Metal Amide Chemistry

, by Lappert, Michael; Protchenko , Andrey; Power, Philip P.; Seeber, Alexandra

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ISBN: 9780470721841 | 0470721847
Cover: Hardcover
Copyright: 2/9/2009

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Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power's 1980 book "Metal and Metalloid Amides."An introduction to the topic is followed by in-depth discussions of the amide compounds of: alkali metals alkaline earth metals zinc, cadmium and mercury the transition metals group 3 and lanthanide metals group 13 metals silicon and the group 14 metals group 15 metals the actinide metalsAccompanied by a substantial bibliography, this is an essential guide for researchers and advanced students in academia and research working in synthetic organometallic, organic and inorganic chemistry, materials chemistry and catalysis.

Biographies	p. xi
Preface	p. xiii
Introduction	p. 1
Scope and Organisation of Subject Matter	p. 1
Developments and Perspectives	p. 2
Alkali Metal Amides	p. 7
Introduction	p. 7
Lithium Amides	p. 8
Introduction	p. 8
Monomeric Lithium Amides	p. 9
Dimeric Lithium Amides	p. 11
Trimeric Lithium Amides	p. 13
Tetrameric Lithium Amides	p. 14
Higher Aggregate Lithium Amides	p. 15
Laddering	p. 17
Heterometallic Derivatives	p. 18
Sodium Amides	p. 20
Introduction	p. 20
Monomeric and Dimeric Sodium Amides	p. 21
Higher Aggregate Sodium Amides	p. 22
Heterometallic Sodium Amides	p. 23
Potassium Amides	p. 25
Introduction	p. 25
Potassium Parent Amides (-NH2 as Ligand)	p. 25
Potassium Primary and Secondary Amides	p. 26
Heterometallic Potassium Amides	p. 26
Rubidium Amides	p. 28
Caesium Amides	p. 30
References	p. 31
Beryllium and the Alkaline Earth Metal Amides	p. 39
Introduction	p. 39
Beryllium Amides	p. 40
Magnesium Amides	p. 43
Introduction	p. 43
Monomeric Magnesium Amides	p. 45
Dimeric Magnesium Amides	p. 48
Higher Aggregates and Related Magnesium Amides	p. 51
Heterometallic Magnesium Amides	p. 52
Magnesium Inverse Crown Complexes	p. 56
Magnesium Imides	p. 59
Calcium Amides	p. 60
Introduction	p. 60
Monomeric Calcium Amides	p. 60
Dimeric Calcium Amides and Higher Aggregates	p. 63
Heterometallic Calcium Amide Derivatives	p. 64
Strontium Amides	p. 65
Introduction	p. 65
Monomeric Strontium Amides	p. 67
Higher Aggregate Strontium Amides	p. 68
Barium Amides	p. 69
Introduction	p. 69
Monomeric Barium Amides	p. 69
Dimeric Barium Amides	p. 70
Heterometallic Barium Amides	p. 70
References	p. 72
Amides of the Group 3 and Lanthanide Metals	p. 79
Introduction	p. 79
The Pre-1996 Literature: Anwander's Review	p. 81
Introduction	p. 81
Ln^2+III Complexes with N-Hydrocarbyl-Amido Ligands	p. 81
Ln^2+III Complexes having Silylamido Ligands	p. 81
Bis(Trimethylsilyl) Amido-Ln^2+II Complexes and a Ce^2+IV Analogue	p. 82
Ln^2+III Complexes having Donor-Functionalised Amido Ligands	p. 83
Ln Amides as Precursors for Ln Coordination or Organometallic Compounds	p. 85
Applications as Materials or Catalysts	p. 85
The Recent (Post-1995) Literature	p. 86
Introduction	p. 86
Ln^2+III Complexes with N-Hydrocarbyl Substituted Ligands	p. 86
Ln^2+III Complexes having Silylamido Ligands	p. 87
Ln^2+II and Ce^2+IV Amides	p. 90
Ln Complexes having Donor-Functionalised Amido Ligands	p. 93
Ln Amides as Precursors for Ln Coordination or Organometallic Compounds	p. 104
Applications as Materials or Catalysts	p. 110
Ln Complexes having 1,4-Disubstituted-1,4-Diazabutadiene Ligands, R2-DAD	p. 111
References	p. 113
Amides of the Actinide Metals	p. 121
Introduction	p. 121
Neutral Amidouranium(IV) and Thorium(IV) Complexes	p. 122
Introduction	p. 122
Hydrocarbylamido-An^2+IV Compounds Free of ¿-Centred Ligands	p. 123
Silylamido-An^2+IV Compounds Free of ¿-Centred Co-ligands	p. 131
An^2+IV Amides Containing ¿-Centred Co-ligands	p. 131
Neutral U^2+III Amides	p. 135
Neutral Mixed Valence (U^2+III/U^2+IV), U^2+II, U^2+V and U^2+VI Amides	p. 136
