Magnetoelectric Polymer-Based Composites Fundamentals and Applications
, by Lanceros-Mé; ndez, Senentxu; Martins, Pedro
- ISBN: 9783527341276 | 3527341277
- Cover: Hardcover
- Copyright: 10/23/2017
The first book on this topic provides a comprehensive and well-structured overview of the fundamentals, synthesis and emerging applications of magnetoelectric polymer materials.
Following an introduction to the basic aspects of polymer based magnetoelectric materials and recent developments, subsequent chapters discuss the various types as well as their synthesis and characterization. There then follows a review of the latest applications, such as memories, sensors and actuators. The book concludes with a look at future technological advances.
An essential reference for entrants to the field as well as for experienced researchers.
Following an introduction to the basic aspects of polymer based magnetoelectric materials and recent developments, subsequent chapters discuss the various types as well as their synthesis and characterization. There then follows a review of the latest applications, such as memories, sensors and actuators. The book concludes with a look at future technological advances.
An essential reference for entrants to the field as well as for experienced researchers.
S. Lanceros-Méndez graduated in physics at the University of the Basque Country, Leioa, Spain. He obtained his PhD degree at the Institute of Physics of the Julius-Maximilians-Universität Würzburg, Germany. He was Research Scholar at Montana State University, Bozeman, MT, USA and visiting scientist at the, Pennsylvania State University, USA and University of Potsdam, among others. Since 2016 he is Ikerbasque Professor at the BCMaterials, Basque Center for Materials, Applications and Nanostructures, Derio, Spain. He is Associate Professor at the Physics Department of the University of Minho, Portugal (on leave), where he belongs to the Center of Physics. From 2012 to 2014 he was also Associate Researcher at the INL - International Iberian Nanotechnology Laboratory. His work is focused in the area of smart materials for sensors and actuators, energy and biomedical applications.
Pedro Martins graduated in Physics and Chemistry in 2006 and received the PhD degree in Physics in 2012, both from the University of Minho, Braga, Portugal. From 2012 to 2014 he was also Visiting Researcher at the INL - International Iberian Nanotechnology Laboratory. He is now a postdoctoral researcher in the University of Minho, Braga, Portugal and his work is focused on polymer-based magnetoelectric materials and electroactive polymers for advanced technological applications. He collaborates with the Basque Country University, Spain; Wollongong University, Australia and Cambridge University, United Kingdom, among others.
Pedro Martins graduated in Physics and Chemistry in 2006 and received the PhD degree in Physics in 2012, both from the University of Minho, Braga, Portugal. From 2012 to 2014 he was also Visiting Researcher at the INL - International Iberian Nanotechnology Laboratory. He is now a postdoctoral researcher in the University of Minho, Braga, Portugal and his work is focused on polymer-based magnetoelectric materials and electroactive polymers for advanced technological applications. He collaborates with the Basque Country University, Spain; Wollongong University, Australia and Cambridge University, United Kingdom, among others.
List of Contributors xi
Preface and Acknowledgments xv
1 Magnetoelectric Effect of Functional Materials: Theoretical Analysis,Modeling, and Experiment 1
Jia-Wei Zhang, Hong-Yan Guo, Xiao Chen, and Rui-Tong Liu
1.1 Introduction of Magnetoelectric Effect 1
1.1.1 Single-Phase Magnetoelectric Materials 1
1.1.2 Multiphase Materials 2
