Macromolecules Containing Metal and Metal-Like Elements, Metal-Coordination Polymers

, by Abd-El-Aziz, Alaa S.; Carraher, Charles E.; Pittman, Charles U.; Zeldin, Martel

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ISBN: 9780471682370 | 0471682373
Cover: Hardcover
Copyright: 6/29/2005

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This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. The fifth volume in this series provides useful descriptions of the transition metals and their applications. Transition Metals are covered in 2 volumes, the second part is covered in Volume 6.

Preface

xiii

Series Preface

Introduction to Metal-Coordination Polymers

(38)

Charles E. Carraher Jr.

Charles U. Pittman Jr.

Alaa S. Abd-El-Aziz

Introduction

(1)

Polymer Solubility

(2)

Polymer Formation

(9)

Complex Structures

(5)

Schiff Base Polymers

(2)

Porphyrin Systems

(2)

Phthalocyanine Systems

(1)

Pyridine and Related Systems

(3)

Miscellaneous Ring and Multisite Systems

(1)

Coordination Networks Constructed from Organometallic Ligand Spacers

(6)

References

(5)

Synthetic Strategies for Inert Metal-Skeletal Polymers

(30)

Ronald D. Archer

Overview Of Metal-Skeletal Polymers

(4)

Step-Growth Synthesis

(13)

Step-Condensation Synthetic Generalities

(3)

Synthesis via Functionalized Metal Species

(2)

Synthesis via Bridging Ligand Coordination

(5)

Synthesis via Bridging Ligand Formation

(2)

Step-Addition Syntheses

(1)

Chain Polymerization

(3)

Radical Polymerization

(1)

Cationic Polymerization

(1)

Anionic Polymerization

(1)

Ring-Opening Polymerization

(2)

Coordination Ring-Opening Polymerization

(1)

Organometallic Ring-Opening Polymerization

(1)

Redox Polymerization

(3)

Reductive Coupling Synthesis

(1)

Oxidative Coupling Synthesis

(2)

Miscellaneous Redox Synthesis

(1)

Conclusions

(1)

Acknowledgments

(1)

References

(3)

Metallo-Supramolecular Polymers: Synthesis, Material Properties, and Potential Future Applications

(14)

Stefan Schmatloch

Harald Hofmeier

Ulrich S. Schubert

Introduction

(1)

Metallo-Supramolecular Polymers

(10)

Linear Coordination Polymers

(1)

Synthetic Strategies

(2)

``Switching'' (Reversing) the Metal--Ligand Bonding

(2)

Thin-Film Morphology

(1)

Terpyridine-Containing Poly(methyl methacrylate)s

(1)

Copolymers

(1)

Terpolymers

(4)

Summary

(1)

Acknowledgments

(1)

References

(3)

Coordination/Organometallic Oligomers and Polymers of Palladium and Platinum: Focus on Metal-Containing Backbone

(34)

Pierre D. Harvey

Introduction

(1)

Mono-Palladium and Platinum Fragment-Containing Polymers

(29)

Organometallic and Coordination Polymers (M--C)

(8)

Coordination Polymers via the M--N Bond

(4)

Coordination/Organometallic Polymers with Cyanide, Isocyanide, and Nitrile Bridges

(4)

Coordination Polymers via the M--O, M--S, and M--P Bonds

100

(8)

Organometallic Polymers with Bi-, Tri-, and Tetranuclear Clusters

108

(4)

Polymers Built Upon Weak Homonuclear M...M Interactions

112

(1)

Conclusion

113

(1)

Acknowledgments

113

(1)

References

114

(3)

Metal-Containing Polymers for Optoelectronic Applications

117

(24)

Wai Kin Chan

Introduction

118

(1)

Background

119

(3)

Metal Complexes Used

119

(1)

Metal Complexes as Electroluminescence Materials

120

(1)

Metal Complexes as Photosensitizing Materials

121

(1)

Metal Complexes in Conjugated Main Chain

122

(12)

