Textile Dyes and Pigments A Green Chemistry Approach
, by Pandit, Pintu; Singha, Kunal; Maity, Subhankar; Ahmed, Shakeel
- ISBN: 9781119904915 | 1119904919
- Cover: Hardcover
- Copyright: 9/7/2022
Textile Dyes and Pigments
The book covers the best possible innovation and advancement in dyes and pigments for application in textile materials.
Green chemistry can be applied across the life cycle of a chemical-intensive product, including its design, manufacture, use, and ultimate disposal. Innovations to green approaches are required either by developing a whole new set of eco-friendly dyes and pigments or by developing and designing unique dyeing methods.
Textile Dyes and Pigments: A Green Chemistry Approach is a response to the many industries currently using conventional textile dyeing and pigmentation methods that are looking for sustainable green chemical options. It describes the various organic and inorganic color pigments and recent developments in vat, reactive, disperse, acid, and azo dyes and their importance in the field of green chemistry. It also covers the various challenges, opportunities, approaches, techniques, marketing, and alternative procedures/sustainable routes involved in developing textile dyes and pigments with green practices. Moreover, the book addresses the structure, process, and the nitty-gritty of modern dyes and pigments in the textile and garment sectors.
Audience
The book will be of prime interest to researchers and industry manufacturers and engineers in dyes, pigments, textile processing technology, fiber technology, and textile chemistry. It will also be an invaluable reference guide to new scholars and industry personnel who wish to learn about green dyes and pigments and their relevant application processes.
Pintu Pandit is an assistant professor in the Textile Design Department at the National Institute of Fashion Technology under the Ministry of Textiles, Govt. of India, Patna campus. He is a PhD (Tech.) and M.Tech. in Fibers and Textile Processing Technology from the Institute of Chemical Technology, Mumbai, India. He has published many research articles in SCI journals as well as edited 4 books with the Wiley-Scrivener imprint.
Kunal Singha is an assistant professor in the Department of Textile Design at National Institute of Fashion Technology, Patna, India. He received M.Tech in fiber science and engineering from the Indian Institute of Technology Delhi and his PhD in supply and manufacturing chain & marketing from the Indian Institute Kharagpur.
Subhankar Maity is an assistant professor in the Department of Textile Technology in Uttar Pradesh Textile Technology Institute, Kanpur, India. His PhD was on textile technology and he has more than 10 years of industrial, teaching and research experience.
Shakeel Ahmed is an assistant professor in chemistry at the Higher Education Department, Government of Jammu and Kashmir, India. He obtained his PhD in the area of biopolymers and bionanaocomposites from Jamia Millia Islamia in the year 2016 and has published several research publications in the area of green nanomaterials and biopolymers for various applications including biomedical, packaging, sensors and water treatment.
Preface xxiii
1 Introduction to Advancement in Textile Dyes and Pigments 1
Pintu Pandit, Kunal Singha and Subhankar Maity
1.1 Introduction 1
1.2 Classification of Dyes 2
1.3 Advancement in Wet Processing Technology 5
1.4 Conclusions 14
References 15
2 Reactive Dye and Its Advancements 17
Sankar Roy Maulik, Ahana Bhattacharya, Partha Pratim Roy and Kausik Maiti
2.1 Introduction 17
2.2 Reactive Dyes—Classification 19
2.3 Methods of Application 24
2.4 Stripping of Reactive Dyes 26
2.5 Reactive Dyeing Process 26
