Natural Gas Conversion IV : Proceedings of the 4th International Natural Gas Conversion Symposium, Kruger Park, South Africa, November 19-23, 1995

, by International Natural Gas Conversion Symposium 1995 Kruger National P; Espinoza, R. L.; Nicolaides, C. P.

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ISBN: 9780444823526 | 0444823522
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Preface

(2)

Organising and Advisory Committee

XVII

(1)

Financial Support

XVIII

1. SYNTHESIS OF ALCOHOLS AND OTHER OXYGENATES

(78)

THE USE OF A JET-STIRRED CONTINUOUSLY STIRRED TANK REACTOR (CSTR) TO STUDY THE HOMOGENEOUS GAS PHASE PARTIAL OXIDATION OF METHANE TO METHANOL

(6)

G.A. Foulds

B.G. Charlton

B.T. Le

J.C. Jones

B.F. Gray

SYNTHESIS OF ALCOHOLS FROM SYNGAS OVER Ni-BASED CATALYST: COMPARISON WITH THE HYDROFORMYLATION REACTION

(6)

J. Llorca

P. Ramirez de la Piscina

N. Homs

E. Brum Pereira

P. Moral

G.A. Martin

ZIRCONIA MODIFIED Ru/Al2O3 CATALYSTS FOR THE SYNTHESIS OF OXYGENATED PRODUCTS FROM SYNGAS

(8)

M.R. Goldwasser

M.L. Cubeiro

M.C. Da Silva

M.J. Perez Zurita

G. Leclercq

L. Leclercq

M. Dufour

L. Gengembre

G.C. Bond

A.D. Hooper

PARTIAL OXIDATION OF METHANE TO FORMALDEHYDE ON BULK AND SILICA SUPPORTED MoO3 AND V2O5 CATALYSTS: SURFACE FEATURES AND REACTION MECHANISM

(6)

A. Parmaliana

F. Arena

F. Frusteri

N. Giordano

M.S. Scurrell

V. Sokolovskii

METHANOL SYNTHESIS FROM CO2/H2 OVER Pd-PROMOTED Cu/ZnO/Al2O3 CATALYSTS: KINETICS AND DEACTIVATION

(6)

M. Sahibzada

D. Chadwick

I.S. Metcalfe

ABOUT THE MECHANISM OF METHANOL SYNTHESIS

(6)

T.M. Yurieva

O.V. Makarova

L.M. Plyasova

T.A. Krieger

A NOVEL APPROACH TO THE SCIENTIFIC DESIGN OF OXIDE CATALYSTS FOR THE PARTIAL OXIDATION OF METHANE TO METHANOL

(6)

G.J. Hutchings

J.S.J. Hargreaves

R.W. Joyner

S.H. Taylor

HIGHER ALCOHOL SYNTHESIS ON IRON-COPPER-MOLYBDENUM CONTAINING CATALYSTS

(8)

A. Barama

M.M. Bettahar

A. Kiennemann

LINKS BETWEEN REACTION INTERMEDIATES, ACTIVITY AND/OR SELECTIVITY IN SYNGAS CHEMISTRY

(8)

A. Kiennemann

P. Chaumette

B. Ernst

J. Saussey

J.C. Lavalley

LOW TEMPERATURE DIRECT OXIDATION OF METHANE TO METHANOL

(4)

K. Fujimoto

Y. Sekine

COPPER-COBALT CATALYSTS FOR HIGHER ALCOHOLS SYNTHESIS FROM SYNGAS

(6)

G.G. Volkova

T.A. Krieger

L.M. Plyasova

V.A. Zaikovskii

T.M. Yurieva

CUSTOM MADE CATALYSTS FOR LOW PRESSURE METHANOL SYNTHESIS

(8)

J. Ladebeck

J.P. Wagner

T. Matsuhisa

2. ECONOMICS AND INDUSTRIAL PROCESSES

(72)

KEYS TO METHANE CONVERSION TECHNOLOGIES

(6)

J.-P. Lange

K.P. de Jong

J. Ansorge

P.J.A. Tijm

ECONOMIC ROUTE FOR NATURAL GAS CONVERSION TO ETHYLENE AND PROPYLENE

(12)

B.V. Vora

T.L. Marker

P.T. Barger

H.R. Nilsen

S. Kvisle

T. Fuglerud

LARGE-SCALE PRODUCTION OF ALTERNATIVE SYNTHETIC FUELS FROM NATURAL GAS

(18)

