Morphotropic Phase Boundary Perovskites, High

Proceedings of the Symposium on Dielectric Materials and Multilayer Electronic Devices and the Symposium on Morphotropic Phase Boundary Phenomena and Perovskite Materials, held April 28 - May 1, 2002, in St. Louis, Missouri, during the 104th Annual Meeting of the American Ceramic Society, and the Focused Session on High Strain Piezoelectrics, held April 22-25, 2001, in Indianapolis, Indiana, during the 103rd Annual Meeting of the American Ceramic Society.

Ruyan Guo is an electrical engineer and the Robert E. Clarke Endowed Professor at the University of Texas, San Antonio. Guo was named a Fellow of the Institute of Electrical and Electronics Engineers in 2013 for his contributions to the understanding of polarization phenomena in ferroelectric solid-solution systems.

K. M. Nair is the editor of Morphotropic Phase Boundary Perovskites, High Strain Piezoelectrics, and Dielectric Ceramics, published by Wiley.

Preface

xi

Morphotropic Phase Boundary Material Systems and Their Structure-Property-Chemistry Relations

Local Atomic Structure and Morphotropic Phase Boundary

3

(14)

T. Egami and W. Dmowski

Structure and Dynamics of The Ferroelectric Relaxors Pb(Mg1/3Nb2/3)O3 and Pb(Zn1/3Nb2/3)O3

17

(20)

Gen Shirane and Peter M. Gehring

Morphotropic Phase Boundary and Related Properties in Relaxor-Based Piezoelectric Perovskite Solid Solutions

37

(18)

A.A. Bokov and Z.-G,Ye

The Morphotropic Phase Boundary in Perovskite Ferroelectric Relaxor Systems

55

(10)

Edward E. Alberta, Ruyan Guo, and Amar S. Bhalla

In-Situ Neutron Diffraction Study of the Ferroelastic Behavior of Pb(Zr,Ti)O3

65

(10)

R.C. Rogan, Ersan Üstündag, B. Clausen, and M.R. Daymond

Fourier Harmonic Analysis of the Electromechanical Response of Electroactive Materials

75

(10)

C.B. DiAntonio, S.M. Pilgrim, EA, Williams Jr., and W.A. Schulze

High Curie Temperature, High Performance Perovskite Single Crystals in the Pb(Yb1/2Nb1/2)O3-PbTiO3 and BiScO3-PbTiO3 Systems

85

(20)

Shujun Zhang, L, Lebrun, C.A. Randall, and TR. Shrout

Electromechanical Performance Advantages and Limitations of [001]- Oriented Pb(Mg1/3Nb2/3)O3-PbTiO3 Crystals 95

D. Viehland and J.F. Li

Polarization Induced Cracking in Partially Electroded PSZT Ceramic

105

(12)

R.H. Moore, S.N. Burchett, G.R. Burns, S.J. Glass, M.A. Hutchinson, T.W. Scofield, M.E. Stavig, C.S. Watson, and P. Yang

Acceptor Doped PZN-PT Single Crystals

117

(10)

Laurent Lebrun, S. Zhang, C.A. Randall, T.R. Shrout, and D. Guyomar

Structure and Dielectric Properties in Novel BiGaO3-PbTiO3 Crystalline Solutions

127

(8)

Jinrong Cheng, Wenyi Zhu, Nan Li, and L.E. Cross

Preparation and Electrical Properties of Pb(In1/2Nb1/2)O3 Based Relaxor Materials

135

(8)

N. Ichinose, Y. Saigo, H. Sakamoto, Y. Hosono, and Y. Yamashita

Composition and Sintering Process Effects on Ferroelectric Fatigue in (1-x)Pb(Mg1/3Nb2/3)O3-x PbTiO3 Ceramics

143

(8)

M.H. Lente, A.L. Zanin, I.A. Santos, D. Garcia, and J.A. Eiras

Sintering Behavior of Additive Free (Pure) Lead Metaniobate Ceramics

151

(8)

N. Marandian Hagh, M. Allahverdi, and A. Safari

Electroceramic Fibers for Active Control

159

(10)

Marina Pascucci, Ravel Bystricky, and H.B. Strock

Influence of Hot-Pressing Parameters in Microstructure Evolution of PBN on Morphotropic Phase Boundary

169

(12)

Vera Lúcia Arantes, J.A. Eiras, and Ivair A. Santos

Synthesis of High Strain Piezoelectric Crystals and Textured Ceramics

Feasibility of the Growth of Relaxor-Based Ferroelectric Single Crystals

181

(10)

Haosu Luo, Haiging Xu, Bijun Fang, and Zhiwen Yin

Two Inches Size Single Crystal Growth of Piezoelectric Pb[(Zn1/3Nb2/3)0.9 l Ti0.09]O3 by the Solution Bridgman Method

191

(8)

Mitsuyoshi Matsushita,Yoshihito Tachi, and Kazuhiko Echizenya

Improved Dielectric and Piezoelectric Properties of Pb(Mg1/3Nb2/3)O3-32.5PbTiO3 Ceramics and [OO1]Textured PMN-PT

199

(12)

A.R. James, S. Kwon, G.L. Messing, and S.T. McKinstry

Solid-State Single Crystal Growth of BaTi03 and PMN-PT

211

(8)

Tae-Moo Heo, Jong-Bong Lee, Dong-Ho Kim, Ho-Yong Lee, Nong-Moon Hwang, Jong-Keuk Park, Ui-Jin Chung, and Doh-Yeon Kim

Laser Heated Pedestal Growth of Lead Magnesium Niobate - Lead Titanate Crystals and Their Characterization

219

(12)