2.6 Some Commercially Available Reactive Dyes 31
2.7 Reactive Dyes on Silk 37
2.8 Development of Reactive Dyes and Dyeing Process 38
2.9 Conclusion 41
Acknowledgment 42
References 42
3 Gravimetric Analysis, Kinetic Study and Optimization of Salt and Alkali in Reactive Dyeing 45
Anjum Ahmad, S.R. Shukla, Pintu Pandit and Saptarshi Maiti
3.1 Introduction 45
3.2 Materials and Methods 49
3.3 Results and Discussion 51
3.4 Conclusions 73
References 73
4 Applications of Chromic Dyes: Examples of Pressure-Sensitive Paint (PSP) and Dyes 75
Kunal Singha, Pintu Pandit, Subhankar Maity and Saptarshi Maiti
4.1 Introduction 75
4.2 Pressure-Sensitive Paint (PSP)—As Chromic Dye and Pigment Materials 76
4.3 PSP Luminance Material Optical Intensity Characterization 82
4.4 Basic Elements in PSP Setup 82
4.5 Advantage of PSP 84
4.6 Limitation of PSP 84
4.7 Conclusions 85
References 85
5 Vat Dye and Its Evolution in Dyeing 87
Sankar Roy Maulik, Deepasree Chakraborty, Manisha Mohanty and Chaitali Debnath
5.1 Introduction 87
5.2 Properties 88
5.3 Classification 88
5.4 Physical Form 93
5.5 Principle of Dyeing 93
5.6 Methods of Application 96
5.7 Stripping of Vat-Dyed Materials 100
5.8 Defects in Dyeing 100
5.9 Ecofriendly Reducing Agent 100
5.10 Conclusion 103
Acknowledgment 103
References 103
6 Advancement in Indigo Dyeing 107
Sankar Roy Maulik and Pintu Pandit
6.1 Introduction 107
6.2 Dyeing With Natural Indigo 110
6.3 Batik Work and Tie-Dye with Natural Indigo 111
6.4 Different Ecofriendly Reducing Agent 112
6.5 Chemical Properties and Dyeing 113
6.6 Indigo Denim 114
6.7 Method of Indigo Dyeing 114
6.8 Indigo Recovery and Reuse 117
6.9 Yellowing or Ozone Fading 118
6.10 Factors Affecting Indigo Destructions and Prevention of Yellowing 119
6.11 Conclusion 119
References 120
7 Advancement in Denim Dyeing 123
Sukumar Roy and Syamal Maiti
7.1 Introduction 123
7.2 Evaluation of Indigo Dyeing Technology for Denim 124
7.3 Chemical Vats 124
7.4 Modern Methods 125
7.5 Techniques of Denim Dyeing 125
7.6 Continuous Dyeing Techniques 126
7.7 Dyeing of Denim Garments 128
7.8 Garment Dyeing Process 129
7.9 Preparation of Garment Dyeing 129
7.10 Selection of Colorants for Garment Dyeing 130
7.11 After Treatments for Garment Dyed Fabrics 131
7.12 Garment Dyeing Machinery 131
7.13 Advances in Garment Dyeing 132
7.14 Conclusion 134
References 134
8 Ecofriendly Single-Bath Acid Dyeing and Multifunctional Finishing of Silk Fabric Using Coconut Shell Extract 137
Pintu Pandit and M. D. Teli
8.1 Introduction 137
8.2 Materials and Methods 138
8.3 Results and Discussion 141
8.4 Conclusions 158
References 159
9 Growths and Advancement of Disperse Dyes in Recent Years 161
Laimayum Jogeeta Devi, Oinam Roselyn Devi and Pintu Pandit
9.1 Introduction 161
9.2 Disperse Dyes 162
9.3 Application of Disperse Dyes in Polyester 165
9.4 Thermosol Process 167
9.5 Recent Advances in the Application of Disperse Dyes on Polyester 168
9.6 Toxicity of Disperse Dyes 170
9.7 Recent Development in Disperse Dye 170
9.8 Development of Nano Disperse Dye 172
9.9 Conclusions 173
References 173
10 Decolorization of C.I. Disperse Orange-25 Dye From Aqueous Solution by Using Modified Biopolymer: Adsorption Equilibrium, Kinetics, and Thermodynamics 177
Tejasvi Potdar, Vikrant Gorade and Ravindra D. Kale
10.1 Introduction 177
10.2 Materials and Methods 179
10.3 Results and Discussions 182
10.4 Conclusion 193
Acknowledgments 193
References 193
11 Ecofriendly Coloration of Polyester by Dispersant-Free Disperse Dyes 197
Chet Ram Meena
11.1 Introduction 197
11.2 Necessity of Ecofriendly Chemicals/Auxiliaries 198
11.3 Ecofriendly Practices in Textile Processing 199
11.4 Dyes and Their Limitations 201
