Future of Glycerol

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ISBN: 9781849730464 | 1849730466
Cover: Hardcover
Copyright: 6/15/2010

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By-products of global biodiesel manufacturing are a modern day global fact responsible for igniting a number of years of worldwide intense research activity into human chemical ingenuity.

About the Authors	p. xiv
Acknowledgements	p. xvi
Glycerol: Properties and Production	p. 1
Properties of Glycerol	p. 1
Traditional Commercial Applications	p. 6
Production of Bioglycerol and Commercial Trends	p. 10
Glycerol as Solvent in Organic Reactions	p. 20
Bioglycerol Purification	p. 23
References	p. 25
Reforming	p. 29
Glycerol as a Platform for Green Fuels	p. 29
Production of Hydrogen via Aqueous Phase Reforming	p. 32
Production of Hydrocarbon Fuels via Aqueous Phase Reforming	p. 36
Industrial Applications	p. 40
References	p. 42
Selective Reduction	p. 45
Reduction of Glycerol	p. 45
Hydrogenolysis to Propylene Glycol	p. 45
Dehydroxylation to 1,3-Propanediol	p. 50
Biological reduction to PDO	p. 51
Commercial Applications	p. 53
References	p. 56
Chlorination	p. 59
Chlorination of Glycerol	p. 59
Production of Epichlorohydrin	p. 62
Industrial Applications	p. 65
References	p. 68
Dehydration	p. 70
Dehydration of Glycerol	p. 70
Dehydration to Acrolein	p. 71
Propane from Acrolein	p. 77
Oxydehydration to Acrylic Acid	p. 80
Dehydration to 3-Hydroxypropionaldehyde	p. 81
Industrial Applications	p. 82
References	p. 84
Etherification	p. 87
Etherification of Glycerol	p. 87
Butylation of glycerol tert-butyl ethers	p. 87
Direct Telomerization and Etherification over CaO	p. 93
Polymerization to Polyglycerol	p. 95
Glycosylalion to Glucosyl Glycerol	p. 97
Industrial Applications	p. 97
References	p. 99
Esterification	p. 102
Esterification of Glycerol	p. 102
Esterification with Carboxylic Acids and Glycerolysis	p. 102
Carboxylation to Glycerol Carbonate	p. 107
Nitration	p. 109
Industrial Applications	p. 110
References	p. 112
Selective Oxidation	p. 115
Selective Oxidation of Glycerol	p. 115
Thermodynamic and Kinetic Aspects of Aerobic C-OH Oxidation	p. 118
Platinum-Group Metal Catalysis	p. 119
Gold and Organocatalysis	p. 122
Oxidation Using an Iron Catalyst	p. 124
Electrochemical Oxidation	p. 126
Biological Oxidation	p. 128
References	p. 131
Bioglycerol in the Construction Industry	p. 135
Polyols as Additives for Cement	p. 135
Glycerol as Anticracking and Waterproofing Agent	p. 139
Raw Glycerol as Quality Enhancer and Grinding Aid	p. 140
Bioglycerol as Anticorrosive Lubricant	p. 142
References	p. 147
Sustainability of Bioglycerol	p. 149
Biofuels: A Triple Bottom Line Analysis	p. 149
Bioglycerol Economics	p. 153
Glycerol: A Platform Chemical for the Biorefinery	p. 160
References	p. 163
Subject Index	p. 166
Table of Contents provided by Ingram. All Rights Reserved.

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Future of Glycerol

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Future of Glycerol

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