The Desulfurization of Heavy Oils and Residua

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ISBN: 9780824789213 | 0824789210
Cover: Hardcover
Copyright: 11/5/1999

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Summary

Supplemental Materials

Expands and updates information on the technological aspects of refining heavy oils, residua, bitumen, and other high-sulfur feed- stocks.

Preface to the Second Edition

iii

Preface to the First Edition

History, Definitions, and Occurrence

(38)

Introduction

(9)

History

(3)

Definitions

(12)

Occurrence

(9)

Sulfur in Petroleum

(5)

References

(3)

Feedstock Evaluation

(44)

Introduction

(5)

Feedstock Evaluation

(28)

Chromatographic Methods

(1)

Molecular Weight

(1)

Other Properties

(3)

Use of the Data

(6)

References

(4)

Feedstock Composition

(44)

Introduction

(10)

Chemical Composition

(13)

Physical (Bulk) Composition

106

(10)

Use of the Data

116

(11)

References

124

(3)

Desulfurization Chemistry

127

(41)

Introduction

127

(5)

Thermodynamic Aspects

132

(2)

Kinetics of Hydrodesulfurization

134

(7)

Sulfur Removal During Refining

141

(12)

Macromolecular Concepts

153

(10)

Sediment Formation

163

(5)

References

164

(4)

The Desulfurization Process

168

(38)

Introduction

168

(3)

Process Description

171

(6)

Reactor Design

177

(7)

Catalysts

184

(9)

Catalyst Bed Plugging

193

(5)

Catalyst Poisoning

198

(1)

Process Variables

199

(7)

References

204

(2)

Influence of Feedstock

206

(48)

Introduction

206

(12)

Feedstock Types

218

(10)

Feedstock Composition

228

(21)

Product Distribution

249

(5)

References

251

(3)

Desulfurization During Refining

254

(48)

Introduction

254

(1)

Distillation

255

(15)

Visbreaking

270

(4)

Catalytic Cracking

274

(5)

Coking

279

(8)

Hydroprocessing

287

(7)

Deasphalting

294

(4)

Feedstock Modification

298

(4)

References

299

(3)

Upgrading Heavy Feedstocks

302

(33)

Introduction

302

(5)

Thermal Processes

307

(7)

Catalytic Cracking Processes

314

(10)

Solvent Processes

324

(11)

References

332

(3)

Desulfurization Processes

335

(51)

Introduction

335

(8)

Process Options

343

(43)

References

384

(2)

Hydrogen Production

386

(15)

Introduction

386

(4)

Hydrogen Production

390

(11)

References

400

(1)

Conversion Factors

401

(2)

Glossary

403

(46)

Index

449

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The Desulfurization of Heavy Oils and Residua

Summary

Table of Contents

Supplemental Materials

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The Desulfurization of Heavy Oils and Residua

Summary

Table of Contents

Supplemental Materials

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