Macromolecules Containing Metal and

Metal- and metalloid-containing macromolecules are defined as large molecules (i.e., polymers, DNA, proteins) that contain a metal or metalloid group affiliated with the molecule. This volume describes what is possible with metal-containing polymers where the metal is an essential ingredient in obtaining desired optical and electronic properties. Covering applications in nonlinear optical materials, solar cells, light-emitting diodes, photovoltaic cells, field-effect transistors, chemosensing devices, and biosensing devices, this indispensible guide focuses on the photochemistry and photophysics of metal-containing polymers, with chapters by leading contributors to the core advances in this field.

Alaa S. Abd-El-Aziz is the Associate Vice-President (Academic and Research) at theUniversity ofBritish Columbia Okanagan. In 1997, he was named a Fellow of the Chemical Institute of Canada, and has been the recipient of a number of awards including the Manitoba Outstanding Chemist Award, the Erica & Arnold Rogers Award for Excellence in Research and Scholarship, and the Clifford J. Robson Memorial Award for Excellence in Teaching.

Charles Carraher is Professor of Chemistry atFloridaAtlanticUniversity and Associate Director of theFloridaCenter for Environmental Studies. Dr. Carraher previously was Dean of the Charles E.Schmidt College of Science at FAU, Chair of the Science Division at theUniversity of South Dakota and Chair of the Department of Chemistry at Wright State University. His research deals with the general topic of polymers as applied to electronics, computers, biomedicine, instrumentation and construction.

Pierre Harvey is Professor of Chemistry at the University of Sherbrooke.

Charles Pittman came to Mississippi State in 1983 as Professor of Industrial Chemistry and Catalysis. He was appointed Full Professor in 1975 and University Research Professor in 1977. He is also Research Director of the University/Industry Chemical Research Center.

Martin Zeldin is Visiting Senior Research Scholar at the University of Richmond in Virginia. He received his Ph.D. in inorganic chemistry in 1968 from Pennsylvania State University.

