Core Level Spectroscopy of Solids

Note: Supplemental materials are not guaranteed with Rental or Used book purchases.

ISBN: 9780849390715 | 0849390710
Cover: Hardcover
Copyright: 3/10/2008

Rent

(Recommended)

$152.96

Term

Due

Price

Semester

Dec 12

$169.95

Quarter

Sep 5

$161.45

Short Term

Aug 13

$152.96

*This item is part of an exclusive publisher rental program and requires an additional convenience fee. This fee will be reflected in the shopping bag.
Buy New

Usually Ships in 3-5 Business Days

$217.58
eBook

Available Instantly

Online: 180 Days

Downloadable: 180 Days

*To support the delivery of the digital material to you, a digital delivery fee of $3.99 will be charged on each digital item.

$178.20*

Core level spectroscopy has become a powerful tool in the study of electronic states in solids. From fundamental aspects to the most recent developments, Core Level Spectroscopy of Solids presents the theoretical calculations, experimental data, and underlying physics of x-ray photoemission spectroscopy (XPS), x-ray absorption spectroscopy (XAS), x-ray magnetic circular dichroism (XMCD), and resonant x-ray emission spectroscopy (RXES).Starting with the basic aspects of core level spectroscopy, the book explains the many-body effects in XPS and XAS as well as several theories. After forming this foundation, the authors explore more advanced features of XPS, XAS, XMCD, and RXES. Topics discussed include hard XPS, resonant photoemission, spin polarization, electron energy loss spectroscopy (EELS), and resonant inelastic x-ray scattering (RIXS). The authors also use the charge transfer multiplet theory to interpret core level spectroscopy for transition metal and rare earth metal systems.Pioneers in the theoretical and experimental developments of this field, Frank de Groot and Akio Kotani provide an invaluable treatise on the numerous aspects of core level spectroscopy that involve solids.