Poly(p-Phenylenevinylene) Incorporated with [Ru(tpy)2]2+ Complexes

122

(2)

Conjugated Polymers with Ruthenium Dipyridophenazine Complexes

124

(4)

Conjugated Polymers with Aromatic Oxadiazole and Phenanthroline Moieties

128

(3)

Metal Complex on Other Types of Polymer Main Chain

131

(3)

Conjugated Polymers with Pendant Metal Complexes

134

(2)

Metal-Containing Polymers for Ultrathin Film Formation

136

(1)

Summary

136

(1)

Acknowledgments

137

(1)

References

137

(4)

Novel Polyphenylazomethine Dendrimer Complexes for Fine-Controlled Metallorganic Hybrid Materials

141

(14)

Kimihisa Yamamoto

Masayoshi Higuchi

Introduction

142

(1)

Metallorganic Hybrid Nanomaterials

143

(2)

Organic Compounds Into Inorganic Mesoporous Materials

143

(1)

Metal Ions Into Organic Polymers

144

(1)

Dendrimer-Metal Complexes

145

(3)

Dendrimers: Structures and Synthesis

145

(1)

Metallodendrimers

146

(1)

Metal-Assembling in Organic Dendrimers

147

(1)

Precise Control of Metal Ions In Dendritic Polyphenylazomethines

148

(5)

Stepwise Complexation with Metal Ions in Dendritic Polyphenylazomethines

148

(2)

Shell-Selective Reduction of Imines in DPAs

150

(1)

A Molecular Size of the Dendrimer-Metal Complex

151

(1)

Dendrimer Assembling on a Plate

152

(1)

Conclusion

153

(1)

References

154

(1)

Structural Diversity, Physical Properties, and Applications of Cyanometalate Coordination Polymers

155

(54)

Julie Lefebvre

Daniel B. Leznoff

Introduction

156

(2)

Structural Diversity of Cyanometalate Coordination Polymers

158

(22)

Hexacyanometalate [M(CN)6]n- Building Blocks

158

(7)

Tetracyanometalate [M(CN)4]n- Building Blocks

165

(4)

Dicyanometalate [M(CN)2]n- Building Blocks

169

(5)

Hepta- and Octacyanometalate [M(CN)7/8]n- Building Blocks

174

(2)

Deca- and Dodecacyanometalate Building Blocks

176

(1)

Heteroleptic [M(CN)xL]n- Building Blocks

177

(2)

Discrete Clusters

179

(1)

Magnetic Properties Of Cyanometalate Coordination Polymers

180

(12)

Prussian Blue Analogues with High Critical Ordering Temperatures

180

(2)

Photomagnetism

182

(2)

Influence of the Building Blocks on Resultant Magnetic Properties

184

(4)

Metamagnetism

188

(1)

Spin Cross-Over Phenomena

189

(2)

Clusters

191

(1)

Materials and Applications

192

(5)

Inclusion Compounds---Mineralomimetic Structures

192

(1)

Sensors

193

(2)

Catalysis

195

(1)

Prussian Blue-Modified Electrodes

195

(2)

Prussian Blue-Based Nanostructures

197

(1)

Concluding Remarks

197

(1)

Acknowledgments

198

(1)

References

198

(11)

Metal Conjugates with Redox-Active π-Conjugated Polymers or Molecules

209

(18)

Toshikazu Hirao

Introduction

210

(1)

Catalysis Of Metal Conjugates

210

(3)

Synthetic Metal Catalytic System

210

(1)

Synthetic Metal-Transition Metal Catalytic System

211

(1)

Redox-Active Ligand in Metal-Catalyzed Reaction

212

(1)

Conjugated Complex

213

(6)

Design of a Conjugated Complex

213

(1)

A Conjugated Polymer Complex

214

(1)

A Conjugated Complex of Quinonediimine

215

(4)

A Functionalized π-Conjugated System

219

(5)

Three-Dimensional π-Electronic System

219

(2)

π-Conjugated System Functionalized by a Complex

221

(3)