Preface
Series Preface
Introduction to Photophysics and Photochemistry
General
Photophysics and Photochemistry
Light Absorption
Luminescence
Emission Lifetime
Ground and Excited State Molecular Interactions
Energy and Electron Transfer Excited State Interactions Reactions
Energy Transfer
Electron Transfer
Nonlinear Optical Behavior
Photoconductive and Photonic Polymers
Photosynthesis
Purple Photosynthetic Bacteria
Green Sulfur Bacteria
Organometallic Polymers and Synthetic Photosynthesis Systems
Summary
References Additional Readings
References
Luminescent Organometallic Coordination Polymers Built on Isocyanide Bridging Ligands
Introduction
Luminescent Organometallic Polynuclear Systems and Coordination Polymers Containing a Terminal Isocyanide Ligand
Luminescent Polymeric Systems Containing an Isocyanide Ligand Assembled via M...M Interactions
Luminescent Organometallic Polymetallic Systems and Coordination Polymers Containing Bridging Isocyanides
Conclusion
Acknowledgments
References
Luminescent Oligomeric and Polymeric Copper Coordination Compounds Assembled by Thioether Ligands
Introduction
Background Informations
Luminescent Copper Polymers Assembled by Thioether Ligands
Copper Polymers Assembled by Monothioether Ligands RSR
Copper Polymers Assembled by Aromatic Dithioether Ligands
Copper Polymers Assembled by Aliphatic Dithioether and Polythioether Ligands
Copper Polymers Assembled by Dithioether and Polythioether Ligands Bearing Heteroelements in the Spacer Unit
Conclusion
Acknowledgments
References
Applications of Metal Containing Polymers in Organic Solar Cells
Introduction
Types of Organic Solar Cells
Dye-Sensitized Solar Cells
Organic Thin Film Solar cells
Solar Cell Characterizations
Metal Containing Polymers in Solar Cells
Dye-Sensitized Solar Cells
Organic Thin Film Solar Cells
Summary
Acknowledgments
References
Functional Silole-Containing Polymers
Introduction
Electronic Transition and Band Gap
Light Emission
Photoluminescence
Electroluminescence
Bulk-Heterojuction Photovoltaic Cells
Field Effect Transistors
Aggregation-Induced Emission
Chemosensors
Conductivity
Optical Limiting
Summary
Acknowledgments
References
Photophysics and Photochemistry of Polysilanes for Electronic Applications
Introduction
Synthesis of Electronic-Grade Polysilanes
Band Structure
Photophysics
Influence of the Backbone Structure
Side Groups
Nanostructured Polysilanes
PL Quenching by Doping
Energy Transfer
Electroluminescence
Cathodoluminescence
Interaction with Photoelectrons
Photochemistry
Photo-Oxidation
Polysilane Thin Films for Electronic Devices
LED
Photoconductors
Photovoltaics
Lithography
Electron Beam
Polysilane Films for Optical Devices
NLO
Summary
References
Polymers with Metal-Metal Bonds as Models in Mechanistic Studies of Polymer Photodegradation
Introduction
Experimental Strategies
Synthesis of Polymers with Metal-Metal Bonds along their Backbones
Step-Growth Polymers
ADMET Polymerization
Chain-Growth Polymers
Photochemical Reactions of the Polymers in Solution
Photochemistry in the Solid State
Factors Controlling the Rate of Polymer Photochemical Degradation in the Solid State
Temperature Effects
Interpreting the Kinetics of Polymer Degradation in the Solid State
Photodegradation Rate Dependence on Polymer Curing Time
The Effects of Stress on Polymer Degradation
Kinetics of Polymer Formation
Concluding Remarks on the Importance of Radical-Radical Recombination on the Efficiency of Polymer Photochemical Degradation
Acknowledgments
References
Optical Properties and Photophysics of Platinum-Containing Poly (aryleneethynylene)
Introduction
Synthetic Methods and Materials Characterization
Optical and Photophysical Properties
Energy Gap Law for Triplet States
Phosphorescence Color Tuning of Metallopolyynes
Roles of Metallopolyynes in Optoelectronic and Photonic Devices
Summary
Acknowledgments
References
Luminescence in Polymetallic Gold-Heteronuclear Derivatives
Introduction and Background
Luminescent Gold-Silver Derivatives
Supramolecular Gold-Silver Complexes with Bidentate Ligands
Supramolecular Gold-Silver Complexes with Tridentate Ligands
Supramolecular Gold-Silver Complexes Built with Metallic Cationic and Anionic Counterparts
Luminescent Gold-Copper Derivatives
Luminescent Gold-Thallium Derivatives
Supramolecular Gold-Thallium Complexes with Bidentate Ligands
Supramolecular Gold-Thallium Complexes through Acid-Base Reactions
Luminescent Gold-Lead Derivatives
Luminescent Gold-Platinum Derivatives
Luminescent Gold-Mercury Derivatives
Conclusion
References
Functional Self-Assembled Zinc(II) Coordination Polymers
Introduction
Zinc(II) Terpyridine Polymers
Zinc(II) Schiff Base Polymer
Summary
Acknowledgment
References
Redox and Photo Functions of Metal Complex Oligomer and Polymer Wires on the Electrode
Introduction
Bottom-Up Fabrication of Redox-Conducting Metal Complex Oligomers on an Electrode Surface and Their Redox Conduction Behavior
Bottom-Up Fabrication of Metal Complex Oligomer and Polymer Wires
Electron Transport Behavior of the Molecular Wires on the Electrode
Photoelectric Conversion System Using Porphyrin and Redox-Conducting Metal Complex Wires
Bottom-Up Fabrication of the Porphyrin-Terminated Redox-Conducting Metal Complex Film on ITO
Photoelectrochemical Properties of the Porphyrin-Terminated Redox-Conducting Metal Complex Film on ITO
Biophotosensor and Biophotoelectrode Composed of Cyanobacterial Photosystem I and Molecular Wires
Biophotosensor Composed of Cyanobacterial Photosystem I, Molecular Wire, Gold Nanoparticle, and Transistor
Biophotoelectrode Composed of Cyanobacterial Photosystem I and Molecular Wires
Conclusion
References
Index
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Macromolecules Containing Metal and Metal-Like Elements, Volume 10 Photophysics and Photochemistry of Metal-Containing Polymers

Summary

Author Biography

Table of Contents

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