PEDOT: Principles and Applications of an Intrinsically Conductive Polymer

Note: Supplemental materials are not guaranteed with Rental or Used book purchases.

ISBN: 9781420069112 | 142006911X
Cover: Hardcover
Copyright: 11/2/2010

Rent

(Recommended)

$168.80

Term

Due

Price

Semester

Dec 12

$177.68

Quarter

Aug 13

$168.80

Short Term

Jul 13

$159.91

*This item is part of an exclusive publisher rental program and requires an additional convenience fee. This fee will be reflected in the shopping cart.
Buy New

Usually Ships in 3-5 Business Days

$227.47
eBook

Available Instantly

Online: 180 Days

Downloadable: 180 Days

$191.40

While there is information available in handbooks on polythiophene chemistry and physics, until now there has been no book focusing exclusively on the most forwardly developed electrically conductive polymer, Poly (3,4-ethylenedioxythiophene), otherwise known as PEDOT. This resource provides the full chemical, physical, and technical information about this important conducting polymer. Discussing basic knowledge and exploring technical applications, the book is based on information generated by universities and academic research, as well as by industrial scientists, providing a full picture of the experimental and the practical aspects.

Foreword	p. xi
Preface	p. xiii
Acknowledgments	p. xvii
Authors	p. xix
Abbreviations	p. xxi
The Discovery and Development of Conducting Polymers	p. 1
The Scope of This Historical Overview	p. 1
Introduction	p. 2
An Early Example: Polyaniline	p. 4
The First Electrically Conductive Poly(Heterocycle): Polypyrrole	p. 9
The Fundamental Breakthrough: Doped Polyacetylene	p. 10
References	p. 15
Conductive Polymers versus Metals and Insulators	p. 21
Metals, Semiconductors, and Insulators	p. 21
Conjugated Polymers	p. 22
Temperature-Dependent Conductivity	p. 24
Order and Disorder	p. 26
References	p. 29
Polythiophenes: A Chance for Maximum Conductivity?	p. 31
Introduction	p. 31
Oxygen-Substituted Polythiophenes	p. 33
References	p. 38
A Short History of the PEDOT Invention	p. 41
References	p. 46
The Synthesis of EDOT Monomer, and Its Physical and Chemical Properties	p. 47
Monomer Synthesis	p. 47
Physical Properties	p. 50
Chemical Properties	p. 53
References	p. 63
From EDOT to PEDOT: Oxidative Polymerization and Other Routes	p. 67
Oxidative Polymerization and Doping	p. 67
ôSelf-Oxidationö of EDOT Halogen Derivatives	p. 72
The Organometallic Route to PEDOT	p. 74
Neutral, Undoped PEDOT by Oxidative Polymerization	p. 76
References	p. 79
Counterfoils for PEDOT	p. 83
Counterions in Electrochemically Polymerized PEDOT	p. 83
Counterions in Chemically Polymerized PEDOT	p. 86
References	p. 87
The In Situ Polymerization of EDOT to PEDOT	p. 91
Synthesis of In Situ PEDOT	p. 91
Properties of In Situ PEDOT	p. 97
In Situ Polymerization of EDOT Derivatives and Relatives	p. 102
References	p. 109
PEDOT:PSS	p. 113
PEDOT:PSS Dispersions	p. 113
Introduction	p. 113
Polyelectrolyte Complexes	p. 113
Synthesis of a PEDOT:PSS Complex	p. 117
Commercial PEDOT:PSS Types and Their Properties	p. 122
Properties of PEDOT:PSS	p. 123
Deposition of PEDOT:PSS	p. 123
Thin-Film Properties	p. 123
Thermal and Lifetime Stability	p. 123
UV Stability	p. 126
Water Uptake	p. 128
Mechanical Properties	p. 130
Morphology: Surface and Bulk	p. 131
Electronic States	p. 136
UV-Vis (Ultraviolet-Visible) Spectra	p. 136
Energy Levels in PEDOT	p. 137
Optical Constants	p. 142
Vibrational Spectra	p. 143
Electrical Properties	p. 144
Conductivity	p. 144
Microscopic Model for Conductivity in PEDOT:PSS	p. 144
Free Charge Carrier Mobility	p. 147
Threshold Currents	p. 148
Secondary Doping	p. 149
Introduction	p. 149
