Ionic Liquids Industrial Applications for

The first book devoted to room-temperature ionic liquids, and it is a must for chemists interested in environmental protection, synthesis, catalysis, or the modern chemical industry.

Preface

xiii

Ionic Liquids in Context

Green Chemistry and Ionic Liquids: Synergies and Ironies

2

(13)

John D. Holbrey

Robin D. Rogers

Neoteric Solvents: An Examination of Their Industrial Attractiveness

15

(15)

Christopher J. Adams

Are Ionic Liquids Green Solvents?

30

(12)

William M. Nelson

Organic Reactions in Ionic Liquids and on Supported Reagents

42

(16)

Richard M. Pagni

George W. Kabalka

Carlos Lee

Rama R. Malladi

Bradley Collins

Nicie Conley

Separations and Engineering

Ionic Liquids as Novel Diluents for Solvent Extraction of Metal Salts by Crown Ethers

58

(11)

Richard A. Bartsch

Sangki Chun

Sergei V. Dzyuba

Supported Ionic Liquid Membranes and Facilitated Ionic Liquid Membranes

69

(21)

Paul Scovazzo

Ann E. Visser

James H. Davis .Jr

Robin D. Rogers

Carl A. Koval

Dan L. DuBois

Richard D. Noble

Green Synthesis

Ionic Liquids: Solvents for the Twenty-First Century

90

(16)

Martyn J. Earle

Preparation of Functional Silica Aerogels Using Ionic Liquids as Solvents

106

(8)

C. Y. Yuan

S. Dai

Y. Wei

Y. W. Chen-Yang

Homopolymerization and Block Copolymer Formation in Room-Temperature Ionic Liquids Using Conventional Free-Radical Initiators

114

(11)

Hongwei Zhang

Lujia Bu

Meichun Li

Kunlun Hong

Ann E. Visser

Robin D. Rogers

Jimmy W. Mays

Effect of Room-Temperature Ionic Liquids as Replacements for Volatile Organic Solvents in Free-Radical Polymerization

125

(9)

Michael G. Benton

Christopher S. Brazel

Green Synthesis: Aromatic Nitrations in Room-Temperature Ionic Liquids

134

(13)

Scott T. Handy

Cristina R. Egrie

Potential Application of Ionic Liquids for Olefin Oligomerization

147

(15)

A. Ranwell

M. A. Tshamano

Nuclear Chemistry and Electrochemistry

Ionic Liquids for the Nuclear Industry: A Radiochemical, Structural, and Electrochemical Investigation

162

(16)

G. M. N. Baston

A. E. Bradley

T. Gorman

I. Hamblett

C. Hardacre

J. E. Hatter

M. J. F. Healy

B. Hodgson

R. Lewin

K. V. Lovell

G. W. A. Newton

M. Nieuwenhuyzen

W. R. Pitner

D. W. Rooney

D. Sanders

K. R. Seddon

H. E. Simms

R. C. Thied

Nuclear Chemistry and Electrochemistry: Superoxide Ion Electrochemistry in Ionic Liquids

178

(10)

M. L. Leonard

M. C. Kittle

I. M. AlNashef

M. A. Matthews

J. W. Weidner

Development of Room-Temperature Ionic Liquids for Applications in Actinide Chemistry

188

(11)

Warren J. Oldham Jr.

David A. Costa

Wayne H. Smith

Ionic Liquids and Metal Ions: From Green Chemistry to Ore Refining

199

(15)

Adam McCluskey

Geoffrey A. Lawrance

Sarah K. Leitch

Michael P. Owen

Ian C. Hamilton

Ionic Liquid Systems

Ionic Liquids in Perspective: The Past with an Eye Toward the Industrial Future

214

(16)

John S. Wilkes

Significance of Cations in Ionic Liquids Chemistry

230

(11)

Keith E. Johnson

Li Xiao

Gordon Driver

Dynamic Supramolecular Chemistry: The Role of Hydrogen Bonding in Controlling the Selectivity of Diels-Alder Reactions in Room-Temperature Ionic Liquids

241

(6)

Alick R. Sethi

Tom Welton

Working Salts: Syntheses and Uses of Ionic Liquids Containing Functionalized Ions

247

(13)

James H. Davis, Jr.

Properties of Ionic Liquids

Gas Solubilities in 1-n-Butyl-3-methylimidazolium Hexafluorophosphate

260

(10)

Jennifer L. Anthony

Edward J. Maginn

Joan F. Brennecke

Free-Energy Relationships and Solvatochromatic Properties of 1-Alkyl-3-methylimidazolium Ionic Liquids

270

(19)

Jonathan G. Huddleston

Grant A. Broker

Heather D. Willauer

Robin D. Rogers

Characterization of Hydrophilic and Hydrophobic Ionic Liquids: Alternatives to Volatile Organic Compounds for Liquid-Liquid Separations

289

(21)

Ann E. Visser

W. Matthew Reichert

Richard P. Swatloski

Heather D. Willauer

Jonathan G. Huddleston

Robin D. Rogers

Catalysis

Palladium-Catalyzed Carbon-Carbon Coupling Reactions in Room-Temperature Ionic Liquids

310

(11)

Paul J. Smith

Tom Welton

Catalytic Oxidations in tonic Liquids

321

(13)

Gregory S. Owens

Mahdi M. Abu-Omar

Transition-Metal-Catalyzed Hydrosilylation and Hydroboration of Terminal Alkynes in Ionic Liquids

334

(13)

S. Aubin

F. Le Floch

D. Carrie

J. P. Guegan

M. Vaultier

Application of Room-Temperature Ionic Liquids in Biocatalysis: Opportunities and Challenges

347

(13)

Nicola J. Roberts

Gary J. Lye

Room-Temperature Ionic Liquids as New Solvents for Carbohydrate Chemistry: A New Tool for the Processing of Biomass Feedstocks?

360

(13)

Noshena Khan

Luc Moens

Biphasic Hydroformylation Using tonic Liquids

373

(14)

Peter Wasserscheid

Horst Waffenschmidt

Chymotrypsin-Catalyzed Transesterification in Ionic Liquids and Ionic Liquid/Supercritical Carbon Dioxide

387

(13)

Joseph A. Laszlo

David L. Compton

Structure and Photochemistry

Small-Angle Scattering from Long-Chain Alkylimidazolium-Based Ionic Liquids

400

(13)

C. Hardacre

J. D. Holbrey

S. E. J. McMath

M. Nieuwenhuyzen

Structure-Property Relationships in Ionic Liquids

413

(15)

James D. Martin

Photochemistry in Ionic Liquids

428

(18)

Charles M. Gordon

Andrew J. McLean

Mark J. Muldoon

Ian R. Dunkin

Technology Review

Green Industrial Applications of Ionic Liquids: Technology Review

446

(13)

John D. Holbrey

Robin D. Rogers

Author Index

459

(2)

Subject Index

461

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Ionic Liquids Industrial Applications for Green Chemistry

Summary

Table of Contents

Supplemental Materials