Preface	p. xv
Acknowledgments	p. xvii
Authors	p. xix
Introduction	p. 1
Fundamental Aspects of Core Level Spectroscopies	p. 11
Core Holes	p. 11
Creation of Core Holes	p. 11
Decay of Core Holes	p. 12
Overview of Core Level Spectroscopies	p. 14
Core Hole Spin-Orbit Splitting	p. 14
Core Hole Excitation Spectroscopies	p. 15
Core Hole Decay Spectroscopies	p. 18
Resonant Photoelectron Processes	p. 19
Resonant X-Ray Emission Channels	p. 22
Overview of the RXES and NXES Transitions	p. 23
Interaction of X-Rays with Matter	p. 25
Electromagnetic Field	p. 26
Transition to Quantum Mechanics	p. 26
Interaction Hamiltonian	p. 27
Golden Rule	p. 27
Optical Transition Operators and X-Ray Absorption Spectra	p. 28
Electric Dipole Transitions	p. 29
Electric Quadrupole Transitions	p. 29
Dipole Selection Rules	p. 29
Transition Probabilities, Cross Sections, and Oscillator Strengths	p. 30
Cross Section, Penetration Depth, and Excitation Frequency	p. 31
X-Ray Attenuation Lengths	p. 32
Interaction of Electrons with Matter	p. 32
X-Ray Sources	p. 34
Synchrotron Radiation Sources	p. 34
X-Ray Beamlines and Monochromators	p. 35
Other X-Ray Sources	p. 36
Electron Sources	p. 37
Many-Body Charge-Transfer Effects in XPS and XAS	p. 39
Introduction	p. 39
Many-Body Charge-Transfer Effects in XPS	p. 40
Basic Description of the XPS Process	p. 40
General Expressions of Many-Body Effects	p. 42
General Description	p. 42
Generating Function and Dielectric Response	p. 44
XPS Spectrum and Its Limiting Forms	p. 45
Slow Modulation Limit	p. 47
Rapid Modulation Limit	p. 47
General Effects in XPS Spectra	p. 47
Screening by Free-Electron-Like Conduction Electrons	p. 47
Screening by Lattice Relaxation Effects	p. 49
Shake-Up Satellites	p. 50
Lifetime Effects	p. 50
Auger Transition	p. 50
Radiative Transition	p. 51
Typical Examples of XPS Spectra	p. 52
Simple Metals	p. 52
La Metal	p. 56
Final State of Type (A)	p. 59
Final State of Type (B)	p. 60
Mixed Valence State in Ce Intermetallic Compounds	p. 62
Insulating Mixed Valence Ce Compounds	p. 67
Transition Metal Compounds	p. 71
Model	p. 71
Simplified Analysis	p. 72
Case A: [Delta subscript f] > 0 ([Delta] > U[subscript dc])	p. 74
Case B: [Delta subscript f] [less than or equal] 0 ([Delta] [less than or equal] U[subscript dc])	p. 74
Many-Body Charge-Transfer Effects in XAS	p. 76
General Expressions of Many-Body Effects	p. 76
XAS in Simple Metals	p. 76
XAS in La Metal	p. 78
Case A: [epsilon subscript f] < [epsilon subscript F]	p. 79
Case B: [epsilon subscript f] > [epsilon subscript F]	p. 80
Ce 3d XAS of Mixed Valence Ce Compounds	p. 81
Ce L[subscript 3] XAS	p. 83
XAS in Transition Metal Compounds	p. 87
Comparison of XPS and XAS	p. 89
Charge Transfer Multiplet Theory	p. 93
Introduction	p. 93
Atomic Multiplet Theory	p. 95
Term Symbols	p. 96
Some Simple Coupling Schemes	p. 98
Term Symbols of d-Electrons	p. 101
Matrix Elements	p. 105
Energy Levels of Two d-Electrons	p. 107
More Than Two Electrons	p. 108
Matrix Elements of the 2p[superscript 3] Configuration	p. 109
Hund's Rules	p. 110
Final State Effects of Atomic Multiplets	p. 111
Ligand Field Multiplet Theory	p. 115
Ligand Field Multiplet Hamiltonian	p. 116
Cubic Crystal Fields	p. 117
Definitions of the Crystal Field Parameters	p. 119
