Thermodynamic Properties of Aqueous Solutions of Organic Substances

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ISBN: 9780849393426 | 0849393426
Cover: Hardcover
Copyright: 12/1/1993

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Thermodynamic Properties of Aqueous Solutions of Organic Substances discusses the structure of aqueous solutions of organic substances and the intermolecular reactions in them, presenting experimental data, modern concepts concerning the properties of these solutions, and the results of computer simulation. The book offers an in-depth study of the properties of maximally dilute aqueous solutions of polar and nonpolar organic molecules as well as the specific enthalpies of mixing. The Addendum contains experimental data on the thermodynamic properties of infinitely dilute solutions.

Preface
Abbreviations
Thermodynamic Study of Liquid Water Today	p. 1
Concept of Liquid Structure	p. 1
Radial Distribution Function of Water	p. 2
Molecular Structure and Hydrogen Bonds	p. 3
Experimental Data on Thermodynamic Properties	p. 4
Empirical and Model Approaches to the Explanation of Water Properties	p. 6
Rigorous Theoretical Methods	p. 9
Aqueous Solutions of Nonpolar Molecules	p. 17
Specific Features of Experimental Research	p. 17
Aqueous Solutions of Nonpolar Gases	p. 18
Solutions of Liquid and Solid Nonpolar Substances	p. 29
Theoretical Conceptions of Aqueous Solutions of Nonpolar Substances	p. 33
Infinitely Dilute Aqueous Solutions of Polar Organic Molecules	p. 63
General Concepts	p. 63
Present State of Experimental Research	p. 64
Partial Molar Volumes	p. 66
Partial Molar Compressibilities	p. 81
Enthalpies of Solution and Solvation	p. 88
Heat Capacity of Solution and Solvation	p. 102
Gibbs Energies	p. 115
Entropies of Solution and Hydration	p. 120
Computer Simulation of Aqueous Solutions of Polar Molecules
Experimental Study of the Thermodynamic Properties of Aqueous Solutions of Organic Substances in a Wide Composition Range	p. 133
Thermodynamic Characteristics of the Formation of Solutions of Finite Concentrations	p. 133
Enthalpy Effects of Mixing	p. 137
Heat Capacity	p. 141
Volume Effects of Mixing	p. 141
Excess Gibbs Energy	p. 146
Regularities of the Concentration Dependence of Thermodynamic Properties of Binary Aqueous Solutions of Organic Substances: Correlations with Intermolecular Interactions	p. 149
Dependence of Thermodynamic Properties of Dilute Solutions on Composition and Solute-Solute Interactions	p. 150
Enthalpy Characteristics of Binary Aqueous Solutions of Nonelectrolytes	p. 170
Excess Heat Capacities	p. 197
Volume Effects of Mixing	p. 203
Concentration Dependence of Excess Gibbs Energy and the Structural Organization of Binary Aqueous Solutions of Nonelectrolytes: Application of the Kirkwood-Buff Theory	p. 214
Influence of the Properties of Water and Aqueous Organic Mixtures on the Characteristics of Chemical Reactions in Them	p. 231
General Concepts	p. 231
Use of Thermodynamic Functions of Solvation to Analyze the Thermodynamics and Kinetics of Reactions	p. 232
Relative Contributions of Solvation of Neutral Molecules and Ions to the Thermodynamics of Reactions	p. 234
Reactions of Pure Solvents: Solvolysis of t-BuCl	p. 235
Reactions in Binary Aqueous Organic Solvents	p. 237
Description of Chemical Reactions in Aqueous Systems by Empirical Parameters	p. 249
Hydrophobic Effects in Chemical Reactions	p. 250
Addendum	p. 255
References	p. 339
Table of Contents provided by Blackwell. All Rights Reserved.

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Thermodynamic Properties of Aqueous Solutions of Organic Substances

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Thermodynamic Properties of Aqueous Solutions of Organic Substances

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