Introduces a special class of polymeric liquid exchanger (PLE) with high affinities for anionic ligands, covering a number of related topics. Treats ion exchange both as discrete topics and together as multidisciplinary study.
Preface
iii
Contributors to Volume 14
vii
Contents of Other Volumes
xiii
Polymer-Supported Reagents: The Role of Bifunctionality in the Design of Ion-Selective Complexants
1
(36)
Spiro D. Alexandratos
Introduction
1
(1)
Ion Exchange Resins and the Development of Ion-Selective Polymers
Synthesis and Application of Functionalized Organo-Ceramic Selective Adsorbents
169
(60)
Lawrence L. Tavlarides
J. S. Lee
Introduction
169
(1)
Synthesis of Solid Supported Extraction Materials
170
(14)
Characterization of Extraction Materials
184
(11)
Aqueous Phase Equilibrium
195
(5)
Metal Ion Adsorption on Supported Extractants
200
(6)
Adsorption Kinetics of Metal Ion on Adsorbents and Ion Exchangers
206
(4)
Metal Ion Adsorption in Packed Beds
210
(7)
Applications
217
(12)
References
223
(6)
Environmental Separation Through Polymeric Ligand Exchange
229
(30)
Arup K. SenGupta
Introduction
229
(2)
Characterization of the Polymeric Ligand Exchanger and Goals
231
(5)
Results, Performance Benchmarking, and Modeling
236
(19)
Conclusion
255
(4)
References
256
(3)
Imprinted Metal-Selective Ion Exchanger
259
(36)
Masahiro Goto
Introduction
259
(1)
Concept of the Molecular Imprinting Technique
260
(2)
The Surface Molecular Imprinting Technique
262
(17)
Application to the Separation of Lanthanide Ions
279
(4)
Preparation of Metal-Imprinted Microspheres
283
(8)
New Directions
291
(4)
References
292
(3)
Synthesis and Characterization of a New Class of Hybrid Inorganic Sorbents for Heavy Metals Removal
295
(58)
Arthur D. Kney
Arup K. SenGupta
Introduction
295
(9)
Experimental Materials and Procedures
304
(6)
Results and Discussion
310
(38)
Conclusion
348
(5)
Acronyms
349
(1)
References
350
(3)
Index
353
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