Miniemulsion Polymerization Technology
, by Mittal, Vikas- ISBN: 9780470625965 | 0470625961
- Cover: Hardcover
- Copyright: 12/31/2014
Preface | p. xiii |
Miniemulsion Polymerization: An Overview | p. 1 |
Introduction to Polymerization Techniques | p. 2 |
Emulsion and Miniemulsion Polymerization | p. 3 |
Properties of Miniemulsion Polymerization | p. 10 |
Controlled Miniemulsion Polymerization | p. 19 |
References | p. 22 |
Multi-Functional Stabilizers in Miniemulsion Polymerization | p. 25 |
Introduction | p. 25 |
Stability of Initial Monomer Droplets | p. 27 |
Stabilizers and Polymerization Processes | p. 30 |
Mass-Transfer Processes | p. 30 |
Reactive Stabilizers | p. 31 |
Conclusion | p. 39 |
References | p. 39 |
Structured Copolymer Particles by Miniemulsion Polymerization | p. 43 |
Introduction | p. 43 |
Styrene-Dodecyl Methacrylate/Stearyl Methacrylate | p. 46 |
n-Butyl Methacrylate-Crosslinking Monomers | p. 49 |
Vinyl Acetate-Butyl Acrylate | p. 51 |
Butyl Acrylate-(2-Methacryloxy)ethyl) trimethyl Ammonium Chloride | p. 53 |
Butyl Acrylate-Methyl Methacrylate-Vinyl Acetate | p. 54 |
Styrene-Acrylic Acid or 2-Aminoethyl Methacrylate Hydrochloride (AEMH) | p. 55 |
Styrene-Butyl Acrylate | p. 57 |
Styrene-Butadiene Rubber | p. 57 |
Fluoroacrylate-Lauryl Methylacrylate-Methyl Methacrylate | p. 61 |
Polyurethane-Block-Polystyrene | p. 62 |
Alkyd-Acrylic | p. 63 |
Oil-Acrylate | p. 65 |
Urethane-Acrylic | p. 67 |
References | p. 68 |
Encapsulation of Inorganic Nanoparticles by Miniemulsion Polymerization | p. 71 |
Introduction | p. 71 |
Miniemulsion Polymerization in the Presence of Inorganic Nanoparticles | p. 73 |
Hydrophobization of Inorganic Nanoparticles | p. 73 |
Dispersion of Hydrophobized Inorganic Nanoparticles in Monomer Phase | p. 75 |
Miniemulsification of the Lipophilic Dispersion in Water | p. 75 |
Polymerization of Droplets | p. 76 |
Encapsulation of Silica Nanoparticles | p. 76 |
Miniemulsion Polymerization with Hydrophilic Silica Nanoparticles | p. 77 |
Miniemulsion Polymerization with Surface-Modified Silica Nanoparticles | p. 78 |
Miniemulsion Polymerization with Locally Surface-Modified Silica Nanoparticles | p. 83 |
Encapsulation of Magnetite Nanoparticles | p. 85 |
Encapsulation of Magnetite by a Single Miniemulsion Polymerization Process | p. 86 |
Encapsulation of Magnetite by a Double Miniemulsion Polymerization Process | p. 89 |
Conclusions and Future Perspectives | p. 91 |
Acknowledgements | p. 92 |
References | p. 92 |
Polymeric Nanocapsules by Interfacial Miniemulsion Polymerization | p. 97 |
Introduction | p. 97 |
Organic Nanocapsules by Interfacial Miniemulsion Polymerization | p. 99 |
Thermodynamic Prediction for the Morphology of Organic Nanocapsules | p. 99 |
Particles Morphology of the System without Added NIPAM and DVB | p. 101 |
Particles Morphology of the System with DVB | p. 103 |
Particle Morphology of the System with Added NIPAM and DVB | p. 105 |
Particle Size and Size Distribution in the Process of Polymerization | p. 109 |
Mechanism for the Formation of Organic Nanocapsules through Interfacial Miniemulsion Polymerization | p. 112 |
Influences on the Formation of Organic Nanocapsules through Interfacial Miniemulsion Polymerization | p. 113 |
Organic-Inorganic Hybrid Nanocapsules by Interfacial Miniemulsion Polymerization | p. 117 |
Thermodynamic Analysis and Morphological Prediction | p. 117 |
Synthesis of Organic-Inorganic Hybrid Nanocapsules under Neutral Conditions | p. 119 |
Synthesis of Organic-Inorganic Hybrid Nanocapsules under Acidic or Basic Conditions | p. 124 |
Mechanism Analysis of Organic-Inorganic Hybrid Nanocapsules Formation | p. 134 |
Conclusions | p. 136 |
References | p. 137 |
Miniemulsion Polymerization of Vegetable Oil Macromonomers | p. 139 |
Introduction and Background | p. 139 |
Emulsion Polymerization of Alkyds and Vegetable Oils | p. 143 |
(Meth)acrylated Vegetable Oil Derivatives | p. 145 |