Energies of the 3d[superscript n] Configurations	p. 120
Symmetry Effects in D[subscript 4h] Symmetry	p. 124
Effect of the 3d Spin-Orbit Coupling	p. 125
Consequences of Reduced Symmetry	p. 126
3d[superscript 0] Systems in Octahedral Symmetry	p. 126
Ab Initio LFM Calculations	p. 132
Charge Transfer Multiplet Theory	p. 133
Initial State Effects	p. 134
Final State Effects	p. 137
XAS Spectrum with Charge-Transfer Effects	p. 138
Small Charge-Transfer Satellites in 2p XAS	p. 140
Large Charge-Transfer Satellites in 2p XPS	p. 141
3d[superscript 0] Compounds	p. 142
3d[superscript 8] Compounds	p. 143
X-Ray Photoemission Spectroscopy	p. 145
Introduction	p. 145
Experimental Aspects	p. 146
XPS of TM Compounds	p. 146
2p XPS	p. 146
Zaanen-Sawatzky-Allen Diagram	p. 152
2p XPS in Early TM Systems	p. 154
Effect of Multiplet Coupling on [Delta] and U[subscript dd]	p. 158
3s XPS	p. 160
3p XPS	p. 164
XPS of RE Compounds	p. 165
Simplified Analysis for RE Oxides	p. 165
Application of Charge-Transfer Multiplet Theory	p. 169
Resonant Photoemission Spectroscopy	p. 176
Fundamental Aspects of RPES	p. 177
RPES in Ni Metal and TM Compounds	p. 180
3p RPES in Ni Metal	p. 180
2p RPES in TM Compounds	p. 182
3p RPES in NiO	p. 185
3d and 4d RPES of Ce Compounds	p. 185
Resonant XPS	p. 187
Resonant Auger Electron Spectroscopy	p. 188
Reducing the Lifetime Broadening in XAS	p. 191
EQ and ED Excitations in the Pre-Edge of Ti 1s XAS of TiO[subscript 2]	p. 191
Hard X-Ray Photoemission Spectroscopy	p. 197
2p HAXPS of Cuprates	p. 197
2p HAXPS of V[subscript 2]O[subscript 3] and La[subscript 1-x]Sr[subscript x]MnO[subscript 3]	p. 198
Ce Compounds: Surface/Bulk Sensitivity	p. 199
Resonant HAXPS of Ce Compounds	p. 202
Resonant Inverse Photoemission Spectroscopy	p. 205
Nonlocal Screening Effect in XPS	p. 212
Auger Photoemission Coincidence Spectroscopy	p. 218
Spin-Polarization and Magnetic Dichroism in XPS	p. 221
Spin-Polarized Photoemission	p. 221
Spin-Polarized Circular Dichroic Resonant Photoemission	p. 221
X-Ray Absorption Spectroscopy	p. 225
Basics of X-Ray Absorption Spectroscopy	p. 225
Metal L[subscript 2,3] Edges	p. 228
Experimental Aspects	p. 228
Transmission Detection	p. 229
Energy Dispersive X-Ray Absorption	p. 229
Fluorescence Yield	p. 229
Self-Absorption Effects in Fluorescence Yield Detection	p. 230
Nonlinear Decay Ratios and Distortions in Fluorescence Yield Spectra	p. 230
Partial Fluorescence Yield	p. 230
Electron Yield	p. 231
Partial Electron Yield	p. 231
Ion Yield	p. 232
Detection of an EELS Spectrum	p. 232
Low-Energy EELS Experiments	p. 233
Space: X-Ray Spectromicroscopy and TEM-EELS	p. 233
Time-Resolved X-Ray Absorption	p. 234
Extreme Conditions	p. 235
L[subscript 2,3] Edges of 3d TM Systems	p. 235
3d[superscript 0] Systems	p. 236
3d[superscript 1] Systems	p. 237
VO[subscript 2] and LaTiO[subscript 3]	p. 237
3d[superscript 2] Systems	p. 237
3d[superscript 3] Systems	p. 238
3d[superscript 4] Systems	p. 239
LaMnO[subscript 3]	p. 240
Mixed Spin Ground State in LiMnO[subscript 2]	p. 240
3d[superscript 5] Systems	p. 241
MnO	p. 241
Fe[subscript 2]O[subscript 3]	p. 242
Fe[superscript 3+](tacn)[subscript 2]	p. 243
Fe[superscript 3+](CN)[subscript 6]	p. 243
Intermediate Spin State of SrCoO[subscript 3]	p. 244
3d[superscript 6] Systems	p. 245