Jianyi Cui, Ruyan Guo, and Amar S. Bhalla

Effect of Li2O and PbO Additions on Abnormal Grain and Single Crystal Growth in the Pb(Mg1/3Nb2/3)P3-35MOL% PbTiO3 System

231

(10)

John Fisher, M.-S. Kim, S.-J. Kang, and H,-Y. Lee

High Aspect Ratio Platelet SrTiO3 for Templated Grain Growth of PMN-PT Ceramics

241

(10)

M.E. Ebrahimi, M. Allahverdi, and A, Safari

Synthesis of PMN and 65PMN-35PT Ceramics and Films by a New Suspension Method

251

(12)

Hongyu Luo, Wan Y. Shih, and Wei-Heng Shih

Dielectric Materials Development and Device Fabrications

Microwave Properties of Low-Temperature Co-Fired Ceramic Systems

263

(24)

Richard G. Geyer, Liang Chai, Aziz Shaikh, and Vern Stygar

Near-Zero τf Doped-Niobate Ceramics for Dielectric Resonator Applications

287

(18)

R.C. Pullar, A.K. Axelsson, and N. McN. Alford

Low-T Sintering, Low-Dielectric Materials for High Frequency Ceramic Multilayer Parts

305

(12)

Linghong Luo, He Ping Zhou, and Ke Xin Chen

Low-Inductance Barium Strontium Titanate Thin Film Capacitors for Decoupling Applications

317

(10)

Koichi Niwa, T. Shioga, J.D. Baniecki, and K. Kurihara

Dielectric Properties of (Sr1-xPbxTiO3 (x=0.2, 0.25, and 0.3): MgO Composites

327

(6)

Y. Somiya, A.S. Bhalla, and L.E. Cross

Lattice Misfit as a Design Parameter for Enhanced Dielectric Response and Tunability in Epitaxial Barium Strontium Titanate Films

333

(12)

Z.-G. Ban and S.R. Alpay

Synthesis and Microwave Characterization of (BaO, SrO)-Al2O3-2SiO2 Ceramics from the Solid-State Reaction Process

345

(10)

C.H. Lin, Y.P. Fu, and C.C. Chang

Dielectric Relaxation of Nb2O5(0.92): Si02(0.08) Ceramics

355

(12)

H. Choosuwan, R. Guo, A.S. Bhalla, and U. Balachandran

Effects of Glass-Frit Addition on the Mechanical Strength and Reliability of Non-Reducible Y5V MLCC

367

(6)

J.H. Hwang, C.H. Lee, S.U. Ma, H.S. Shin, W.B. Park, S.K. Wi, J.H. Kim, and Y.H. Han

Dielectric Properties of Modified NaO,5BiO.5TiO3 Ceramic Materials

373

(16)

J.-P Mercurio, Pascal Marchet, Senda Said, Jean-Richard Gomah-Pettry, and Jan Suchanicz

Fabrication of Grain Oriented Barium Titanate

389

(18)

T. Sugawara, M. Shimizu, T. Kimura, K. Takatori, and T. Tani

Low Temperature Deposition of Bi4Ti3O12 -Based Ferroelectric Thin Films Using Site Engineering Concept

407

(10)

H. Funakubo, T. Sakai, T. Watanabe, T. Kojima, Y. Noguchi, M. Miyayama, and M. Osada

Chemical Approach to Ferroelectric Thin Films of Novel Bi-Based Layer-Structured Perovskite

417

(10)

Kazumi Kato, Kazuyuki Suzuki, Desheng Fu, Kaori Nishizawa, and Takeshi Miki

Effects of Added Boric Oxide on the Dispersion of Aqueous Barium Titanate Suspensions

427

(10)

C.-C. Li and J.-H. Jean

Effect of Re-Oxidation Treatment on the TC in Rare-Earth and Acceptor (Mg,Mn) Doped BaTiO3

437

(14)

Hitoshi Kishi, Noriyuki Kohzu, Hitoshi Ohsato, and Takashi Okuda

Temperature Dependence of Dielectric Properties of Rare-Earth Element Doped BaTiO3

451

(16)

Eunsang Na,Yunsung Jung, Sungchurl Choi, Ungyu Paik, Jinha Lee, and Jonghee Kim

Dielectric Properties of Barium Titanate Sintered with ZnO-WO3 Flux

467

(12)

Deep Prakash, BP Sharma, P Gopalan, and T.R. Rama Mohan

Effect of Processing Conditions on the Core-Shell Structure and Electrical Properties of Strontium Titanate Doped with Yttrium Oxide

479

(10)

Stephen J. Lombardo, Rajesh V. Shende, and Daniel S. Krueger

The Effect of Microstructure on the Electrical Properties of PZT Thin Films

489

(8)

C.R. Foschini, B.D. Stojanovic, J.A. Varela, and JE Fernández

Pb(Zr,S2Ti.48)O3 Thin Films on Metal Foils by RF Magnetron Sputtering

497

(12)

Suk Hun Choi, W.Y. Shih, J.W. Yi, Y.H. Lee, and Wei-Heng Shih

Materials and Design Issues for Piezoelectric Materials

Designing with Piezoelectric Actuators

509

(24)

Kenji Uchino

Piezoceramic Bimorph Flexure Beam Displacements and Rotations

533

(22)

Arthur Ballato

Materials and Design Issues for Cryogenic-Use Multilayers

555

(12)

Steven Pilgrim

Ferroelectric Relaxor Characteristics and Phase Transitions Studied by Thermal Strain and Optical Methods

567

Ruyan Guo

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Morphotropic Phase Boundary Perovskites, High Strain Piezoelectrics, and Dielectric Ceramics

Summary

Author Biography

Table of Contents

Supplemental Materials