11.5 Scopes for Development in Disperse Dyes 202
11.6 Chromophoric Systems of Disperse Dyes 204
11.7 Dispersing Agents 207
11.8 Dispersant-Free Disperse Dyes 209
11.9 Innovations in Coloration Techniques of Disperse Dye 212
11.10 Microencapsulated Dyeing 213
11.11 Electro Powder Spraying Process 213
11.12 Microemulsion Dyeing 214
11.13 Synthesis of Dispersant-Free Disperse Dye 214
11.14 Characterization of Synthesized Dyes 216
11.15 Dyeing of Polyester with Synthesized Dyes 217
11.16 Conclusions 221
References 222
12 Advances in the Thiazole Backbone—Classification, Synthesis, Properties, and Applications of Azo Dyes 225
Zahir Ali Siddiqui, Babita Chaudhary, Srishti Tewari, Nagaiyan Sekar and Sandeep More
12.1 Introduction 225
12.2 Classification of the Thiazole-Based Azo Dyes 227
12.3 Synthetic Routes for the Synthesis of Thiazole-Based Azo Dyes 228
12.4 Classification of the Thiazole-Based Dyes 229
12.5 Conclusions 245
References 246
13 Simultaneous Azoic Dyeing and Multifunctional Finishing of Cotton Fabric 249
Pintu Pandit, M.D. Teli and Pravin P. Chavan
13.1 Introduction 249
13.2 Materials and Methods 251
13.3 Results and Discussion 254
13.4 Conclusion 264
References 264
14 Functional Aspects of Natural Dyes 267
Seiko Jose, Sabu Thomas, Anuradha Sankaran and Kumari Medha
14.1 Introduction 267
14.2 Antimicrobial Activities of Natural Dyes 268
14.3 Important Natural Dyes Having Antimicrobial Properties 270
14.4 Methods of Assessment 272
14.5 Mode of Action 272
14.6 Factors Affecting the Antimicrobial Activity of Natural Dyes on Textiles 272
14.7 Moth-Repellent Properties of Natural Dyes 273
14.8 UV Protection Properties 276
14.9 Deodorizing Properties 280
14.10 Agro-Waste as a Source of Natural Dyes for Functional Finishing 286
14.11 Future Aspects and Market 288
14.12 Conclusion 288
References 289
15 Sustainable Application of Flavonoid-Based Natural Colorants 295
Mahwish Salman, Shahid Adeel, Fatima Batool, Muhammad Usama, Atya Hassan, Meral Ozomay and Mozhgan Hosseinnezhad
15.1 Introduction 295
15.2 Flavonoids 297
15.3 Extraction Strategies 300
15.4 Carthamus Tinctorius L. (Safflower) 301
15.5 Tagetes Erecta L. (Marigold) 302
15.6 Crocus Sativus L. (Saffron) 303
15.7 Acacia Nilotica (Acacia) 304
15.8 Camellia Sinensis L. (Tea) 306
15.9 Allium Cepa L. (Onion) 307
15.10 Rosa Indica (Rose) 308
15.11 Vitis Vinifera (Common Grapevine) 309
15.12 Fagopyrum Esculentum (Buckwheat) 310
15.13 Liriope Platyphylla (Liriope) 311
15.14 Conclusion 312
Acknowledgment 312
References 313
16 Natural Dyes—A Way Forward 323
Akankshya Panda, Saptarshi Maiti, Pallavi Madiwale and Ravindra Adivarekar
16.1 Introduction 323
16.2 Synthetic Dyes: A Threat to Our Ecosystem 324
16.3 Sustainable Dyes and Pigments 324
16.4 Drive Toward Greener and Sustainable Dyes 326
16.5 Dyes and Pigments from Natural Sources 326
16.6 Production, Extraction, and Purification 330
16.7 Semisynthetic/Modified Dyes 333
16.8 Ecofriendly Dyeing Methods vs Natural Dyes 333
16.9 Emergence Toward Natural Dyes: Challenges and Sustainability 333
16.10 Biodyes and Their Acceptance: Reality Check 334
16.11 Natural Colorants: An Environment-Friendly Alternative to Synthetic Dyes 335
16.12 Fight to Optimize Their Variability 337
16.13 Effect of Mordants and Its Repercussions 337
16.14 Market Contest (Price, Quality, Availability, and Shade Matching) 338
16.15 Recent Developments 339
16.16 Conclusion 339
References 339
17 Rejuvenation of Natural Dyes From Medicinal-Based Plants 345
Shahid Adeel, Noman Habib, Aqsa Kanwal, Zeeshan Ali Shah, Mozhgan Hosseinnezhad, Fatima Batool and Muhammad Abdul Qayyum
17.1 Introduction 346
17.2 Classification of Natural Dyes 346
17.3 Isolation Methods 346
17.4 Mordanting as Shade Development Process 350