I. Dybkjaer

J.B. Hansen

DIMETHYL ETHER: A FUEL FOR THE 21st CENTURY

117

(10)

T.H. Fleisch

A. Basu

M.J. Gradassi

J.G. Masin

SOFC BASED ON SUPPORTED THICK-FILM Ce(Gd)O2-x ELECTROLYTES

127

(6)

K. Zheng

B.C.H. Steele

I.S. Metcalfe

USE OF NATURAL GAS IN A CATALYTIC RADIANT BURNER FOR LOW-EMISSION HEAT PRODUCTION

133

(6)

P. Brockerhoff

B. Emonts

ETHERMIX PROCESS: SYNTHESIS OF ETHERS FROM CO/H2

139

(6)

E. Micheli

G.B. Antonelli

D. Sanfilippo

B. Cometa

G.C. Pecci

A TECHNICAL AND ECONOMIC COMPARISON OF NATURAL GAS AND COAL FEEDSTOCKS FOR FISCHER-TROPSCH SYNTHESIS

145

(8)

D. Gray

G. Tomlinson

3. FISCHER-TROPSCH

153

(104)

FISCHER-TROPSCH SYNTHESIS ON COBALT CATALYSTS: STRUCTURAL REQUIREMENTS AND REACTION PATHWAYS

153

(10)

E. Iglesia

ACTIVITY AND SELECTIVITY OF IRON FISCHER-TROPSCH CATALYSTS IN A STIRRED TANK SLURRY REACTOR

163

(6)

D.B. Bukur

X. Lang

L. Nowicki

THE ROLE OF CATALYST ACTIVATION ON THE ACTIVITY AND ATTRITION OF PRECIPITATED IRON FISCHER-TROPSCH CATALYSTS

169

(6)

A.K. Datye

M.D. Shroff

M.S. Harrington

A.G. Sault

N.B. Jackson

ROLE OF CO2 OXYGENATES AND ALKENES IN THE INITIATION OF CHAIN GROWTH DURING THE FISCHER-TROPSCH SYNTHESIS

175

(6)

B.H. Davis

L. Xu

S. Bao

KINETIC ANALYSIS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS

181

(6)

K. Fujimoto

M. Shimose

Y.Z. Han

DRIFTS STUDIES ON Co/TiO2 FISCHER-TROPSCH CATALYSTS

187

(6)

B. Mothebe

D.J. Duvenhage

V.D. Sokolovskii

N.J. Coville

EFFECT OF WATER PARTIAL PRESSURE ON STEADY STATE FISCHER-TROPSCH ACTIVITY AND SELECTIVITY OF A PROMOTED COBALT CATALYST

193

(8)

H. Schulz

M. Claeys

S. Harms

POTASSIUM-PROMOTED TITANIA-SUPPORTED NICKEL-IRON CATALYSTS FOR FISCHER-TROPSCH SYNTHESIS

201

(6)

J. van de Loosdrecht

A.J. van Dillen

D. Reinders

A.A. van der Horst

E. Boellaard

A.M. van der Kraan

J.W. Geus

COBALT AS AN ALTERNATIVE FISCHER-TROPSCH CATALYST TO IRON FOR THE PRODUCTION OF MIDDLE DISTILLATES

207

(6)

P.J. van Berge

R.C. Everson

SELECTION, DESIGN AND SCALE UP OF THE FISCHER-TROPSCH REACTOR

213

(6)

J.W.A. De Swart

R. Krishna

S.T. Sie

DEVELOPMENT IN FISCHER-TROPSCH TECHNOLOGY

219

(6)

B. Jager

COBALT ON TUNGSTEN-MODIFIED ALUMINA CATALYSTS FOR OLEFIN SYNTHESIS

225

(6)

B.G. Baker

S. Thomson

M. Jasieniak

HYDROGENATION OF CO AND CO2 WITH K AND Mn PROMOTED IRON CATALYSTS

231

(6)

M.L. Cubeiro

G. Valderrama

M.R. Goldwasser

F. Gonzalez-Jimenez

M.C. Da Silva

M.J. Perez-Zurita

REOXIDATION OF SUPPORTED COBALT FISCHER-TROPSCH CATALYSTS

237

(6)

A.M. Hilmen

D. Schanke

A. Holmen

FISCHER-TROPSCH SYNTHESIS: DRIFTS AND SIMS SURFACE INVESTIGATION OF Co AND Co/Ru ON TITANIA SUPPORTS

243

(6)

