Early Transition Metal Clusters with pi-Donor

The discovery and evolution of oranometallic cluster chemistry is a major event in the development of inorganic chemistry. This is the second volume in the series 'The Chemistry of Metal Clusters' edited by Du Shriver, Herb Kaesz, and Richard Adams. This volume focuses on the chemistry of the early transition elements in their lower and middle oxidation states, i.e., halide, sulfide, oxide, phosphate, alkoxide, and related o-donor ligands. The key feature linking all these complexes in metal-metal bonding is the presence of pi-donor ligands.

Malcolm Harold Chisholm, FRS FRSE was a Scottish inorganic chemist who was a Professor of Chemistry and Biochemistry, and Distinguished University Professor of Mathematical and Physical Sciences at Ohio State University who contributed to the synthesis and structural chemistry of transition metal complexes.

Halide Supported Octahedral Clusters of Zirconium: Structural and Bonding Questions.

Cluster and Metal-Metal Bonded Chains in Molybdenum Oxide Systems.

Chalcogenide Cluster Complexes of Early Transition Metals.

Alkoxide Clusters in Molybdenum and Vanadium Phosphate Solids.

Organophosphonate and Organoarsonate Complexes with the Oxovanadium and Oxomolybdenum.

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Early Transition Metal Clusters with pi-Donor Ligands

Summary

Author Biography

Table of Contents

Supplemental Materials