Metal Ions in Biological Systems: Volume 37: Manganese and Its Role in Biological Processes

Note: Supplemental materials are not guaranteed with Rental or Used book purchases.

ISBN: 9780824702885 | 0824702883
Cover: Hardcover
Copyright: 1/27/2000

Rent

(Recommended)

$298.96

Term

Due

Price

Semester

Dec 12

$332.18

Quarter

Sep 4

$315.57

Short Term

Aug 13

$298.96

*This item is part of an exclusive publisher rental program and requires an additional convenience fee. This fee will be reflected in the shopping bag.
Buy New

Usually Ships in 3-5 Business Days

$425.27
eBook

Available Instantly

Online: 180 Days

Downloadable: 180 Days

*To support the delivery of the digital material to you, a digital delivery fee of $3.99 will be charged on each digital item.

$56.10*

"Highlights the availability of magnesium to organisms, its uptake and transport in microorganisms and plants as well as its role in health and disease of animals and humans including its toxicology. "

Preface to the Series

iii

Preface to Volume 37

Contributors

Contents of Previous Volumes

xxi

Handbook on Toxicity of Inorganic Compounds

xlv

Handbook on Metals in Clinical and Analytical Chemistry

xlvi

Manganese in Natural Waters and Earth's Crust: Its Availability to Organisms

(34)

James J. Morgan

Introduction

(4)

Chemical Properties

(8)

Rates of Manganese Reactions in Water

(7)

Managanese Profiles in the Oceans

(5)

Freshwaters

(1)

Concluding Remarks

(8)

Acknowledgments

(1)

References

(5)

Manganese Transport in Microorganisms

(22)

Valeria Cizewski Culotta

Introduction and Overview

(1)

Biochemical Studies in Bacteria

(2)

Genes Controlling Manganese Accumulation in Bacteria

(2)

Genes Controlling Manganese Accumulation in Yeast

(6)

Genes Controlling the Intracellular Transport and Trafficking of Manganese Ions in Yeast

(4)

Conclusions and Directions for the Future

(6)

Acknowledgments

(1)

Abbreviations

(1)

References

(4)

Manganese Uptake and Transport in Plants

(32)

Zdenko Rengel

Introduction

(1)

Availability of Manganese in the Rhizosphere

(2)

Uptake of Manganese by Plant Cells

(8)

Transport of Manganese in Xylem and Phloem

(5)

Loading of Manganese into Developing Grain

(2)

Genotypic Differences in Manganese Uptake and Utilization

(1)

Conclusions

(12)

Acknowledgments

(1)

Abbreviations

(1)

References

(11)

Manganese Metabolism in Animals and Humans Including the Toxicity of Manganese

(34)

Carl L. Keen

Jodi L. Ensunsa

Michael S. Clegg

Introduction

(1)

Chemical and Physical Properties

(1)

Analysis

(1)

Physiological Role

(5)

Manganese Deficiency

(7)

Manganese Toxicity

104

(6)

Assessment of Manganese Status

110

(2)

Summary and Future Directions

112

(11)

Acknowledgment

113

(1)

Abbreviations

113

(1)

References

114

(9)

Interrelations Between Manganese and Other Metal Ions in Health and Disease

123

(34)

James C. K. Lai

Margaret J. Minski

Alex W. K. Chan

Louis Lim

Introduction

125

(1)

Interdependence Between Manganese and Other Metals in Absorption

125

(1)

Interrelations Between Manganese and Other Metals in Peripheral Organs

126

(9)

Interrelations Between Manganese and Other Metals in Brain

135

(13)

Interrelations Between Manganese and Other Metals in Brain in Human Health and Diseases

148

(4)

Conclusions and Prospects for Future Studies

152

(5)

Acknowledgments

152

(1)

Abbreviations

152

(1)

References

152

(5)

The Use of Manganese as a Probe for Elucidating the Role of Magnesium Ions in Ribozymes

157

(26)

Andrew L. Feig

Introduction

158

(4)

Use of Mn2+ in Biochemical Studies of Phosphorothioate-Containing Ribozymes

162

(6)

Use of Mn2+ in Crystallographic Experiments to Find Mg2+ Binding Sites

168

(3)