J.G. Price

D. Glasser

D. Hildebrandt

N.J. Coville

NASCENT CHARACTERISTICS OF COBALT-BASED FISCHER-TROPSCH CATALYSTS

249

(8)

G. Hills

H. Chen

A.A. Adesina

4. NOVEL METHANE REACTIONS

257

(36)

THE CONVERSION OF METHANE TO BENZENE OVER Mo/ZSM-5 ZEOLITES IN THE ABSENCE OF AN OXIDANT

257

(6)

J.H. Lunsford

M.P. Rosynek

D. Wang

METHANE HOMOLOGATION ON Co SUPPORTED CATALYSTS

263

(6)

G. Boskovic

J.S.M. Zadeh

K.J. Smith

METHANE TO VINYL CHLORIDE BY "CHLORO-PYROLYSIS" OF METHYLCHLORIDE

269

(6)

P.M. Marquaire

M.Al Kazzaz

Y. Muller

J. Saint Just

PALLADIUM-CATALYZED ACETIC ACID SYNTHESIS FROM METHANE AND CARBON DIOXIDE

275

(4)

Y. Fujiwara

Y. Taniguchi

K. Takaki

M. Kurioka

T. Jintoku

T. Kitamura

FORMATION OF ETHANE AND ETHYLENE BY THE REACTION OF METHANE AND CARBON DIOXIDE OVER UNSUPPORTED METAL OXIDES

279

(6)

K. Asami

K. Kusakabe

N. Ashi

Y. Ohtsuka

REACTION CHARACTERISATION AND MECHANISM FOR THE SELECTIVE REDUCTION OF NITROGEN OXIDES BY METHANE OVER COBALT-CONTAINING MEDIUM PORE ZEOLITES

285

(8)

A.D. Cowan

N.W. Cant

5. OXIDATIVE COUPLING

293

(104)

BENEFICIAL EFFECTS OF INORGANIC CHLORINE GRAFTING ON Sm2Sn2O7 PYROCHLORE DURING OXIDATIVE COUPLING OF METHANE

293

(8)

A.C. Roger

C. Petit

S. Libs

J.F. Koenig

A. Kiennemann

DIRECT OXIDATIVE CONVERSION OF METHANE INTO HIGHER HYDROCARBONS AND OXY-PRODUCTS IN THE PRESENCE OF HYDROGEN PEROXIDE

301

(6)

I. Eskendirov

N.J. Coville

A. Parmaliana

V.D. Sokolovskii

OXIDATIVE COUPLING OF METHANE TO ETHYLENE WITH 85% YIELD IN A GAS RECYCLE ELECTROCATALYTIC OR CATALYTIC REACTOR SEPARATOR

307

(6)

I.V. Yentekakis

Y. Jiang

M. Makri

C.G. Vayenas

METHANE OXIDATIVE COUPLING OVER METALLO OXIDE CATALYSTS

313

(6)

Z. Kalenik

E.E. Wolf

OXIDATIVE COUPLING OF METHANE OVER NATURAL CALCIUM COMPOUNDS IN FIXED-AND FLUIDIZED-BED REACTORS

319

(6)

T. Wakatsuki

M. Yamamura

H. Okado

K. Chaki

S. Okada

K. Inaba

S. Suzuki

T. Yoshinari

METHANE OXIDATIVE COUPLING USING POROUS CERAMIC MEMBRANE REACTORS. EFFECT OF AN INCREASED PERMEATION FLUX

325

(8)

J. Coronas

M. Menendez

J. Santamaria

COMPARATIVE STUDY ON LOW TEMPERATURE METHANE ACTIVATION OVER COBALT AND RUTHENIUM SUPPORTED ON Al2O3, SiO3 AND NaY

333

(6)

L. Guczi

K. V. Sharma

Zs. Koppany

R. Sundararajan

Z. Zsoldos

A REACTION-SEPARATION COMBINED OCM PROCESS FOR HIGH C2 HYDROCARBON YIELDS

339

(6)

Y. Jiang

C. Yu

W. Li

J. Yan

Y. Ji

STRUCTURE SENSITIVITY OF OXIDATIVE COUPLING OF METHANE AND DEHYDROGENATION OF ETHANE OVER LANTHANA CATALYSTS

345

(6)

