Functional Organic Materials Syntheses, Strategies and Applications

, by Mü; ller, Thomas J. J.; Bunz, Uwe H. F.

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ISBN: 9783527313020 | 3527313028
Cover: Hardcover
Copyright: 2/12/2007

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This timely overview of the syntheses for functional pi-systems focuses on target molecules that have shown interesting properties as materials or models in physics, biology and chemistry. The unique concept allows readers to select the right synthetic strategy for success, making it invaluable for a number of industrial applications. A "must have" for everyone working in this new and rapidly expanding field.

Preface
List of Contributors
3-D Carbon-rich ¿-Systems – Nanotubes and Segments
Functionalization of Carbon Nanotubes
Introduction to Carbon Nanotubes – A New Carbon Allotrope
Functionalization of Carbon Nanotubes
Covalent Functionalization
Noncovalent Exohedral Functionalization–Functionalization with Biomolecules
Endohedral Functionalization
Conclusions
Experimental
Cyclophenacene Cut Out of Fullerene
Introduction
Synthesis of [10]Cyclophenacene ¿-Conjugated Systems from [60]Fullerene
Conclusion
Experimental
Strategic Advances in Chromophore and Materials Synthesis
Cruciform ¿-Conjugated Oligomers
Introduction
Oligomers with a Tetrahedral Core Unit
Oligomers with a Tetrasubstituted Benzene Core
Oligomers with a Tetrasubstituted Biaryl Core
Conclusion
Experimental
Design of ¿-Conjugated Systems Using Organophosphorus Building Blocks
Introduction
Phosphole-containing ¿-Conjugated Systems
Phosphine-containing ¿-Conjugated Systems
Phosphaalkene- and Diphosphene-containing ¿jugated Systems
Conclusion
Selected Experimental Procedures
Diversity-oriented Synthesis of Chromophores by Combinatorial Strategies and Multi-component Reactions
Introduction
Combinatorial Syntheses of Chromophores
Novel Multi-component Syntheses of Chromophores
Conclusion and Outlook
Experimental Procedures
High-yield Synthesis of Shape-persistent Phenylene–Ethynylene Macrocycles
Introduction
Synthesis
Conclusion
Experimental Procedures
Functional Materials via Multiple Noncovalent Interactions
Introduction
Biologically Inspired Materials via Multi-step Self-assembly
Small Molecule-based Multi-step Self-assembly
Polymer-based Self-assembly
Conclusion and Outlook
Molecular Muscles, Switches and Electronics
Molecular Motors and Muscles
Introduction
Mechanically Interlocked Molecules as Artificial Molecular Machines
Chemically Induced Switching of the Bistable Rotaxanes
Electrochemically Controllable Bistable Rotaxanes
Photochemically Powered Molecular Switches
Conclusions
Diarylethene as a Photoswitching Unit of Intramolecular Magnetic Interaction
Introduction
Photochromic Spin Coupler
Synthesis of Diarylethene Biradicals
Photoswitching Using Bis(3-thienyl)ethene
Reversed Photoswitching Using Bis(2-thienyl)ethene.9
Table of Contents provided by Publisher. All Rights Reserved.

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Functional Organic Materials Syntheses, Strategies and Applications

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Functional Organic Materials Syntheses, Strategies and Applications

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