- ISBN: 9783527339105 | 3527339108
- Cover: Hardcover
- Copyright: 1/17/2017
Edited and written by renowned experts in the field, this is the first book to reflect the state of the art of nanocatalysis in ionic liquids.
Divided into two core areas, the first part of the book describes the different classes of metal nanoparticles as well as their synthesis in ionic liquids, while the second focuses on such emerging issues as the application of such systems to energy and biomass conversion.
Divided into two core areas, the first part of the book describes the different classes of metal nanoparticles as well as their synthesis in ionic liquids, while the second focuses on such emerging issues as the application of such systems to energy and biomass conversion.
Martin Prechtl received the valuable Scientist NRW-Returnee Award 2009 and accepted an offer of the University of Cologne in Germany in 2010, where he also became Privatdozent and Heisenberg-Fellow in 2015. His research interest covers hydrogen storage and selective hydrogenation and dehydrogenation reactions with molecular and nanoscale catalysts in multiphase systems based on water or ionic liquids. Before moving to Cologne, he studied at the University of Wuppertal (Germany) and the Universidade de S?o Paulo (Brazil). In S?o Paulo he did research studies together with Jo?o Valdir Comasseto (catalysis) and Omar El Seoud (cellulose chemistry), and in Wuppertal he worked on his diploma thesis about ligand design and catalysis under Hans-Josef Altenbach. Martin Prechtl performed his PhD studies in the field of organometallic chemistry and catalysis at the Max-Planck-Institut fur Kohlenforschung in Mulheim/Ruhr in Germany under guidance of Walter Leitner and David Milstein on metal hydride complexes and received the doctoral degree from RWTH Aachen in 2007. Afterwards he worked as Feodor-Lynen-Fellow of the Alexander-von-Humboldt Foundation at the Universidade Federal do Rio Grande do Sul in Porto Alegre (Brazil) with Jairton Dupont and at the Humboldt University Berlin (Germany) with Thomas Braun and Erhard Kemnitz in the fields of nanoparticle synthesis and catalysis.
List of Contributors XI
Preface XV
Foreword XIX
Symbols and Abbreviations XXI
Part I Synthesis, Characterization, and Evaluation of Nanocatalysts in Ionic Liquids 1
1 Fe, Ru, and Os Nanoparticles 3
Madhu Kaushik, Yuting Feng, Nathaniel Boyce, and Audrey Moores
1.1 Introduction 3
1.2 Synthesis of Fe, Ru, and Os NPs in ILs 4
1.2.1 Synthesis via Reduction of Metal Precursors or Ligands 6
1.3 Ionic Liquid Stabilization of Metal Nanoparticles 9
1.4 Applications of Ru, Fe, and Os Nanoparticles to Catalysis 11
1.5 Conclusion 21
Acknowledgments 21
References 21
2 Co, Rh, and Ir Nanoparticles 25
Jackson D. Scholten andMuhammad I. Qadir
2.1 Introduction 25
2.2 Chemical Routes for the Synthesis of Metal NPs in ILs 26
2.3 Catalytic Application of Metal NPs in ILs 31
2.4 Conclusions 37
References 37
3 Ni and Pt Nanoparticles 41
Carla Weber Scheeren
3.1 Introduction 41
3.2 Synthesis and Characterization of Pt NPs in ILs 42
3.3 Catalytic Applications of Pt NPs in ILs 47
3.4 Synthesis and Characterization of Ni NPs in ILs 48
3.5 Catalytic Applications of Ni NPs in ILs 53
3.6 Summary and Conclusions 58
Symbols and Abbreviations 59
Characterization Methods 59
Ionic Liquids 59
References 59
4 Pd Nanoparticles for Coupling Reactions and Domino/Tandem Reactions 63
Anna M. Trzeciak
4.1 Introduction 63
4.2 Formation of Pd NPs in ILs 65