C. Mirodatos

G. Xu

S. Lacombe

V. Ducarme

W. Li

G.A. Martin

KINETIC LIMIT OF C2 HYDROCARBONS YIELD AT GAS-PHASE OXIDATIVE COUPLING OF METHANE

351

(4)

V.S. Arutyunov

V. Ya. Basevich

V.I. Vedeneev

MEASUREMENT OF KINETIC ISOTOPE EFFECTS OVER METHANE COUPLING CATALYSTS IN THE PRESENCE OF CARBON DIOXIDE

355

(6)

N.W. Cant

P.F. Nelson

B.L. Duffy

OXIDATIVE DEHYDROGENATION OF ETHANE AT LOW TEMPERATURE OVER NICKEL CATALYSTS: INFLUENCE OF MORPHOLOGY AND CHEMICAL STATE OF THE SOLID DURING REACTION

361

(6)

V. Ducarme

H.M. Swaan

A. Thaib

G.A. Martin

DEHYDROGENATIVE COUPLING OF METHANE IN THERMAL DIFFUSION REACTOR WITH PLATINUM IMPREGNATED CARBON ROD AS A PYROGEN

367

(6)

K. Onoe

S. Suzuki

T. Yamaguchi

OXIDATIVE COUPLING OF METHANE OVER Li/Sn/MgO CATALYSTS. USE OF A FLUIDIZED BED REACTOR AT LOW GAS VELOCITIES

373

(6)

A. Santos

M. Menendez

J. Santamaria

OXIDATIVE COUPLING OF METHANE BY WATER

379

(4)

X. Li

K. Tomishige

K. Fujimoto

EFFECT OF GAS PHASE REACTIONS IN THE OXIDATIVE COUPLING OF METHANE

383

(6)

P.M. Marquaire

N. Gueritey

G.-M. Come

F. Baronnet

OXIDATIVE METHANE COUPLING. PROSPECTS AND CONCEPTUAL DESIGN FOR CO-GENERATION OF OLEFINS AND ELECTRIC POWER WITH REDUCED CO2 EMISSION AND FEED STOCK DEMAND

389

(8)

J.M.L. Penninger

6. PARTIAL OXIDATION

397

(94)

HYDROGEN PRODUCTION ON NICKEL-MONOLITH STRUCTURES BY PARTIAL OXIDATION OF METHANE AT HIGH PRESSURE

397

(6)

J.P. Gomez

J.M. Jimenez

S. Vic

J. Lezaun

P. Terreros

I. Cabrera

M.A. Pena

J.L.G. Fierro

NEW HIGHLY ACTIVE CATALYSTS IN DIRECT PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS

403

(6)

A.G. Steghuis

J.G. van Ommen

K. Seshan

J.A. Lercher

DEVELOPMENT OF DENSE CERAMIC MEMBRANES FOR METHANE CONVERSION

409

(6)

U. Balachandran

J.T. Dusek

P.S. Maiya

B. Ma

R.L. Mieville

M.S. Kleefisch

C.A. Udovich

T.H. Fleisch

A.C. Bose

PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS-EXPERIMENTAL AND MODELLING STUDIES

415

(6)

K. Heitnes Hofstad

B. Andersson

A. Holmgren

O.A. Rokstad

A. Holmen

CATALYTIC PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS-CATALYSIS AND REACTION ENGINEERING

421

(8)

M. Baerns

O.V> Buyevskaya

L. Mleczko

D. Wolf

SYNGAS PRODUCTION BY PARTIAL OXIDATION OF METHANE: DEPENDENCE OF REACTIVITY ON CATALYST PROPERTIES AND CONTACT TIME

429

(6)

L. Basini

M. D'Amore

G. Fornasari

D. Matteuzzi

D. Sanfilippo

F. Trifiro

A. Vaccari

PARTIAL OXIDATION OF METHANE TO SYNTHESIS GAS OVER SUPPORTED RUTHENIUM CATALYSTS

435

(6)

J. Boucouvalas

A.M. Efstathiou

Z.L. Zhang

X.E. Verykios

PARTIAL OXIDATION OF METHANE TO SYNGAS OVER Ni-LOADED ULTRASTABLE HY ZEOLITE CATALYSIS

441

(6)

M.A. Pena

B. Pawelec

P. Terreros

J.L.G. Fierro

J. Lezaun

J.P. Gomez

J.M. Jimenez

S. Vic

PARTIAL OXIDATION OF METHANE OVER NICKEL-AND COBALT-BASED CATALYSTS

447

(8)