1.2 Applications of Magnetoelectric Effect 2
1.2.1 Magnetoelectric Sensors 3
1.2.2 Magnetoelectric Transducer 3
1.2.3 Magnetoelectric Microwave Devices 4
1.3 Magnetoelectric Effect of Piezoelectric Ceramic 4
1.4 Magnetoelectric Effect in Insulating Polymers 7
1.5 Conclusion 11
Acknowledgments 11
References 11
2 Materials Selection, Processing, and Characterization Technologies 13
JingMa, Lu Song, Chen Liu, and Chengzhou Xin
2.1 Introduction 13
2.2 Materials Selection and Processing 14
2.2.1 Polymer as the Piezoelectric/Ferroelectric Phase 15
2.2.2 Piezoelectric Polymer as the Matrix 17
2.2.3 Non-piezoelectric Polymer as the Active Matrix 18
2.2.4 Polymer as the Binder 18
2.3 Characterization Technologies 19
2.3.1 Ferroelectric and Piezoelectric Characterization 19
2.3.1.1 Piezoelectric Characterization 19
2.3.1.2 Ferroelectric Characterization 20
2.3.2 Magnetostrictive and Magnetism Characterization 22
2.3.2.1 MagnetismMeasurement 23
2.3.2.2 MagnetostrictionMeasurement 26
2.3.3 Characterization of Magnetoelectric Coupling 27
2.3.3.1 Direct Magnetoelectric Coupling 27
2.3.3.2 Converse Magnetoelectric Coupling 30
2.4 Concluding Remarks 34
Acknowledgments 34
References 34
3 Types of Polymer-BasedMagnetoelectric Materials 45
3a Laminates 47
Marco Silva, PedroMartins, and Senentxu Lanceros-Mendez
3a.1 Introduction 47
3a.2 Laminated Magnetoelectric Composites 47
3a.3 Piezoelectric Phase for Magnetoelectric Laminates 53
3a.3.1 PVDF and Its Copolymers 53
3a.3.2 Diamines 54
3.4a Magnetostrictive Phase for Magnetoelectric Laminates 55
3a.4.1 Metglas 55
3a.4.2 VITROVAC 57
3a.4.3 Terfenol-D 57
3.5a Bonding Agent for Magnetoelectric Laminates 57
3a.6 Structures for Magnetoelectric Laminates 58
3a.7 Limitations and Remaining Challenges 59
Acknowledgments 59
References 60
3b Polymer-BasedMagnetoelectric Composites: Polymer as a Binder 65
Yang Song, De’an Pan, Zhijun Zuo, and Alex Alexei Volinsky
3b.1 Introduction 65
3b.2 Polymer-Based Tb1−xDyxFe2−y by MagneticWarm Compaction 66
3b.2.1 Experiment for MagneticWarm Compaction 66
3b.2.2 Results and Discussion of MagneticWarm Compaction 67
3b.2.3 Conclusions for MagneticWarm Compaction 70
3b.3 Multifaceted Magnetoelectric Composites 70
3b.3.1 Experiment for Multifaceted Magnetoelectric Composites 70
3b.3.2 Results and Discussion for Multifaceted Magnetoelectric Composites 70
3b.3.3 Conclusions for Multifaceted Magnetoelectric Composites 73
3b.4 Bonded Cylindrical Composites 73
3b.4.1 Experiment for Bonded Cylindrical Composites 73
3b.4.2 Results and Discussion for Bonded Cylindrical Composites 74
3b.4.3 Conclusions for Bonded Cylindrical Composites 76
3b.5 Multi-electrode Cylinder Composites 77
3b.5.1 Experiment for Multi-electrode Cylinder Composites 77
3b.5.2 Results and Discussion for Multi-electrode Cylinder Composites 78
3b.5.3 Conclusions for Multi-electrode Cylinder Composites 81
3b.6 Polymer Content and Particle Size Effects 81
3b.6.1 Experiment for Polymer Content and Particle Size Effects 81
3b.6.2 Results and Discussion for Polymer Content and Particle Size Effects 81
3b.6.3 Conclusions for Polymer Content and Particle Size Effects 83
Acknowledgments 84
References 84
3c Poly(vinylidene fluoride)-BasedMagnetoelectric Polymer Nanocomposite Films 87
Thandapani Prabhakaran and Jawaharlal Hemalatha
3c.1 Introduction 87
3c.2 Ferroelectric Polymers 89
3c.2.1 Poly(Vinylidene Fluoride) 90
3c.2.2 Crystallization of β-Phase PVDF 91
3c.2.2.1 By Solvent 91
3c.2.2.2 By the Temperature 91
3c.2.2.3 Electric Poling on PVDF 92
3c.3 The Selection of Magnetic Nanofillers 93
3c.4 ExperimentalMethods 94
3c.4.1 Materials 94
3c.4.2 Synthesis of Magnetic Nanoparticles 95
3c.4.3 Fabrication of ME Polymer Nanocomposites 95
3c.5 Characterization 96
3c.5.1 IR Vibrational Studies 96