Effect of 3d Spin-Orbit Coupling in Fe[subscript 2]SiO[subscript 4]	p. 246
Co[superscript 3+] Oxides	p. 247
3d[superscript 7] Systems	p. 248
Effects of 3d Spin-Orbit Coupling on the Ground State of Co[superscript 2+]	p. 248
Mixed Spin Ground State in PrNiO[subscript 3]	p. 249
3d[superscript 8] Systems	p. 251
NiO	p. 251
High-Spin and Low-Spin Ni[superscript 2+] and Cu[superscript 3+] Systems	p. 251
3d[superscript 9] Systems	p. 253
Other X-Ray Absorption Spectra of the 3d TM Systems	p. 254
TM M[subscript 2,3] Edges	p. 254
TM M[subscript 1] Edges	p. 255
TM K Edges	p. 255
Ligand K Edges	p. 260
Oxygen K Edges of High T[subscript c] Copper Oxides	p. 264
Soft X-Ray K Edges by X-Ray Raman Spectroscopy	p. 264
Modifying the Selection Rules	p. 265
X-Ray Absorption Spectra of the 4d and 5d TM Systems	p. 265
L[subscript 2,3] Edges of 4d TM Systems	p. 266
Picosecond Time-Resolved 2p XAS Spectra of [Ru(bpy) subscript 3 superscript 2+]	p. 268
Higher Valent Ruthenium Compounds	p. 269
Pd L Edges and the Number of 4d Holes in Pd Metal	p. 270
X-Ray Absorption Spectra of the 5d Transition Metals	p. 271
X-Ray Absorption Spectra of the 4f RE and 5f Actinide Systems	p. 272
M[subscript 4,5] Edges of Rare Earths	p. 273
M[subscript 4,5] Edge of Tm	p. 274
M[subscript 4,5] Edge of La[superscript 3+]	p. 277
M[subscript 4,5] Edge of CeO[subscript 2]	p. 278
N[subscript 4,5] Edges of Rare Earths	p. 278
L[subscript 2,3] Edges of Rare Earths	p. 281
O[subscript 4,5] Edges of Actinides	p. 282
M[subscript 4,5] Edges of Actinides	p. 282
X-Ray Magnetic Circular Dichroism	p. 287
Introduction	p. 287
XMCD Effects in the L[subscript 2,3] Edges of TM Ions and Compounds	p. 288
Atomic Single Electron Model	p. 288
XMCD Effects in Ni[superscript 2+]	p. 293
XMCD of CrO[subscript 2]	p. 297
Magnetic X-Ray Linear Dichroism	p. 297
Orientation Dependence of XMCD and XMLD Effects	p. 298
XMLD for Doped LaMnO[subscript 3] Systems	p. 299
Sum Rules	p. 299
Sum Rules for Orbital and Spin Moments	p. 299
Application of the Sum Rules to Fe and Co Metals	p. 302
Application of the Sum Rules to Au/Co-Nanocluster/Au Systems	p. 304
Limitations of the Sum Rules	p. 308
Theoretical Simulations of the Spin Sum Rule	p. 309
XMCD Effects in the K Edges of Transition Metals	p. 310
X-Ray Natural Circular Dichroism and X-Ray Optical Activity	p. 311
XMCD Effects in the M Edges of Rare Earths	p. 312
XMCD and XMLD Effects from Atomic Multiplets	p. 312
Temperature Effects on the XMCD and XMLD	p. 314
XMCD Effects in the L Edges of Rare Earth Systems	p. 314
Effects of 4f5d Exchange Interaction	p. 315
Contribution of Electric Quadrupole Transition	p. 319
Effect of Hybridization between RE 5d and TM 3d States	p. 319
XMCD at L Edges of R[subscript 2]Fe[subscript 14]B (R = La-Lu)	p. 320
Mixed Valence Compound CeFe[subscript 2]	p. 324
Multielectron Excitations	p. 328
Applications of XMCD	p. 329
Magnetic Oxides	p. 329
Thin Magnetic (Multi)layers, Interface, and Surface Effects	p. 330
Impurities, Adsorbates, and Metal Chains	p. 332
Magnetic Nanoparticles and Catalyst Materials	p. 333
Molecular Magnets	p. 333
Metal Centers in Proteins	p. 334
Resonant X-Ray Emission Spectroscopy	p. 335
Introduction	p. 335
Experimental Aspects of XES (RXES and NXES)	p. 337