Use of Mn2+ in Magnetic Resonance Experiments to Study Metal Binding Sites

171

(4)

Conclusions

175

(8)

Acknowledgments

176

(1)

Abbreviations

176

(1)

References

177

(6)

Mn2+ As a Probe of Divalent Metal Ion Binding and Function in Enzymes and Other Proteins

183

(26)

George H. Reed

Russell R. Poyner

Introduction and Overview

184

(1)

Survey of Coordination Properties and Tendencies

185

(2)

CW EPR Properties

187

(5)

Ligand Superhyperfine Splittings and Structure Determinations

192

(8)

ENDOR and ESEEM Methods

200

(1)

Electron Spin-Spin Coupling and Multinuclear Metal Centers

201

(8)

Acknowledgment

202

(1)

Abbreviations

202

(1)

References

202

(7)

Enzymes and Proteins Containing Manganese: An Overview

209

(70)

James D. Crowley

Deborah A. Traynor

David C. Weatherburn

Introduction

211

(4)

Oxidoreductases

215

(13)

Transferases

228

(8)

Hydrolases

236

(6)

Lyases

242

(3)

Isomerases

245

(4)

Ligases

249

(4)

Proteins Containing Bound Manganese

253

(2)

Conclusions

255

(24)

Acknowledgment

256

(1)

Abbreviations

256

(1)

References

257

(22)

Manganese(II) in Concanavalin a and Other Lectin Proteins

279

(26)

A. Joseph Kalb(Gilboa)

Jarjis Habash

Nicola S. Hunter

Helen J. Price

James Raftery

John R. Helliwell

Introduction: The Biology and Molecular Biology of Concanavalin A

280

(2)

Isolation and Characterization

282

(4)

Spectroscopic Studies

286

(1)

Crystals of Concanavalin A: Introduction and Early History

287

(2)

Ultrahigh-Resolution X-Ray Protein Crystallography

289

(2)

Manganese Multiwavelength Anomalous Dispersion Protein Crystallography

291

(1)

Neutron Laue Diffraction

292

(3)

Role of Manganese in Saccharide Binding in Concanavalin A and Other Legume Lectins

295

(3)

Concluding Remarks

298

(7)

Acknowledgments

299

(1)

References

300

(5)

Manganese-Activated Phosphatases

305

(40)

Frank Rusnak

Introduction: Phosphate Esters in Biological Systems

306

(3)

Classification of Metal-Activated Phosphatases

309

(5)

Phosphatase Structure and Active Site Metal Ion Geometry

314

(13)

Mechanisms of Hydrolysis

327

(6)

Conclusions

333

(12)

Acknowledgments

337

(1)

Abbreviations

337

(1)

References

337

(8)

Manganese(II) as a Probe for the Mechanism and Specificity of Restriction Endonucleases

345

(20)

Geoffrey S. Baldwin

Niall A. Gormley

Stephen E. Halford

Introduction

346

(2)

DNA Recognition and Cleavage

348

(3)

Restriction Endonucleases with Manganese

351

(8)

Conclusions

359

(6)

Acknowledgments

361

(1)

Abbreviations and Definitions

361

(1)

References

361

(4)

Role of the Binuclear Manganese(II) Site in Xylose Isomerase

365

(42)

Ralf Bogumil

Reinhard Kappl

Jurgen Huttermann

Introduction

366

(2)

X-Ray Crystal Structures of Xylose Isomerase

368

(8)

The Two Metal Binding Sites

376

(5)

EPR Studies on Manganese-Substituted Xylose Isomerase

381

(16)

The Catalytic Mechanism and the Role of the Binuclear Center

397

(10)

Acknowledgments

402

(1)

Abbreviations

402

(1)

References

402

(5)

Arginase: A Binuclear Manganese Metalloenzyme

407

(22)

David E. Ash

J. David Cox

David W. Christianson

Introduction

408

(1)

Enzymology and Bioinorganic Chemistry

409

(7)

Arginase Structure and Mechanism

416

(7)

Related Binuclear Manganese Metalloenzymes

423

(2)

Conclusions

425

(4)

Acknowledgment

425

(1)

References

425

(4)

The Use of Model Complexes to Elucidate the Structure and Function of Manganese Redox Enzymes

429

(76)

Vincent L. Pecoraro

Wen-Yuan Hsieh

Introduction

430

(1)

Manganese Catalases

431

(13)

The Oxygen Evolving Complex

444

(36)

The Energetics of Water Oxidation and the Role of Protons

480

(6)

Toward a Unified View of Biological Water Oxidation Chemistry

486

(5)

Conclusion

491

(14)

Acknowledgments

493

(1)

Abbreviations and Definitions

493

(1)

References

494

(11)

Manganese(II)-Dependent Extradiol-Cleaving Catechol Dioxygenases

505

(22)

Lawrence Que, Jr.

