Design and Construction of Coordination

Design and Construction of Coordination Polymers Edited by Mao-Chun Hong Ling Chen

Mao-Chun Hong is Professor and Director of the Fujian Institute of Research on the Structure of Matter (FIRSM) at the Chinese Academy of Sciences (CAS). He was selected as the member of CAS in 2003. He received his MS from FIRSM in 1981 and his PhD from Nagoya University, Japan, 2002. He is the associate editor of Crystal Growth & Design and Chinese Journal of Structural Chemistry, and on the editorial boards for Inorganic Chemistry Communications, Inorg. Chim. Acta, and the Journal of Molecular Structure.

Ling Chen is Professor of the Fujian Institute of Research on the Structure of Matter (FIRSM) at the Chinese Academy of Sciences (CAS). She received her MS from Beijing Normal University and her PhD from FIRSM, CAS, in 1999, and concluded her postdoctoral research at Iowa State University from 2000 to 2003. Professor Chen won an award in the "One Hundred Talent Project" from CAS in 2003. Her group's research efforts focus on inorganic and materials chemistry dealing with synthesis, characterization, and understanding of novel solid-state functional materials, especially thermoelectric multinary antimonides and tellurides.

Contributors	p. xi
Preface	p. xv
Coordinative Flexibility of Monovalent Silver in [AgI&arrow;L1]L2 Complexes	p. 1
Introduction	p. 1
Ligands L1 with 1,2 N-Donor Functions	p. 2
Ligands L1 with 1,3 N-Donor Functions	p. 7
Ligands L1 with 1,4 N-Donor Functions	p. 12
Conclusions	p. 19
References	p. 22
Indium(III)-Organic Coordination Polymers with Versatile Topological Structures Based on Multicarboxylate Ligands	p. 25
Introduction	p. 25
Architectures Constructed by In(III) and Benzenedicarboxylates	p. 27
Architectures Constructed by In(III) and Benzenetricarboxylates	p. 35
Architectures Constructed by In(III) and Other Benzenemulticarboxylates	p. 49
Luminescence, Ion Exchange, and Hydrogen Storage	p. 55
Conclusions	p. 56
References	p. 59
Crystal Engineering of Coordination Polymers via Solvothermal In Situ Metal-Ligand Reactions	p. 63
Introduction	p. 63
Metal-Redox Reaction	p. 65
Conversion of Carboxylic Acid	p. 69
Carbon-Carbon Bond Formation	p. 72
Heterocycle Formation from Small Molecules	p. 75
Transformation of Sulfur-Containing Ligands	p. 81
Conclusions	p. 83
References	p. 84
Construction of Some Organic-Inorganic Hybrid Complexes Based on Polyoxometalates	p. 87
Introduction	p. 87
Complexes Built Up by POMs with 1,2,4-Triazolate and Its Derivatives	p. 88
Complexes Built Up by Molybdenum Oxide Chains with Pyridine Derivatives	p. 102
Conclusions	p. 107
References	p. 108
Silver(I) Coordination Polymers	p. 111
Introduction	p. 111
Coordination Geometries of Ag+ Ions	p. 112
Ligands in Silver(I) Coordination Polymers	p. 121
Supramolecular Interactions and Counter Anions in Silver(I) Coordination Polymers	p. 128
One-to Three-Dimensional Coordination Polymers Based on Silver-Ligand Coordination Bonds	p. 130
Intertwining or Interpenetrating of Silver(I) Coordination Polymers	p. 135
Properties of Silver(I) Coordination Polymers	p. 137
References	p. 139
Tuning Structures and Properties of Coordination Polymers by the Noncoordinating Backbone of Bridging Ligands	p. 145
Introduction	p. 145
Ligand Design for Coordination Polymers	p. 146
Role of Noncoordinating Backbones of Bridging Ligands	p. 150
Conclusions	p. 164
References	p. 165
Ferroelectric Metal-Organic Coordination Compounds	p. 71
Introduction	p. 71
Homochiral Discrete or Zero-Dimensional MOCCs	p. 173
Acentric MOCPs Produced by Supramolecular Crystal Engineering	p. 179
Homochiral MOCPs Constructed with Optical Organic Ligands	p. 183
Conclusions	p. 191
References	p. 192
Constructing Magnetic Molecular Solids by Employing Three-Atom Ligands as Bridges	p. 195
Introduction	p. 195
Coordination Characteristics of Three-Atom Bridges and Their Role in Mediating Magnetic Interaction	p. 197
Co-Ligands, Templating Cations, and Other Short Bridges	p. 200
Magnetic Molecular Solids Based on Three-Atom Bridges	p. 202
Conclusions	p. 222
References	p. 223
Structures and Properties of Heavy Main-Group Iodometalates	p. 229
Introduction	p. 229
Structural Features of Iodobismuthates and Iodoplumbates	p. 230
Structural Modification	p. 249
Optical and Thermal Properties	p. 255
Summary	p. 262
References	p. 263
Cluster-Based Supramolecular Compounds from Mo(W)/Cu/S Cluster Precursors	p. 267
Introduction	p. 267
Strategies for Design and Assembly	p. 268
Structural Features	p. 273
Luminescent and Third-Order Nonlinear Optical Properties	p. 298
Conclusions	p. 301
References	p. 302
Microporous Metal-Organic Frameworks as Functional Materials for Gas Storage and Separation	p. 307
Introduction	p. 307
Design, Rational Synthesis, and Structure Description	p. 309
Structure Stability, Permanent Microporosity, and Hydrogen Adsorption	p. 322
Hydrocarbon Adsorption	p. 332
Ship-in-Bottle Synthesis	p. 348
Summary and Conclusions	p. 349
References	p. 350
Design and Construction of Metal-Organic Frameworks for Hydrogen Storage and Selective Gas Adsorption	p. 353
Introduction	p. 353
Hydrogen Storage in Porous Metal-Organic Frameworks	p. 354
Porous Metal-Organic Frameworks for Selective Gas Adsorption	p. 366
Outlook	p. 369
References	p. 370
Structure and Activity of Some Bioinorganic Coordination Complexes	p. 375
Introduction	p. 375
Biomimetic Modeling of a Metalloenzyme with a Cluster Structure	p. 376
Bioinspired Complexes with a Recognition Domain	p. 384
Functional Complexes as Therapeutic Agents	p. 391
Conclusions	p. 400
References	p. 401
Index	p. 405
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Design and Construction of Coordination Polymers

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