The Chemical Nature of Secondary Dopants in PEDOT:PSS	p. 150
Properties of PEDOT:PSS Films Including Secondary Dopants	p. 152
Conductivity as a Function of Temperature	p. 152
X-Ray Diffraction	p. 152
Optical Characterization of PEDOT:PSS Films	p. 153
Surface Analysis of PEDOT:PSS Films	p. 153
Atomic Force Microscopy and Scanning Tunnel Microscopy	p. 154
Work Function and Electron Paramagnetic Resonance	p. 155
Discussion	p. 156
References	p. 158
Applications	p. 167
Solid Electrolyte Capacitors	p. 167
Introduction	p. 167
Capacitor Basics	p. 169
Design of Solid Electrolyte Capacitors	p. 170
Deposition Methods for PEDOT Cathode	p. 172
Electrochemical Oxidative Polymerization	p. 174
Chemical Oxidative Polymerization	p. 175
Conducting Polymer Dispersions	p. 177
Reformation and High Voltage Application	p. 179
Self-Healing and Thermal Runaway	p. 182
Conclusions	p. 183
Through Hole Plating for Printed Wiring Boards	p. 184
ITO Substitution	p. 188
Antistatic Coatings	p. 194
Solvents	p. 198
Surfactants	p. 199
Binders	p. 199
Hardness and Abrasion	p. 200
Conductivity-Enhancing Additives	p. 201
Use of PEDOT in Antistatic Coatings	p. 202
Electroluminescent Lamps	p. 204
Organic Light Emitting Diodes (OLEDs)	p. 205
Introduction	p. 205
PEDOT:PSS as a Hole-Injection Layer	p. 207
The PEDOT:PSS-Semiconductor Interface	p. 209
Lifetime Restraints by PEDOT:PSS Hole Injection Layers	p. 213
Modified PEDOT-Based Materials for HILs	p. 214
PEDOT:PSS in Organic Solar Cells	p. 216
Introduction	p. 216
PEDOT:PSS as a Transparent Anode in OSCs	p. 217
PEDOT:PSS as a Buffer Layer in OSCs	p. 218
PEDOT:PSS in Dye-Sensitized Solar Cells	p. 221
Electrochromic Behavior	p. 222
Introduction	p. 222
Control of Optical Properties	p. 226
EDOT Derivatives	p. 229
Copolymers	p. 231
Organic-Inorganic Hybrid Polymers	p. 233
PEDOT with Pendant Electrochromic Dyes	p. 233
Blends and Layer-by-Layer Deposition	p. 234
Electrolytes	p. 235
Ion Storage Materials	p. 236
Dual Polymer Cells	p. 237
Substrates and Patterning	p. 237
Organic Field-Effect Transistors	p. 238
Introduction	p. 238
PEDOT:PSS as Electrodes	p. 239
PEDOT:PSS as an Interlayer	p. 241
PEDOT:PSS as an Active Layer	p. 242
References	p. 244
Technical Use and Commercial Aspects	p. 265
References	p. 269
EDOT and PEDOT Derivatives with Covalently Attached Side Groups	p. 271
EDOT-CH₂OH and Its Derivatives	p. 271
EDOT-CH₂Cl and Its Follow-Up Products	p. 280
Alkyl EDOTs	p. 282
Water Soluble, ôSelf-Dopingö EDOT Derivatives	p. 286
References	p. 289
XDOTs, EDXTs, EDOXs, and 2(5)-X₍₂₎-EDQTs: Ring Size Variations, Heteroanalogs, and Derivatives of EDOT with Substituents at the Thiophene Ring	p. 293
3,4-Methylenedioxythiophene (MDOT)	p. 293
ProDOT (Propylenedioxythiophene) Derivatives	p. 295
Vinylenedioxythiophene (VDOT) and Benzo-EDOT	p. 299
3,4-Ethyleneoxythiathiophene (EOTT)	p. 301
3,4-Ethylenedithiathiophene (EDTT)	p. 304
3,4-Ethylenedioxypyrrole (EDOP) and Its Derivatives	p. 306
3,4-Ethylenedioxyselenophene (EDOS)	p. 309
2,5-Disubstituted EDOT Derivatives [2(,5)-X₍₂₎-EDOTs]	p. 311
References	p. 322
The Electrochemical Behavior of EDOT and PEDOT	p. 329
References	p. 340
Index	p. 345
Table of Contents provided by Ingram. All Rights Reserved.

Please wait while the item is added to your bag...

FREE SHIPPING

Rent More, Save More! Use code: BBRENTAL

5% off 1 book, 7% off 2 books, 10% off 3+ books

PEDOT: Principles and Applications of an Intrinsically Conductive Polymer

Summary

Table of Contents

Supplemental Materials

FREE SHIPPING

Rent More, Save More! Use code: BBRENTAL

5% off 1 book, 7% off 2 books, 10% off 3+ books

PEDOT: Principles and Applications of an Intrinsically Conductive Polymer

Summary

Table of Contents

Supplemental Materials

Digital License