Mark F. Reynolds

Introduction

506

(1)

The Intradiol Cleavage Precedent

506

(4)

Fe(II)-Dependent Extradiol-Cleaving Dioxygenases

510

(3)

Mn(II)-Dependent Dioxygenases

513

(14)

Acknowledgment

521

(1)

Abbreviations

521

(1)

References

522

(5)

Manganese Catalases

527

(32)

Derek W. Yoder

Jungwon Hwang

James E. Penner-Hahn

Introduction

528

(2)

Reactivity

530

(9)

Spectroscopy

539

(8)

Structural Characterization

547

(3)

Mechanism

550

(9)

Acknowledgments

552

(1)

Abbreviations and Definitions

552

(1)

References

553

(6)

Manganese Peroxidase

559

(28)

Michael H. Gold

Heather L. Youngs

Maarten D. Sollewijn Gelpke

Introduction

560

(1)

General Properties of Mn Peroxidase

561

(1)

Reactions Catalyzed by Mn Peroxidase

561

(2)

Biophysical Studies of Mn Peroxidase

563

(4)

Mn Peroxidase cDNA and Genomic Sequences

567

(2)

Crystal Structure of Mn Peroxidase

569

(5)

Structure-Function Studies of Mn Peroxidase

574

(4)

Regulation of Mn Peroxidase Gene Expression

578

(9)

Acknowledgments

579

(1)

Abbreviations

579

(1)

References

580

(7)

Manganese Superoxide Dismutase

587

(26)

James W. Whittaker

Introduction

588

(3)

Manganese Superoxide Dismutase

591

(3)

Molecular Structure

594

(5)

Ligand Interactions

599

(5)

Mutagenic Dissection of the Active Site

604

(1)

Metal Specificity: The Irony of Mn Superoxide Dismutase

605

(2)

Superoxide Dismutase as a One-Electron Redox Engine

607

(6)

Acknowledgments

607

(1)

Abbreviations

608

(1)

References

608

(5)

Mechanistic Aspects of the Tyrosyl Radical-Manganese Complex in Photosynthetic Water Oxidation

613

(44)

Curtis W. Hoganson

Gerald T. Babcock

Introduction

615

(4)

Structure of the Catalytic Site

619

(6)

Water Binding and Exchange

625

(1)

Proton Release

626

(5)

Mechanisms for Oxygen Production

631

(8)

The Nature of S-State Cycle Intermediates

639

(10)

Conclusions

649

(8)

Acknowledgments

649

(1)

Abbreviations

650

(1)

References

650

(7)

The Polypeptides of Photosystem II and Their Influence on Manganotyrosyl-Based Oxygen Evolution

657

(56)

Richard J. Debus

Introduction

658

(3)

The Polypeptides of Photosystem II

661

(19)

The Environments of the Redox-Active Tyrosine Residues

680

(3)

The Environment of the Manganese Cluster

683

(9)

Concluding Remarks

692

(21)

Acknowledgments

692

(1)

Abbreviations

693

(1)

References

693

(20)

Subject Index

713

Please wait while the item is added to your bag...

FREE SHIPPING

Rent More, Save More! Use code: BBRENTAL

5% off 1 book, 7% off 2 books, 10% off 3+ books

Metal Ions in Biological Systems: Volume 37: Manganese and Its Role in Biological Processes

Summary

Table of Contents

Supplemental Materials

FREE SHIPPING

Rent More, Save More! Use code: BBRENTAL

5% off 1 book, 7% off 2 books, 10% off 3+ books

Metal Ions in Biological Systems: Volume 37: Manganese and Its Role in Biological Processes

Summary

Table of Contents

Supplemental Materials

Digital License