3c.5.2 Surface Analysis on the Composites 98
3c.5.3 Magnetic Studies on MPNCs 100
3c.5.4 Correlation of F(;;) with Ferroelectric Parameters 102
3c.5.5 Magnetoelectric Effect in MPNCs 102
3c.6 Summary 107
3c.7 Future Directions 108
Acknowledgments 109
References 109
4 Low-Dimensional Polymer-BasedMagnetoelectric Structures 115
Renato Gonçalves, Senentxu Lanceros-Mendez, and Pedro Martins
4.1 Introduction 115
4.2 Magnetoelectric Spheres 117
4.3 Magnetoelectric Fibers 118
4.4 MagnetoelectricMembranes 119
4.5 Conclusions and Future Perspectives 120
Acknowledgments 121
References 122
5 Design of Magnetostrictive Nanoparticles for Magnetoelectric Composites 125
Victor Sebastian
5.1 Introduction 125
5.1.1 Magnetoelectric Composites 125
5.1.2 Magnetostriction and Magnetostrictive Materials 126
5.1.3 Ferromagnetic Ferrites 129
5.1.4 Ferroelectric Perovskites 131
5.2 Synthesis Approaches to Produce Magnetostrictive Nanoparticles for Magnetoelectric Composites 132
5.2.1 Top-Down Production Approaches 133
5.2.1.1 Mechanosynthesis or Mechanical Attrition 133
5.2.1.2 Mechanical Alloying 134
5.2.1.3 Inert-Gas Condensation Approach 134
5.2.2 Bottom-Up Production Approaches 135
5.2.2.1 Solid-State Reaction 135
5.2.2.2 Pyrolysis 136
5.2.2.3 Wet-Chemical Approaches 137
5.3 Summary and Future Perspectives 145
Acknowledgments 146
References 146
6 Applications of Polymer-BasedMagnetoelectric Materials 153
6a Sensors, Actuators, Antennas, andMemories 155
Sílvia Reis,Marco Silva, PedroMartins, and Senentxu Lanceros-Mendez
6a.1 Introduction 155
6a.2 Polymer-Based Magnetoelectric Sensors 156
6a.3 Polymer-Based Magnetoelectric Actuators 159
6a.4 Polymer-Based Magnetoelectric Antennas 161
6a.5 Polymer-Based MagnetoelectricMemories 164
6a.6 Opportunities, Limitations, and Remaining Challenges 165
Acknowledgments 166
References 166
6b Magnetoelectric Composites for Bionics Applications 171
Tian Zheng, Yan Zong, Zhilian Yue, Gordon G.Wallace, andMichael J. Higgins
6b.1 Introduction 171
6b.2 Bionics 171
6b.2.1 Implantable Electrode Devices 171
6b.2.2 Organic Electrode Materials 172
6b.2.3 New Opportunities for Advanced Electrical Stimulation 173
6b.3 Cell Interactions and Electrical Stimulation 175
6b.3.1 Synthetic Polymer-Based ME 175
6b.3.2 Nanostructured and Nanoscale ME Materials 177
6b.3.3 ME Concept for Electrical Stimulation of Cells 179
6b.4 Future Biomaterials for ME Composites 180
6b.4.1 Piezoelectric DNA, Proteins, and Microorganisms 180
6b.4.2 ME Biopolymers: Cellulose 182
6b.5 Characterization Tools for Nanoscale ME 184
6b.5.1 Piezoresponse Force Microscopy (PFM) 184
6b.5.2 Bio-Atomic Force Microscopy (Bio-AFM) 187
Acknowledgments 188
References 189
6c Energy Harvesting 197
Chess Boughey and Sohini Kar-Narayan
6c.1 Introduction 197
6c.2 Magnetoelectric Composites for Energy Harvesting 198
6c.2.1 Magnetostrictive Effect in Ferromagnetic Materials 200
6c.2.2 Piezoelectricity in Polymers 201
6c.2.3 Key Parameters, Equations, and Figures of Merit 205
6c.2.4 Magnetoelectric Effect in Piezoelectric–Ferromagnetic Composites 208
6c.3 Energy-Harvesting Devices Based on Magnetoelectric Composites 211
6c.4 Conclusion 212
References 215
6d High-Temperature Polymers for Magnetoelectric Applications 225
AlbertoMaceiras, José Luis Vilas, and LuisManuel León
6d.1 Introduction 225
6d.2 Types of Piezoelectric Polymers 226
6d.2.1 Piezocomposites 226
6d.2.2 Ferroelectrets 226
6d.2.3 Bulk Piezoelectric Polymers 229
6d.2.3.1 Semicrystalline Piezoelectric Polymers 229
6d.2.3.2 Amorphous Piezoelectric Polymers 235
6d.3 ME Effect Using Piezoelectric Polyimides 240
6d.4 Summary and Conclusions 241
References 242
7 Open Questions, Challenges, and Perspectives 255
PedroMartins and Senentxu Lanceros-Mendez
References 258
Index 259
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