Detectors for Soft X-Ray XES	p. 338
Detectors for Hard X-Ray XES	p. 338
X-Ray Raman Allows Soft X-Ray XAS under Extreme Conditions	p. 338
Basic Description and Some Theoretical Aspects	p. 338
Rare Earth Compounds	p. 343
Effect of Intra-Atomic Multiplet Coupling	p. 343
Effect of Interatomic Hybridization in CeO[subscript 2] and PrO[subscript 2]	p. 348
Metallic Ce Compounds with Mixed-Valence Character	p. 351
Kondo Resonance in Yb Compounds	p. 354
Dy 2p3d RXES Detection of the 2p4f EQ Excitation	p. 357
EQ Excitations in Light Rare Earth Elements	p. 360
High T[subscript c] Cuprates and Related Materials	p. 363
Cu 2p3d RXES	p. 363
Cu 1s4p RXES	p. 367
Cu 1s2p RXES	p. 373
O 1s2p RXES	p. 377
Nickel and Cobalt Compounds	p. 380
Ni 2p3d RXES in NiO: Charge Transfer Excitations	p. 380
Ni 2p3d RXES in NiO: dd Excitations	p. 384
Ni 2p3d RXES in NiO: Spin-Flip Excitations	p. 386
Ni 1s4p RXES of NiO: Pressure Dependence	p. 387
Co 2p3d RXES in CoO and Other Co Compounds	p. 389
Co 1s2p RXES of CoO: Effect of Resolution	p. 389
Co 1s2p RXES: Nonlocal Dipole Transitions	p. 391
Iron and Manganese Compounds	p. 393
Fe 1s2p RXES of Iron Oxides: 2D RXES Images	p. 393
HERFD-XAS of Iron Oxides	p. 395
Fe 2p XAS Spectra Measured at the Fe K Edge	p. 397
Valence Selective XAS	p. 397
Mn 2p3d RXES of MnO	p. 399
Mn 2p3d RXES: Interplay of dd and Charge Transfer Excitations	p. 402
Mn 1s4p RXES of LaMnO[subscript 3]	p. 405
Mn and Ni 1s3p XES: Chemical Sensitivity	p. 406
Mn 1s3p XES: K Capture Versus X-Ray Ionization	p. 408
Atomic Multiplet Calculation	p. 409
LFM Calculation	p. 410
Charge Transfer Multiplet Calculation	p. 410
Coherent Calculation of Mn 1s3p NXES Spectra	p. 411
Early Transition Metal Compounds	p. 412
Ca 2p3s RXES in CaF[subscript 2]	p. 413
Ti 2p3d RXES of TiO[subscript 2]: Polarization Dependence	p. 415
Sc 2p3d RXES of the ScF[subscript 3], ScCl[subscript 3], and ScBr[subscript 3]	p. 420
TM 2p3d RXES of d[superscript n] (n = 1, 2, 3) Systems	p. 420
V 2p3d RXES of Vanadium Oxides	p. 423
Electron Spin States Detected by RXES and NXES	p. 423
Local Spin-Selective Excitation Spectra	p. 423
Spin-Dependent TM 1s3p NXES Spectra	p. 425
TM 1s3p NXES and Spin-Transitions	p. 426
Local-Spin Selective XAS and XMCD	p. 429
MCD in RXES of Ferromagnetic Systems	p. 429
Longitudinal and Transverse Geometries in MCD-RXES	p. 429
MCD-RXES in LG of CeFe[subscript 2]	p. 433
Experiments and Theory of MCD-RXES in TG	p. 435
Precise Derivation of XPS Formula	p. 439
Derivation of Equation 3.88 in Chapter 3	p. 443
Fundamental Tensor Theory	p. 447
Derivation of the Orbital Moment Sum Rule	p. 451
Theoretical Test of the Spin Sum Rule	p. 453
Calculations of XAS Spectra with Single Electron Excitation Models	p. 457
References	p. 463
Index	p. 483
Table of Contents provided by Ingram. All Rights Reserved.

Please wait while the item is added to your bag...

FREE SHIPPING

Rent More, Save More! Use code: BBRENTAL

5% off 1 book, 7% off 2 books, 10% off 3+ books

Core Level Spectroscopy of Solids

Summary

Table of Contents

Supplemental Materials

FREE SHIPPING

Rent More, Save More! Use code: BBRENTAL

5% off 1 book, 7% off 2 books, 10% off 3+ books

Core Level Spectroscopy of Solids

Summary

Table of Contents

Supplemental Materials

Digital License