Organic Chemistry
, by Carey, Francis A.- ISBN: 9780073311845 | 0073311847
- Cover: Hardcover
- Copyright: 1/9/2007
Structure Determines Properties | |
Atoms, Electrons, and Orbitals | |
Ionic Bonds | |
Covalent Bonds, Lewis Structures, and the Ocelet Rule | |
Double Bonds and Triple Bonds | |
Polar Covalent Bonds and Electronegativity Electrostatic Potential Maps | |
Structural Formuala of Organic Molecules | |
Formal Charge | |
Resonance | |
The Shape of Some Simple Molecules Molecular Modeling | |
Molecular Dipole Moments | |
Curved Arrows and Chemical Reactions | |
Acids and Bases: The Arrhenius View | |
Acids and Bases: The Brønsted-Lowry View | |
What Happened to pKb? | |
How Structure Affects Acid Strength | |
Acid-Base Equilibria | |
Lewis Acids and Lewis Bases | |
Summary Problems Descriptive Passage and Interpretive Problems 1: Amide Lewis Structures | |
Alkanes and Cycloakanes: Introduction to Hydrocarbons | |
Classes of Hydrocarbons | |
Electron Waves and Chemical Bonds | |
Bonding in H2: The Valence Bond Model | |
Bonding in H2: The Molecular Orbital Model | |
Introduction to Alkanes: Methane, Ethane, and Propane Methane and the Biosphere | |
sp3 Hybridization and Bonding in Methane | |
Bonding in Ethane | |
Isomeric Alkanes: The Butanes | |
Higher n -Alkanes | |
The C5H12 Isomers | |
IUPAC Nomenclature of Unbranched Alkanes What''s in a Name? Organic Nonmenclature | |
Applying the IUPAC Rules: The Names of the C6H14 Isomers | |
Alkyl Groups | |
IUPAC Names of Highly Branched Alkanes | |
Cycloalkane Nomenclature | |
Sources of Alkanes and Cycloalkanes | |
Physical Properties of Alkanes and Cycloalkanes | |
Chemical Properties. Combustion of Alkanes | |
Oxidation-Reduction in Organic Chemistry Thermochemistry | |
sp2 Hybridization and Bonding in Ethylene | |
sp Hybridization and Bonding in Acetylene | |
Which Theory of Chemical Bonding is Best? | |
Summary Problems Descriptive Passage and Interpretive Problems 2: Some Biochemical Reactions of Alkanes | |
Alkanes andCycloalkanes: Conformations and cis-trans Stereoisomers | |
Conformational Analysis of Ethane | |
Conformational Analysis of Butane Molecular Mechanics Applied to Alkanes and Cycloalkanes | |
Conformations of Higher Alkanes | |
The Shapes of Cycloalkanes: Planar or Nonplanar | |
Small Rings: Cyclopropane and Cyclobutane | |
Cyclopentane | |
Conformations of Cyclohexane | |
Axial and Equatorial Bonds in Cyclohexane | |
Conformational Inversion (Ring Flipping) in Cyclohexane | |
Conformational Analysis of Monosubstituted Cyclohexanes | |
Disubstituted Cycloalkanes. Stereoisomers Enthalpy, Free Energy, and Equilibrium Constant | |
Conformational Analysis of Disubstituted Cyclohexanes | |
Medium and Large Rings | |
Polycyclic Ring Systems | |
Heterocyclic Compounds | |
Summary Problems Descriptive Passage and Interpretive Problems 3: Cylic Forms of Carbohydrates | |
Alcohols and Alkyl Halides | |
Functional Groups | |
IUPAC Nomenclature of Alkyl Halides | |
IUPAC Nomenclature of Alcohols | |
Classes of Alcohols and Alkyl Halides | |
Bonding in Alcohols and Alkyl Halides | |
Physical Properties of Alcohols and Alkyl Halides: Intermolecular Forces | |
Preparation of Alkyl Halides From Alcohols and Hydrogen Halides | |
Mechanism of the Reaction of Alcohols with Hydrogen Halides | |
Potential Energy Diagrams for Multistep Reactions. The SN1 Mechanism | |
Structure, Bonding, and Stability of Carbocations | |
Effect of Alcohol Structure on Reaction Rate | |
Reaction of Primary Alcohols with Hydrogen Halides. The SN2 Mechanism | |
Other Methods for Converting Alcohols to Alkyl Halides | |
Halogenation of Alkanes | |
Chlorination of Methane | |
Structure and Stability of Free Radicals | |