Amidouranates	p. 139
Amidouranium Tetraphenylborates	p. 141
References	p. 144
Amides of the Transition Metals	p. 149
Introduction	p. 149
Transition Metal Derivatives of Monodentate Amides	p. 150
Overview	p. 150
Synthesis	p. 162
Structure and Bonding	p. 164
Parent Amido (-NH₂) Derivatives	p. 167
Low-coordinate Transition Metal Amides	p. 170
'Two-sided' Amido Ligands	p. 173
Transition Metal Complexes of Polydentate Amido Ligands	p. 178
Introduction	p. 178
Amido Phosphine Ligands	p. 179
Multidentate Podand Ligands	p. 180
Other Chelating Amido Ligands	p. 184
References	p. 186
Amides of Zinc, Cadmium and Mercury	p. 205
Introduction	p. 205
Neutral Homoleptic Zinc, Cadmium and Mercury Amides	p. 206
Ionic Metal Amides	p. 208
Amidometallates	p. 208
Zincation Mediated by Amidozinc Complexes	p. 208
Other Ionic Group 12 Metal Amido Salts	p. 211
Lewis Base Complexes, Chelated Metal Amides and Heteroleptic Amido Complexes	p. 212
References	p. 214
Amides of the Group 13 Metals	p. 219
Introduction	p. 219
Synthesis	p. 220
M-N Bonding (M = Al, Ga, In or Tl)	p. 220
Multiple Character in M-N (M = Al - Tl) Bonds	p. 221
Aluminium Amides	p. 221
Aluminium Parent Amides (-NH₂ as Ligand)	p. 221
Monomeric Aluminium Amides	p. 223
Dimeric Aluminium Amides	p. 226
Higher Aggregate Aluminium Amides	p. 228
Heterometallic Aluminium Amides	p. 230
Aluminium Imides (Iminoalanes)	p. 232
Aluminium(I) Amides	p. 235
Gallium Amides	p. 236
Introduction	p. 236
Monomeric Gallium Amides	p. 237
Associated Gallium Amides	p. 238
Heterometallic Gallium Amides	p. 239
Iminogallanes (Gallium Imides)	p. 240
Gallium Amides in Low (<+3) Oxidation States	p. 242
Indium Amides	p. 242
Introduction	p. 242
Monomeric Indium(III) Amides	p. 242
Associated Indium Amides	p. 243
Heterometallic Indium Amides	p. 245
Iminoindanes (Indium Imides)	p. 245
Indium Amides in Oxidation States <+3	p. 247
Thallium Amides	p. 248
Introduction	p. 248
Thallium(I) Amides	p. 248
Thallium(III) Derivatives	p. 251
Thallium Amides in Mixed Oxidation States	p. 251
Heterometallic Derivatives	p. 252
References	p. 253
Subvalent Amides of Silicon and the Group 14 Metals	p. 263
Introduction	p. 263
Subvalent Amidosilicon Compounds	p. 263
Introduction	p. 264
Bis(amino)silylenes: Pre-2001	p. 265
Bis(amino)silylenes: 2001-2004	p. 266
Bis(amino)silylenes: Post-2004	p. 271
Amidometal(II) Chemistry [Ge(II), Sn(II), Pb(II)]	p. 279
Introduction	p. 279
Homoleptic Metal(II) Amides: Synthesis, Structures and Physical Properties	p. 279
Protonolyses of Homoleptic Metal(II) Amides	p. 287
Heteroleptic Metal(II) Amides	p. 290
Metathetical Exchange Reactions	p. 295
Reactions with Heterocumulenes	p. 297
Oligomeric Metal(II) Imides	p. 298
Metal(II) Amides based on 1,4-Diazabutadienes or a Related Compound	p. 298
Oxidative Addition and Redox Reactions	p. 299
Reactions with Transition Metal Complexes	p. 306
Dimeric Metal(III) Imides: Biradicaloid Compounds	p. 312
Higher-Nuclearity Group 14 Metalloid Clusters having Amido Ligands	p. 316
References	p. 318
Amides of the Group 15 Metals (As, Sb, Bi)	p. 327
Introduction	p. 327
Mononuclear Group 15 Metal(III) Amides	p. 329
Introduction	p. 329
Synthesis, Structures and Protolyses of Metal(III) Amides	p. 329
Synthesis, Structures and Reactions of Heteroleptic Mononuclear Bis(amido) Metal(III) Compounds	p. 330
Synthesis, Structures and Reactions of Heteroleptic Mononuclear Amidometal(III) Compounds	p. 333
Bis(amido)Metal(III) Salts	p. 334
Oligomeric Group 15 Metal Imides	p. 338
Binuclear and Oligomeric Group 15 Metal(III) Imides	p. 339
Binuclear Group 15 Metal(V) Imides	p. 342
Mononuclear Group 15 Metal(V) Amides	p. 343
Group 15 Metal(III) Macrocyclic Imides	p. 344
Miscellaneous Group 15 Metal-Nitrogen Compounds	p. 345
References	p. 347
Index	p. 351
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Metal Amide Chemistry

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