Extractions in Petroleum Industry with CO2 Conversion Plants to Lessen Investments

387

(16)

Marco Antonio G. Teixeira

Maria Luisa A. Goncalves

Author Index

403

(1)

Subject Index

404

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CO2 Conversion and Utilization

Summary

Table of Contents

Supplemental Materials