Mechanism of Methane Chlorination | |
Halogenation of Higher Alkanes From Bond Enthalpies to Heats of Reaction | |
Summary Problems Descriptive Passage and Interpretive Problems 4: More About Potential Energy Diagrams | |
Structure and Preparation of Alkenes: Elimination Reactions | |
Alkene Nomenclature | |
Structure and Bonding in Alkenes Ethylene | |
Isomerism in Alkenes | |
Naming Stereoisomeric Alkenes by the E-Z Notational System | |
Physical Properties on Alkenes | |
Relative Stabilities of Alkenes | |
Cycloalkenes | |
Preparations of Alkenes: Elimination Reactions | |
Dehydration of Alcohols | |
Regioselectivity in Alcohol Dehydration: The Zaitsev Rule | |
Stereoselectivity in Alcohol Dehydration | |
The E1 and E2 Mechanisms of Alcohol Dehydration | |
Rearrangements in Alcohol Dehydration | |
Dehydrohalogenation of Alkyl Halides | |
The E2 Mechanism of Dehydrohalogenation of Alkyl Halides | |
Anti Elimination in E2 Reactions: Stereoelectronic Effects | |
Isotope Effects and the E2 Mechanism | |
The E1 Mechanism of Dehydrohalogenation of Alkyl Halides | |
Summary Problems Descriptive Passage and Interpretive Problems 5: A Mechanistic Preview of Addition Reactions | |
Reactions of Alkenes | |
Hydrogenation of Alkenes | |
Heats of Hydrogenation | |
Stereochemistry of Alkene Hydrogenation | |
Electrophilic Addition of Hydrogen Halides to Alkenes | |
Regioselectivity of Hydrogen Halide Addition: Markovnikov''s Rule | |
Mechanistic Basis for Markovnikov''s Rule Rules, Laws, Theories, and the Scientific Method | |
Carbocation Rearrangements in Hydrogen Halide Addition to Alkenes | |
Free-Radical Addition of Hydrogen Bromide to Alkenes | |
Addition of Sulfuric Acid to Alkenes | |
Acid-Catalyzed Hydration of Alkenes | |
Thermodynamics of Addition - Elimination Equilibria | |
Hydroboration-Oxidation of Alkenes | |
Stereochemistry of Hydroboration-Oxidation | |
Mechanism of Hydroboration-Oxidation | |
Addition of Halogens to Alkenes | |
Stereochemistry of Halogen Addition | |
Mechanism of Halogen Addition to Alkenes: Halonium Ions | |
Conversion of Alkenes to Vicinal Halohydrins | |
Epoxidation of Alkenes | |
Ozonolysis of Alkenes | |
Introduction to Organic Chemical Synthesis | |
Reactions of Alkenes with Alkenes: Polymerization Ethylene and Propane: The Most Important Industrial Organic Chemicals | |
Summary Problems Descriptive Passage and Interpretive Problems 6: Some Unusual Electrophilic Additions | |
Stereochemistry | |
Molecular Chirality: Enantiomers | |
The Chirality Center | |
Symmetry in Achiral Structures | |
Optical Activity | |
Absolute and Relative Configuration | |
The Cahn-Ingold-Prelog R-S Notation System | |
Fischer Projections | |
Properties of Enantiomers Chiral Drugs | |
Reactions That Create a Chirality Center | |
Chiral Molecules With Two Chirality Centers | |
Achiral Molecules With Two Chirality Centers | |
Molecules With Multiple Chirality Centers Chirality of Disubstituted Cyclohexanes | |
Reactions That Produce Diastereomers | |
Resolution of Enantiomers | |
Stereoregular Polymers | |
Chirality Centers Other Than Carbon | |
Summary Problems Descriptive Passage and Interpretive Problems 7: Prochirality | |
Nucleophilic Substitution | |
Functional Group Transformation by Nucleophilic Substitution | |
Relative Reactivity of Halide Leaving Groups | |
The SN2 Mechanism of Nucleophilic Substitution | |
Steric Effects and SN2 Reaction Rates | |
Nucleophiles and Nucleophilicity | |
The SN1 Mechanism of Nucleophilic Substitution Enzyme-Catalyzed Nucleophilic Substitution of Alkyl Halides | |
Carbocation Stability and SN1 Reaction Rates | |
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