H.M. Swaan

R. Rouanet

P. Widyananda

C. Mirodatos

INTERNAL AND EXTERNAL TRANSPORT EFFECTS DURING THE OXIDATIVE REFORMING OF METHANE ON A COMMERCIAL STEAM REFORMING CATALYST

455

(6)

J.N. Theron

M.E. Dry

E. van Steen

J.C.Q. Fletcher

HIGH YIELD SYNGAS FORMATION BY PARTIAL OXIDATION OF METHANE OVER Co-ALUMINA CATALYSTS

461

(6)

V.D. Sokolovskii

J.C. Jeannot

N.J. Coville

D. Glasser

D. Hildebrandt

M. Makoa

EFFECT OF La2O3 ADDED TO NiO/Al2O3 CATALYST ON PARTIAL OXIDATION OF METHANE TO SYNGAS

467

(6)

L. Cao

Y. Chen

W. Li

THE ROLE OF CATALYSIS IN THE CONVERSION OF NATURAL GAS FOR POWER GENERATION

473

(18)

J.R. Rostrup-Nielsen

K. Aasberg-Petersen

P.S. Schoubye

7. REFORMING

491

(82)

A COMPARISON OF NICKEL AND RHODIUM CATALYSTS FOR THE REFORMING OF METHANE BY CARBON DIOXIDE

491

(6)

N.W. Cant

R. Dumpelmann

A.M. Maitra

THE INFLUENCE OF RARE EARTH OXIDES ON Ni/Al2O3 CATALYSTS DURING CO2 REFORMING OF CH4

497

(6)

A. Slagtern

U. Olsbye

R. Blom

I.M. Dahl

STUDIES ON Ni/Al2O3 CATALYST FOR CO2 REFORMING OF CH4 TO SYNTHESIS GAS--A COMBINED RESEARCH FOR TPD, TPPR AND XPS

503

(8)

C. Yu

Y. Lu

X. Ding

S. Shen

PERFORMANCE OF Ni/La2O3 CATALYST IN CARBON DIOXIDE REFORMING OF METHANE TO SYNTHESIS GAS

511

(6)

Z. Zhang

X. Verykios

A NEW ROUTE TO SYNGAS--COMBINED CONVERSION OF CARBON DIOXIDE AND ETHANE ON ZEOLITES

517

(8)

F. Roessner

O. Klepel

A. Hagen

REACTION OF CH4 WITH CO2 AND H2O OVER SUPPORTED lr CATALYST

525

(6)

A. Erdohelyi

K. Fodor

F. Solymosi

THE PRODUCTION OF SYNTHESIS GAS BY THE REDOX OF CERIUM OXIDE

531

(6)

K. Otsuka

E. Sunada

T. Ushiyama

I. Yamanaka

THE DEVELOPMENT OF PLATINUM-ZIRCONIA CATALYSTS FOR THE CO2 REFORMING OF METHANE

537

(10)

A.N.J. van Keulen

M.E.S. Hegarty

J.R.H. Ross

P.F. van den Oosterkamp

LOW-TEMPERATURE SYNGAS FORMATION BY CO2 REFORMING OF METHANE IN A HYDROGEN-PERMSELECTIVE MEMBRANE REACTOR

547

(8)

E. Kikuchi

Y. Chen

CO2 REFORMING OF METHANE IN A MEMBRANE REACTOR

555

(6)

A.A. Ponelis

P.G.S. van Zyl

MEMBRANE REACTORS--A NEW TECHNOLOGY FOR PRODUCTION OF SYNTHESIS GAS BY STEAM REFORMING

561

(6)

J. Sogge

T. Strom

A GAS FIRED HEAT-PIPE REFORMER FOR SMALL-SCALE HYDROGEN PRODUCTION

567

(6)

J.T. Richardson

AUTHOR INDEX

573

(4)

OTHER VOLUMES IN THE SERIES

577

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Natural Gas Conversion IV : Proceedings of the 4th International Natural Gas Conversion Symposium, Kruger Park, South Africa, November 19-23, 1995

Table of Contents

Supplemental Materials

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Natural Gas Conversion IV : Proceedings of the 4th International Natural Gas Conversion Symposium, Kruger Park, South Africa, November 19-23, 1995

Table of Contents

Supplemental Materials

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