Vegetable Oil Macromonomers | p. 146 |
The Potential for Emulsion Polymerization of Model Saturated Monomers | p. 150 |
Nucleation Mechanisms | p. 152 |
Design of Thermosetting Latex Polymers | p. 154 |
Classifying Monomer Solubility for Macro and Miniemulsion Polymerization | p. 158 |
Soybean Acrylated Monomer Synthesis | p. 160 |
Miniemulsion Polymerization | p. 160 |
Conclusions | p. 168 |
References | p. 169 |
Controlled/Living Radical Polymerization in Aqueous Miniemulsion | p. 173 |
Introduction | p. 174 |
Controlled/Living Radical Polymerization in Bulk/Solution: General Considerations | p. 174 |
CLRP Based on Reversible Termination | p. 175 |
Nitroxide-Mediated Polymerization (NMP) | p. 176 |
Atom Transfer Radical Polymerization (ATRP) | p. 177 |
CLRP Based on Degenerative Transfer | p. 178 |
Reversible Addition-Fragmentation Chain Transfer (RAFT) | p. 179 |
Iodine Transfer Polymerization (ITP) | p. 180 |
Nitroxide-Mediated Miniemulsion Polymerization | p. 182 |
Oil-Soluble Bicomponent Initiating System | p. 183 |
Water-Soluble Bicomponent Initiating System | p. 185 |
Oil-Soluble Monocomponent Initiating System | p. 186 |
Water-Soluble Monocomponent Initiating System | p. 188 |
Atom Transfer Radical Miniemulsion Polymerization | p. 188 |
Direct ATRP | p. 190 |
Reverse ATRP | p. 190 |
Simultaneous Reverse and Normal Initiation (SR&NI) ATRP | p. 192 |
Activators Generated by Electron Transfer (AGET) ATRP | p. 192 |
Reversible Addition-Fragmentation Chain Transfer Miniemulsion Polymerization | p. 193 |
Key-Steps for the Success of RAFT Miniemulsion Polymerization | p. 194 |
Inhibition and Retardation | p. 194 |
Colloidal Instability | p. 196 |
Livingness and Controlled Polymerization | p. 198 |
RAFT Miniemulsion Polymerization of Vinyl Acetate | p. 199 |
Nanocapsules Synthesized by RAFT Miniemulsion Polymerization | p. 200 |
Iodine Transfer Polymerization in Miniemulsion | p. 201 |
Conclusion | p. 202 |
References | p. 203 |
Inverse Miniemulsion Polymerization of Unsaturated Monomers | p. 211 |
Introduction | p. 211 |
General | p. 215 |
Kinetic Studies | p. 218 |
Traditional and Nonconventional Inverse Latexes | p. 221 |
Water Soluble Monomers | p. 221 |
Hydrophobic Monomers | p. 230 |
Controlled Radical Miniemulsion Polymerization | p. 232 |
Amphiphilic and Associating Copolymers | p. 237 |
Conclusion | p. 240 |
Acknowledgements | p. 244 |
Abbreviations | p. 244 |
References | p. 246 |
Double Miniemulsion Preparation for Hybrid Latexes | p. 251 |
Introduction | p. 252 |
Hybrids via Mini-Emulsion Polymerization | p. 253 |
Double-Miniemulsion Formation | p. 255 |
Stability | p. 255 |
Characterization | p. 257 |
Applications | p. 261 |
Effects of Reaction Conditions | p. 266 |
Initiator Dosage | p. 266 |
MMA Monomer Concentration | p. 267 |
Rheological Properties of Magnetic Emulsion | p. 268 |
Viscosity Versus Time | p. 268 |
Viscosity with/without Magnetic Field | p. 269 |
Applications of Magnetic Polymer Microspheres | p. 270 |
Summary | p. 271 |
Acknowledgments | p. 272 |
References | p. 272 |
Surfactant Effect in Miniemulsion Polymerization for Biodegradable Latexes | p. 277 |
Introduction | p. 277 |
Miniemulsion Polymerization of Biodegradable Latexes | p. 278 |
Mechanisms of Surfactant Protection of Colloidal Dispersions | p. 282 |
General Behavior of a Surfactant Molecule at the Interface | p. 282 |
Mechanism 1: Lowering the Interfacial Tension | p. 284 |
Mechanism 2: Electrostatic Stabilization | p. 286 |
Mechanism 3: Steric Stabilization | p. 288 |
Effect of Surfactants on Miniemulsion Polymerization | p. 291 |
Effect of Surfactant Type on the Particle Size and Latex Yield | p. 291 |
Effect of Surfactant Concentration on Particle Size and Latex Yield | p. 294 |
Effect of Surfactant on the Stability | p. 297 |
Final Remarks | p. 298 |
References | p. 299 |
Index | p. 303 |
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