Recoverable and Recyclable Catalysts

Drawing on international research, this book serves as a practical guide to the use of recoverable and recyclable catalysts. It includes an introductory chapter on the general principles of catalyst recovery and recycling, and follows with chapters on catalysts on insoluble or soluble supports, thermoresponsive catalysts, self-supported catalysts, perfluorous catalytic systems, biphasic systems, recoverable organic catalysts, microencapsulated catalysts, flow/membrane reactors, and microreactor technologies. Each chapter combines basic general principles, practical information on the design and synthesis of catalysts, and strategies for catalyst recovery. The book concludes with a comparison of several different catalytic systems, so the reader can easily compare a given catalysts, and the positive and negative features of each approach.

Maurizio Benaglia is Associate Professor at the Department of Organic and Industrial Chemistry, University of Milan, Italy. He is author of over ninety publications in international scientific journals, including five review articles. His current research focuses on stereoselective reactions, synthesis of chiral supramolecular systems, synthesis of supported organometallic and metal-free catalysts, and design and synthesis of new chiral catalysts, and environmentally pure catalysts.

Preface
Acknowledgements
Contributors
The Experimental Assay of Catalyst Recovery: General Concepts
Introduction
Catalyst Precursor vs Catalyst
Catalyst vs Catalyst Resting State
Catalyst Inventory: Loss Mechanisms
Evaluation of Catalyst Recovery
Prospective
References
Surface-functionalized Nanoporous Catalysts for Renewable Chemistry
Introduction
Immobilization Strategies of Heterogeneous Catalysts
Efficient Heterogeneous Catalysts with Enhanced Reactivity and Selectivity with Functionality
Other Heterogeneous Catalyst Systems on Nonsilica Supports
Conclusion
References
Insoluble Resin-supported Catalysts
Introduction
Transition Metal Catalyzed C_C Bond Formation Reactions
Oxidation
Reduction
Organocatalyzed Reactions
Annulation Reactions
Miscellaneous
Conclusion
References
Catalysts Bound to Soluble Polymers
Introduction
Soluble Supports - General Considerations
Recent Developments of Soluble Polymer-supported Catalysts
Recent Examples for Reactions Promoted by Catalysts Bound to Soluble Polymers
Conclusion
List of Abbreviations
References
Polymeric, Recoverable Catalytic Systems
Introduction
Polymeric Catalyst Systems
Summary
Acknowledgements
References
Thermomorphic Catalysts
Introduction
Thermomorphic Catalyst Separation Strategies
Hydrogenation Reactions Under Thermomorphic Conditions
Hydroformylation Reactions Under Thermomorphic Conditions
Hydroaminations Under Thermomorphic Conditions
Pd-catalyzed Reactions Under Thermomorphic Conditions
Polymerization Reactions Under Thermomorphic Conditions
Organocatalysis Under Thermomorphic Conditions
Cu(I)-catalyzed 1,3-Dipolar Cycloadditions Under Thermomorphic Conditions
Thermomorphic Hydrosilylation Catalysts
Thermomorphic Catalytic Oxidations
Conclusions
References
Self-supported Asymmetric Catalysts
Introduction
Self-supported Asymmetric Catalysts Formed by Linking Catalytically Active Subunits via Metal-Ligand Coordination
Self-supported Asymmetric Catalysts Formed by Post-synthetic Modifications of Coordination Polymers
Self-supported Asymmetric Catalysts Formed by Linking Multitopic Chiral Ligands with Catalytic Metal Centers
Conclusions and Outlook
Acknowledgments
References
Fluorous Chiral Catalyst Immobilization
Introduction
Fluorous Chemistry and its Basic Recovery Concepts
Application of Fluorous Chiral Catalysts
Summary
References
Biphasic Catalysis: Catalysis in Supercritical CO2 and in Water
Introduction
Biphasic Catalysis
Aqueous Biphasic Catalysis
Supercritical Carbon Dioxide
Conclusion
References
Asymmetric Catalysis in Ionic Liquids
Introduction
Metal-catalyzed Asymmetric Reactions in ILs
Asymmetric Organocatalytic Reactions in ILs
Concluding Remarks
References
Recoverable Organic Catalysts
Introduction
Achiral Organic Catalysts
Chiral Organic Catalysts
Catalysts Derived from Amino Acids
General Considerations on Recyclable Organocatalysts
Outlook and Perspectives
References
Organic Polymer-microencapsulated Metal Catalysts
Introduction
Non-cross-linked Polymer-microencapsulated Catalysts
Cross-linked Polymer-microencapsulated Catalysts
Summary Table
Conclusions
References
Organic Synthesis with Mini Flow Reactors Using Immobilised Catalysts
Introduction
Catalysis in Mini Flow Reactors with Immobilised Catalysts
Miscellaneous Enabling Techniques for Mini Flow Systems
Perspectives and Outlook
References
Homogeneous Catalysis Using Microreactor Technology
Introduction
Acid-catalysed Reactions
Liquid-liquid Biphasic Systems
Photocatalysis
Asymmetric Catalytic Reactions
Unusual Reaction Conditions
References
Catalyst Immobilization Strategy: Some General Considerations and a Comparison of the Main Features of Different Supports
Introduction
General Considerations on Catalyst Immobilization
Comparison of Different Supports Employed for the Immobilization of Proline
Comparison of Different Supports Employed for the Immobilization of Bis(oxazolines)
Conclusions
References
Index
Table of Contents provided by Publisher. All Rights Reserved.

What is included with this book?

The New copy of this book will include any supplemental materials advertised. Please check the title of the book to determine if it should include any access cards, study guides, lab manuals, CDs, etc.

The Used, Rental and eBook copies of this book are not guaranteed to include any supplemental materials. Typically, only the book itself is included. This is true even if the title states it includes any access cards, study guides, lab manuals, CDs, etc.

FREE SHIPPING

Amazon no longer offers textbook rentals. We do!

Recoverable and Recyclable Catalysts

Summary

Author Biography

Table of Contents

Supplemental Materials