Materials for Lithium-Ion Batteries

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ISBN: 9780792366508 | 0792366506
Cover: Hardcover
Copyright: 11/1/2000

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A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.

Preface

Acknowledgements

xiii

Part 1: Lectures

Design considerations for lithium batteries

(20)

C. Julien

Principles determining the potentials and capacities of electrochemical cells

(26)

R.A. Huggins

Binary electrodes under equilibrium or near-equilibrium conditions

(28)

R.A. Huggins

Better electrode materials for energy storage applications through chemistry

(30)

J.M. Tarascon

Carbon-lithium negative electrode for lithium ion batteries: main characteristics and features

105

(56)

R. Yazami

Reactivity and safety aspects of carbonaceous anodes used in lithium-ion batteries. Correlation of structural parameters and reactivity

161

(18)

G. A. Nazri

B. Yebka

Structure and electrochemistry of new lithium intercalation compounds prepared via low temperature techniques

179

(44)

J.P. Pereira-Ramos

S. Bach

J. Farcy

N. Baffier

Structure and electrochemistry of doped LiMO2 (M=Ni, Co) cathode materials

223

(18)

C. Julien

New transition metal oxide electrodes for lithium batteries

241

(22)

A. Le Gal La Salle

A. Verbaere

Y. Piffard

D. Guyomard

Electrochemical features of lithium batteries based on molybdenum-oxide compounds

263

(16)

C. Julien

B. Yebka

EXAFS: a structural probe for cathode materials in lithium ion batteries

279

(14)

M.S. Islam

B. Ammundsen

D.J. Jones

J. Roziere

Atomistic computer modelling of oxide cathode materials for lithium ion batteries

293

(16)

M.S. Islam

B. Ammundsen

Local environment in 4-volt cathode materials for Li-ion batteries

309

(18)

C. Julien

Raman spectra of anode and cathode materials

327

(14)

R. Aroca

M. Nazri

T. Lemma

A. Rougier

G. A. Nazri

Advanced impedance techniques for lithium batteries study. Part I: experimental setup

341

(8)

Z. Stoynov

Advanced impedance techniques for lithium batteries study. Part II: data processing

349

(10)

Z. Stoynov

Advanced impedance techniques for lithium batteries study. Part III: four dimensional analysis

359

(12)

Z. Stoynov

Advanced impedance techniques for lithium batteries study. Part IV: differential impedance analysis

371

(10)

Z. Stoynov

Lithium microbatteries

381

(20)

C. Julien

Fundamental aspects of electrochemical, chemical and electrostatic potentials in lithium batteries

401

(12)

W. Weppner

Chemical stability aspects of high performance lithium batteries

413

(18)

W. Weppner

Kinetic aspects of high performance solid electrolytes and electrodes

431

(20)

W. Weppner

Solid state electrochemical methods for the characterization of the kinetics, thermodynamics and phase equilibria of lithium battery materials

451

(20)

W. Weppner

Part 2: Seminars

LiNi(M)O2 layered oxides: positive electrode materials for lithium batteries

471

(6)

A. Rougier

C. Delmas

New generation of 3-volt lithiated manganese oxide for high-performance lithium batteries

477

(4)

B. Banov

A. Trifonova

A. Momchilov

B. Puresheva

Sol-gel synthesis and electrochemical characterization of polycrystalline powders and thin films of Li1+x V3O8

481

(4)

S.V. Pushko

Microstructure of Li1+x Mn2-xO4 cathode materials monitored by EPR of Mn4+

485

(6)

E. Zhecheva

R. Stoyanova

M. Gorova

EPR studies onthe microstructure of LiNi1-yCoyO2 electrode materials for lithium-ion batteries

491

(6)

R. Stoyanova

E. Zhecheva

R. Alcantara

P. Lavela

J.-L. Tirado

Mechanochemical synthesis of cathode materials for lithium batteries

497

(4)

N.V. Kosova

Electronic transport properties in LixCr0.11 V2O5.16

501

(16)

J.C. Badot

G. Gregoire

N. Baffier

7Li NMR in some lithium intercalation compounds

Taking advantage of electronic spins

507

(10)

M. Menetrier

Single conductive polymer electrolytes: from pressure conductivity measurements to transport mechanism

517

(4)

O. Brylev

M. Duclot

F. Alloin

J.-Y. Sanchez

J.-L. Souquet

Electrochemical and structural characterisation near the NiO2 composition

521

(4)

L. Croguennec

C. Pouillerie

C. Delmas

Synthesis of overlithiated LiNiO2 cathode materials for Li-ion cells

525

(4)

R. Moshtev

P. Zlatilova

Differential capacity analysis, a tool to examine the performance of graphites for Li-ion cells