17.5 Natural Dye Sources 351
17.6 Importance of Natural Dyes in Electronics 357
17.7 Conclusion 358
References 358
18 Recent Advances in Developing Ecofriendly Cost-Effective Textile Processing 365
Shahid Adeel, Tanvir Ahmad, Fazal-ur-Rehman, Muhammad Kamran, Muhammad Sultan, Nimra Amin and Atya Hassan
18.1 Introduction 365
18.2 Fabrics Used in Textiles 366
18.3 Radiation as a Novel Tool 368
18.4 Microwave (MW) Radiation 368
18.5 Ultrasonic (US) Radiation 368
18.6 Ultraviolet (UV) Radiation 369
18.7 Gamma Radiation 369
18.8 Plasma Treatment 369
18.9 Recent Advances in Textile 370
18.10 Conclusion 373
Acknowledgment 373
References 373
19 Coloration with Natural Dyes of North-Eastern Region of India 377
Ritwik Chakraborty, Th. Basanta Singh, Palash Paul and Arup Kumar Haloi
19.1 Introduction 377
19.2 Natural Dyes 378
19.3 Natural Dyes of NER 379
19.4 Coloration with Selected Natural Dyes of NER 379
19.5 Conclusion 390
Acknowledgment 390
References 390
20 Aspects of Mordants and Metal Complex Dyes 393
Pranjul Vajpeyee, Sakshi Singh, Subhankar Maity, Pintu Pandit and Kunal Singha
20.1 Introduction 393
20.2 Chemistry of Metal-Complex Dyes 395
20.3 Premetallized Dyes 395
20.4 Structural Characteristics of Metal Complex Dyes 398
20.5 Stereochemistry and Isomerism 399
20.6 Mordant Dyes 402
20.7 Kinetics of Metal Complex Dye 403
20.8 Intraparticle Diffusion Model 405
20.9 Determination of Chromium Content 405
20.10 Conclusions 406
References 406
21 Challenges in Developing Sustainable Dyes and Pigments 411
Yogesh Gaikwad
21.1 Introduction 411
21.2 Sustainable Product 412
21.3 Sustainability in the Context of Dyes and Pigments 412
21.4 Sustainable Technologies for Dyeing and Printing 414
21.5 Digital Printing 415
21.6 Supercritical Dyeing 416
21.7 Selected Pigment Printing Methods 417
21.8 Laser Printing on Denim 417
21.9 D Mounding or 3D Printing 418
21.10 Sustainable Pigments 419
21.11 Future Perspective and Conclusion 420
References 420
22 Evolutions in Green Chemistry and Sustainable Economy 421
Ashok Athalye
22.1 Introduction 421
22.2 Rising Textile Consumption 422
22.3 Ecological Aspects in Textile Pocessing 422
22.4 Sustainability in Textile Value Chain 423
22.5 Expectations of a Textile Processor 425
22.6 Evolution of Eco-Norms 426
22.7 Environmental Management Systems 426
22.8 Green Chemistry and Technology 427
22.9 Ecology and Ecosystems 428
22.10 Pollutants From Textile Processing 428
22.11 Influent and Input Output Analysis 430
22.12 Effluent Characteristics 432
22.13 Ecostandards and Certifications 435
22.14 Conclusions 440
References 440
23 Progress in Innovative Green Chemistry and Circular Economy in Textiles 443
Subhankar Maity, Pintu Pandit, Kunal Singha and Saurav Kar
23.1 Introduction 443
23.2 Green Chemicals and Hazardous Substances 444
23.3 Recent Trends in Green Solvents 446
23.4 Textile Supply Chain and Life Cycle Assessment 448
23.5 Green Textile Fibers 449
23.6 Approach Toward Green Textile Pretreatment Processes 450
23.7 Approaches for Greener Textile Coloration 450
23.8 Barriers of Green Chemistry 451
23.9 Circular Economy 452
23.10 Challenges for Circular Economy 454
23.11 Conclusions 454
References 454
24 Critical Review on the Role of Nanomaterials in Textile Wastewater Treatment 457
Shanmugasundaram O. Lakshmanan
24.1 Introduction 457
24.2 Titanium-di-oxide Nanoparticles on Photocatalytic Activity 458
24.3 Tin Oxide Nanoparticles 459
24.4 Carbon Nanotubes 460
24.5 Silver Nanoparticles 460
24.6 Nanoparticles Doped with Transition Metals 460
24.7 Nanocomposites 461
24.8 Other Nanomaterials 461
24.9 Limitations of Nanomaterials 462
24.10 Conclusion 462
References 462
Index 469
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