Metal-organic Framework Materials

Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H₂ or CO₂. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis.  Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. 

Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. 

The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc

Leonard R. MacGillivray is an Associate Professor of Chemistry at the University of Iowa. His research focuses on processes of molecular self-assembly, particularly its application to organic synthesis. In 2002, he was awarded a 2002 National Science Foundation CAREER Award and a Research Corporation Research Innovation Award. In 2004, he received the Young Investigator Award of the Inter-American Photochemical Society and the Etter Early Career Award of the American Crystallographic Association. Dr. MacGillivray was elected a Fellow of the Royal Society of Chemistry in 2006 and received a 2007 Cope Scholar Award from the American Chemical Society. He has published 140 manuscripts and sits on six editorial boards.

Charles M. Lukehart, Professor, Vanderbilt University in Nashville, Tennessee is Section Editor for Organometallic Chemistry and Solid State, Materials, Nanomaterials and Catalysis in King: Encyclopedia of Inorganic Chemistry, 2nd Edition.

Contributors xi

Series Preface xv

Volume Preface xvii

Part 1: Design and Synthesis 1

Porous Coordination Polymer Nanoparticles and Macrostructures 3
Julien Reboul and Susumu Kitagawa

Nanoscale Metal-Organic Frameworks 19
Kyriakos C. Stylianou, Inhar Imaz and Daniel Maspoch

Mesoporous Metal-Organic Frameworks 39
Yao Chen and Shengqian Ma

Porphyrinic Metal-Organic Frameworks 67
Chao Zou, Min Zhao and Chuan-De Wu

Fluorinated Metal-Organic Frameworks (FMOFs): Concept, Construction, and Properties 85
Pradip Pachfule and Rahul Banerjee

Synthesis and Structures of Aluminum-Based Metal-Organic Frameworks 99
Norbert Stock

Polyrotaxane Metal-Organic Frameworks 115
Stephen J. Loeb and V. Nicholas Vukotic

Photoreactive Metal-Organic Frameworks 135
Anjana Chanthapally and Jagadese J. Vittal

Edible Metal-Organic Frameworks 159
Ross Stewart Forgan

Mechanochemical Approaches to Metal-Organic Frameworks 173
Tomislav Friščić

Part 2: Post-Modification 193

Postsynthetic Modification of Metal-Organic Frameworks 195
Andrew D. Burrows

Part 3: Properties and Applications 219

Functional Magnetic Materials Based on Metal Formate Frameworks 221
Ran Shang, Sa Chen, Zhe-Ming Wang and Song Gao

Metal-Organic Frameworks from Single-Molecule Magnets 245
Athanassios D. Katsenis, Euan K. Brechin and Giannis S. Papaefstathiou

Open Metal Sites in Metal-Organic-Frameworks 259
Yabing He and Banglin Chen

Gas Storage in Metal-Organic Frameworks 283
Muwei Zhang, Hao Li, Zachary Perry and Hong-Cai Zhou

Metal-Organic Frameworks for Removal of Harmful Gases 303
Jian Liu, B. Peter McGrail, Denis M. Strachan, Jun Liu, Jian Tian and Praveen K. Thallapally

Adsorption of Hydrocarbons and Alcohols in Metal-Organic Framework Materials 321
Debasis Banerjee, Benjamin J. Deibert, Hao Wang and Jing Li

Metal Uptake in Metal-Organic Frameworks 343
Michaele J. Hardie

Photoreactive Properties Hosted in Metal-Organic Frameworks 363
Victoria J. Richards, Thomas J. Reade, Michael W. George and Neil R. Champness

Semiconducting Metal-Organic Frameworks 373
Zhengtao Xu

Patterning Techniques for Metal-Organic Frameworks 387
Paolo Falcaro and Mark J. Styles

Metal-Organic Frameworks in Mixed-Matrix Membranes 403
Harold B. Tanh Jeazet and Christoph Janiak

Electrochemical Properties of Metal-Organic Frameworks 419
Frédéric Jaouen and Adina Morozan

Applications of Metal-Organic Frameworks to Analytical Chemistry 443
Na Chang, Cheng-Xiong Yang and Xiu-Ping Yan

Recent Solid-State NMR Studies of Quadrupolar Nuclei in Metal-Organic Frameworks 457
Yining Huang, Jun Xu, Farhana Gul-E-Noor and Peng He

Part 4: Nets 471

Single-Crystal to Single-Crystal Transformations in Metal-Organic Frameworks 473
Subhadip Neogi, Susan Sen and Parimal K. Bharadwaj

Interpenetration and Entanglement in Coordination Polymers 523
Stuart R. Batten

Index 539

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