4.3 The Heck Coupling 68
4.4 The Suzuki Reaction 74
4.5 The Stille Coupling 75
4.6 The Sonogashira Coupling 76
4.7 Summary and Conclusions 78
Acknowledgments 79
References 79
5 Soluble Pd Nanoparticles for Catalytic Hydrogenation 83
Ran Zhang and Zhenshan Hou
5.1 Introduction 83
5.2 Synthesis of Pd Nanoparticles in ILs 85
5.3 Pd Nanoparticles for Hydrogenation 88
5.4 Summary and Conclusions 93
Ionic Liquid Abbreviations 93
References 94
6 Au, Ag, and Cu Nanostructures 97
Abhinandan Banerjee and RobertW. J. Scott
6.1 Introduction 97
6.2 Au NPs in the Presence of ILs 98
6.3 Catalytic Applications of AuNP/IL Composites 106
6.4 Ag NPs in the Presence of ILs 108
6.5 Cu NPs in the Presence of ILs 113
6.6 Summary and Conclusions 118
Acronyms 119
References 119
7 Bimetallic Nanoparticles in Ionic Liquids: Synthesis and Catalytic Applications 125
Isabelle Favier, Emmanuelle Teuma, and Montserrat Gómez
7.1 Introduction 125
7.2 Synthesis of Bimetallic Nanoparticles in Ionic Liquids 127
7.3 Applications in Catalysis 137
7.4 Summary and Outlook 143
Acknowledgments 144
References 144
8 Synthesis and Application of Metal Nanoparticle Catalysts in Ionic Liquid Media using Metal Carbonyl Complexes as Precursors 147
Raquel Marcos Esteban and Christoph Janiak
8.1 Introduction 147
8.2 Metal Carbonyls – Synthesis, Structure, and Bonding 150
8.3 Metal Carbonyls for the Synthesis of Metal Nanoparticles (M-NPs) 152
8.4 Catalytic Applications of Metal Nanoparticles from Metal Carbonyls in ILs 160
8.5 Conclusions 163
Acknowledgment 164
References 164
9 Top-Down Synthesis Methods for Nanoscale Catalysts 171
Tsukasa Torimoto, Tatsuya Kameyama, and Susumu Kuwabata
9.1 Introduction 171
9.2 Sputter Deposition of Metals in RTILs 172
9.3 Thermal Vapor Deposition on RTILs for Preparation of Metal Nanoparticles 196
9.4 Laser-Induced Downsizing and Ablation of Materials 197
9.5 Preparation of Single Crystals by Vapor Deposition onto RTILs 199
9.6 Conclusion 202
References 203
10 Electrochemical Preparation of Metal Nanoparticles in Ionic Liquids 207
Yasushi Katayama
10.1 Introduction 207
10.2 Basics of Electrodeposition 208
10.3 Electrodeposition of Silver and Formation of Silver Nanoparticles in Ionic Liquids 210
10.4 Electrochemical Formation of the Nanoparticles of Various Metals 215
10.5 Summary and Conclusions 225
References 227
Part II Perspectives for Application of Nanocatalysts in Ionic Liquids 231
11 Tailoring Biomass Conversions using Ionic Liquid Immobilized Metal Nanoparticles 233
Srinidhi Narayanan, Jiaguang Zhang, and Ning Yan
11.1 Introduction 233
11.2 Cellulose 234
11.3 Lignin 238
11.4 Fatty Acid and Its Derivatives 241
11.5 Other Biomass Substrates 243
11.6 Conclusion 245
References 245
12 Nanoparticles on Supported Ionic Liquid Phases – Opportunities for Application in Catalysis 249
Pedro Migowski, Kylie L. Luska, and Walter Leitner
12.1 Introduction 249
12.2 Synthesis of Supported Ionic Liquid Phases (SILPs) 250
12.3 Nanoparticles Immobilized onto Supported Ionic Liquid Phases (NPs@SILPs) 252
12.4 Catalytic Applications of NPs@SILPs 256
12.5 Summary and Conclusions 268
Acknowledgments 269
References 269
13 Photovoltaic, Photocatalytic Application, andWater Splitting 275
Adriano F. Feil, Heberton Wender, and Renato V. Gonçalves
13.1 Introduction 275
13.2 Photovoltaic Cells 276
13.3 Photocatalytic Processes 281
13.4 Water Splitting 285
13.5 Summary and Conclusions 291
References 292
Index 295
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