529

(6)

E. Hatzikraniotis

C.L. Mitsas

D.I. Siapkas

Part 3: Posters

Physico-chemical properties of LiMn2O4 films grown by laser ablation

535

(8)

M.A. Camacho-Lopez

L. Escobar-Alarcon

E. Haro-Poniatowski

C. Julien

ESR studies of cathode materials with spinel structure

543

(6)

F. Gendron

C. Julien

LiNi1-yCoyO2 cathode materials synthesized by wet chemistry

549

(6)

D. Mazas-Brandariz

M.A. Senaris-Rodriguez

S. Castro-Garcia

M.A. Camacho-Lopez

C. Julien

Comparative study between 4-V LiMn2O4, LiCoO2 and 3-V Li0.3MnO2, LiV3O8 as cathode materials for Li batteries

555

(4)

B. Banov

A. Momchilov

A. Trifonova

B. Puresheva

Comparative study of the electrochemical behaviour of lithium and potassium vanadates treated by water molecules

559

(6)

A. Momchilov

B. Banov

A. Trifonova

B. Puresheva

PTFE-acetylene black and ultrafine carbon suspensions as a conductive binder and conductive additive for the positive electrodes of the lithium and Li-ion batteries

565

(6)

A. Momchilov

A. Trifonova

B. Banov

B. Puresheva

A. Kozawa

Electrolytes for lithium batteries on the basis of complex fluorides and aprotic media

571

(6)

V.N. Plakhotnik

I.V. Goncharova

A.V. Plakhotnik

N.F. Tovmash

L.A. Yaryshkina

Lithium insertion mechanism in copper indium tin sulfospinels studied by 119Sn Mossbauer spectroscopy and Rietveld analysis

577

(4)

R. Dedryvere

S. Denis

J. Olivier-Fourcade

J.C. Jumas

Lithium insertion mechanism in tin oxides: anode materials for lithium-ion batteries

581

(4)

J. Chouvin

J. Olivier-Fourcade

J.C. Jumas

B. Simon

Ph. Biensan

Characterization of nanostructure tin alloys as anodes in lithium-ion batteries

585

(2)

E. Peled

A. Ulus

Mechanical activation of V2O5 in different media: ethanol, water and air

587

(2)

A.I. Kharlamov

V.A. Zazhigalov

P.A. Kosoroulov

N.V. Kirillova

γ-MnO2 compounds as insertion hosts for Li+ and H+

589

(2)

S. Jouanneau

S. Sarciaux

A. Le Gal La Salle

Y. Piffard

D. Guyomard

Morphology and electrochemical performance in graphite

591

(2)

L. Fransson

K. Edstrom

Impedance of lithium ion batteries. Basic models and differential analysis

593

(4)

D. Vladikova

New polymer membrane-separation materials for lithium batteries

597

(2)

G.K. Elyashevich

A.G. Kozlov

I.S. Kuryndin

E. Yu. Rosova

Amorphous carbon films: magnetron sputter deposition and Li-intercalation properties

599

(4)

V. Gregor

J. Pridal

J. Pracharova

J. Bludska

I. Jakubec

L. Papadimitriou

Y. Samaras

Transport properties of composite superionic material LiIO3+SiO2

603

(4)

A.E. Aliev

N. Kh. Akhmedjanova

V.F. Krivorotov

I.N. Kholmanov

A.A. Fridman

Magnetron sputtered CuInSe2 layers as materials for solid-state batteries

607

(4)

P. Docheva

I. Dermendjiev

G. Vassilev

B. Arnaudov

Electron-gun evaporated carbon films for Li-ion microbatteries

611

(4)

I. Samaras

E. Pavlidou

G. Perentzis

L. Papadimitriou

Comparison study of the physical characteristics and cycling performance of commercially available Li-ion batteries

615

(4)

R. Moshtev

B. Johnson

Synthesis, properties and applications of Li-containing nanoparticles as electrode materials

619

(4)

S. Bliznakov

G. Ivanova

I. Dragieva

A. Popov

Z. Stoynov

PMMA based gel polymer electrolytes

623

(4)

J. Vondrak

M. Sedlarikova

J. Reiter

D. Kaspar

Dielectric relaxations in lithium composite polymer electrolytes based on PEO and diethylaluminum carboxylate

627

(6)

B. Misztal-Faraj

F. Krok

J.R. Dygas

Z. Florjanczyk

E. Zygad o-Monikowska

E. Rogalska

Author index

633

(2)

Subject index

635

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Materials for Lithium-Ion Batteries

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Table of Contents

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Materials for Lithium-Ion Batteries

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