Conclusion

224

(1)

Acknowledgments

225

(1)

References

225

(2)

Catalytic Activity of Macromolecules Obtained from Metal-Containing Monomers

227

(32)

Piero Mastrorilli

Cosimo Francesco Nobile

Introduction

228

(2)

Nitrogen and Mixed Nitrogen/Oxygen Ligands

230

(8)

Ligands Bound by Oxygen Atoms

238

(11)

Ligands Bound by Phosphorus Atoms

249

(2)

Ligands Bound by Carbon Atoms

251

(3)

Outlook

254

(1)

References

255

(4)

Organometalloligands as Components in Supramolecular Coordination Networks

259

(26)

Moonhyun Oh

Jeffrey A. Reingold

Dwight A. Sweigart

Introduction

260

(20)

Supramolecular Organometallic Systems not Based on Coordination-Directed Self-Assembly

261

(4)

Discrete Organometallic Supramolecular Networks Formed via Self-Assembly

265

(4)

Polymeric Organometallic Coordination Networks Formed via Self-Assembly

269

(9)

Lanthanide-Based Organometallic Coordination Networks

278

(2)

Conclusion

280

(1)

Acknowledgments

280

(1)

References

280

(5)

Metal Complexes of π-Conjugated Polymers and Related Polymers

285

(12)

Takakazu Yamamoto

Hiroki Fukumoto

Introduction

286

(1)

Preparation of Metal Complexes of π-Conjugated Polymers and Chemical Properties and Functionalities of the Metal Complex

287

(4)

Preparation of π-Conjugated Chelating Polymer Ligands and Their Metal Complexes

287

(3)

Polymerization of Metal Complexes

290

(1)

Chemical Properties and Functionalities of the Metal Complexes of π-Conjugated Polymers

291

(3)

Electronic and Optical Properties

291

(1)

Catalytic Behavior

292

(2)

References

294

(3)

Polyamides Containing Metals

297

(28)

Issifu I. Harruna

Odessa N. Petzold

Introduction

298

(1)

Polyamide--Metal Systems

298

(14)

Polyamides Containing a Pyridine Chelating Moiety

298

(2)

Polyamides Containing a Bipyridyl Chelating Moiety

300

(5)

Polymers Containing a Piperazine Moiety

305

(2)

Fully Aliphatic Polyamide Metal Chelates

307

(5)

Applications of Polyamide--Metal Systems

312

(9)

Catalyst Supports and Catalysts

312

(7)

Therapeutics

319

(1)

Chromatography

320

(1)

Extension of Shelf Life

321

(1)

Summary

321

(1)

References

321

(4)

Ruthenium-Containing Polymers for Solar Energy Conversion

325

(18)

Charles E. Carraher Jr.

Amanda Taylor Murphy

Introduction

326

(1)

Photointeractive Polymers

326

(3)

Solar Energy Conversion

329

(4)

Current Efforts

333

(5)

Future Directions

338

(1)

References

339

(4)

Uranium-Containing Polymers

343

(38)

Charles E. Carraher Jr.

Background

344

(2)

Salts of Dicarboxylic Acids

346

(4)

Salts of Polycarboxylic Acids

350

(2)

Oxygen-Bonded Complexes

352

(7)

Resins

359

(3)

Nitrogen-Bonded Complexes: General

362

(1)

Nitrogen-Coordinated Polymer Backbones

363

(1)

Pendant Nitrogen-Coordinated Polymers

364

(5)

Mixed Nitrogen and Oxygen Complexes

369

(9)

Chitosan

378

(2)

Phosphorus-Containing Materials

380

(1)

Summary

380

(1)

References

381

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Macromolecules Containing Metal and Metal-Like Elements, Metal-Coordination Polymers

Summary

Author Biography

Table of Contents

Supplemental Materials

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Macromolecules Containing Metal and Metal-Like Elements, Metal-Coordination Polymers

Summary

Author Biography

Table of Contents

Supplemental Materials

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